Spontaneous hydrolysis of sodium borohydride in harsh conditions

International Journal of Hydrogen Energy

Volumn 36, Issue 1, 2011, Pages 224-233

  Andrieux, Jérôme ^a   Demirci, Umit Bilge ^a   Hannauer, Julien ^a   Gervais, Christel ^b   Goutaudier, Christelle ^a   Miele, Philippe ^a  

^a UNIVERSITÉ CLAUDE BERNARD LYON 1   (France)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

Hydroxyborate anions; Kinetics; Sodium borohydride; Sodium metaborate; Spontaneous hydrolysis

Indexed keywords

APPARENT ACTIVATION ENERGY; EXPERIMENTAL CONDITIONS; HYDROGEN STORAGE MATERIALS; HYDROXYBORATE ANIONS; PH VARIATION; PORTABLE APPLICATIONS; REACTION ORDERS; SODIUM BOROHYDRIDE; SODIUM BOROHYDRIDES; SODIUM METABORATE; SPONTANEOUS HYDROLYSIS; STABILIZING AGENTS; XRD;

ACTIVATION ENERGY; HYDROGEN STORAGE; HYDROLYSIS; SODIUM;

REACTION INTERMEDIATES;

EID: 79451470077     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.10.055     Document Type: Article

References (39)

1. H.I. Schlesinger, H.C. Brown, A.E. Finholt, J.R. Gilbreath, H.R. Hoekstra, and E.K. Hyde Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen J Am Chem Soc 75 1953 215 219
2. U.B. Demirci, and P. Miele Sodium tetrahydroborate as hydrogen/energy carrier, its history C R Chim 12 2009 943 950
3. M. Kilpatrick, and C.D. McKinney Kinetics of the reaction of lithium borohydride in aqueous solution J Am Chem Soc 72 1950 5474 5476
4. R.L. Pecsok Polarographic studies of the oxidation and hydrolysis of sodium borohydride J Am Chem Soc 75 1953 2862 2864
5. R.E. Davis, and C.G. Swain General acid catalysis of the hydrolysis of sodium borohydride J Am Chem Soc 82 1960 5949 5950
6. R.E. Davis, E. Bromels, and C.L. Kibby Boron hydrides. III. Hydrolysis of sodium borohydride in aqueous solution J Am Chem Soc 84 1962 885 892
7. W.H. Stockmayer, R.R. Miller, and R.J. Zeto Kinetics of borohydride hydrolysis J Phys Chem A 61 1961 1076 1077
8. W.L. Jolly, and R.E. Mesmer Exchange of hydrogen between water and hydroborate ion J Am Chem Soc 83 1961 4470 4471
9. R.E. Mesmer, and W.L. Jolly The hydrolysis of aqueous hydroborate Inorg Chem 1 1962 608 612
10. - hydrolysis Kinet Katal 6 1965 541 544
11. K.N. Mochalov, V.S. Khain, and G.G. Gil'manshin Generalized scheme for the hydrolysis of the borohydride ion and diborane Dokl Akad Nauk 162 1965 402 406
12. J.A. Gardiner, and J.W. Collat The hydrolysis of sodium tetrahydroborates. Identification of an intermediate J Am Chem Soc 86 1964 3165 3166
13. J.A. Gardiner, and J.W. Collat Kinetics of the stepwise hydrolysis of tetrahydroborate ion J Am Chem Soc 87 1965 1692 1700
14. 3 as an intermediate in tetrahydroborate hydrolysis J Am Chem Soc 94 1972 6371 6376
15. S.C. Amendola, S.L. Sharp-Goldman, M.S. Janjua, N.C. Spencer, M.T. Kelly, and P.J. Petillo A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst Int J Hydrogen Energy 25 2000 969 975
16. Ö Metin, and S. Özkar Hydrogen generation from the hydrolysis of sodium borohydride by using water dispersible, hydrogenphosphate-stabilized nickel(0) nanoclusters as catalyst Int J Hydrogen Energy 32 2007 1707 1715
17. A.J. Hung, S.F. Tsai, Y.Y. Hsu, J.R. Ku, Y.H. Chen, and C.C. Yu Kinetics of sodium borohydride hydrolysis reaction for hydrogen generation Int J Hydrogen Energy 33 2008 6205 6215
18. B.H. Liu, and Q. Li A highly active Co-B catalyst for hydrogen generation from sodium borohydride hydrolysis Int J Hydrogen Energy 33 2008 7385 7391
19. R. Oronzio, G. Monteleone, A. Pozio, M. De Francesco, and S. Galli New reactor design for catalytic sodium borohydride hydrolysis Int J Hydrogen Energy 34 2009 4555 4560
20. O. Akdim, U.B. Demirci, and P. Miele More reactive cobalt chloride in the hydrolysis of sodium borohydride Int J Hydrogen Energy 34 2009 9444 9449
21. P.P. Prosini, and P. Gislon Water consumption during solid state sodium borohydride hydrolysis Int J Hydrogen Energy 2010 10.1016/j.ijhydene.2010.07.094
22. X.L. Ding, X. Yuan, C. Jia, and Z.F. Ma Hydrogen generation from catalytic hydrolysis of sodium borohydride solution using Cobalt-Copper-Boride (Co-Cu-B) catalysts Int J Hydrogen Energy 2010 10.1016/j.ijhydene.2010.07.030
23. D. Hua, Y. Hanxi, A. Xinping, and C. Chuansin Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst Int J Hydrogen Energy 28 2003 1095 1100
24. E.H. Jensen A study on sodium borohydride with special reference to its analytical application in organic chemistry 1954 Nyt. Nordisk Forlag Copenhagen
25. B. Molina Concha, M. Chatenet, F. Maillard, E.A. Ticianelli, F.H.B. Lima, and R.B. de Lima In situ infrared (FTIR) study of the mechanism of the borohydride oxidation reaction Phys Chem Phys Chem 12 2010 11507 11516
26. 1H NMR investigation of the hydroxyborohydride anion Inorg Chem Commun 10 2007 1074 1078
27. CRC handbook of chemistry and physics 81st ed. 2000 CRC Press Boca Raton
28. 4 hydrolysis and its behavior at a room temperature Int J Hydrogen Energy 33 2008 7378 7384
29. V.J. Goubeau, and H. Kallfass Die reaktion natriumborhydrid and wasser Z Anorg Allg Chem 1959 160 169
30. K.T. Harvey, and N.R. McQuaker Infrared and Raman spectra of potassium and sodium borohydride Can J Chem 49 1971 3272 3281
31. 4; syntheses, crystal structures, thermal analyses, mass and vibrational spectra J Alloys Compd 491 2009 98 105
32. L. Jun, X. Shuping, and G. Shiyang TF-IR and Raman spectroscopic study of hydrated borates Spectrochim Acta 51A 1995 519 532
33. F.A. Miller, and C.H. Wilkins Infrared spectra and characteristics frequencies of inorganic ions Anal Chem 24 1952 1253 1261
34. B. Molina Concha, M. Chatenet, C. Coutanceau, and F. Hahn In situ infrared (FTIR) study of the borohydride oxidation reaction Electrochem Commun 11 2009 223 226
35. R. Janda, and G. Heller IR- and Ramanspektren isotop markierter tetra- und pentaborate? Spectrochim Acta 36 1982 997 1001
36. 2O Korean J Chem Eng 25 2008 1331 1337
37. 11B NMR measurements J Phys Chem B 110 2006 17024 17033
38. E.Y. Marrero-Alfonso, T.A. Davis, and M.A. Matthews Minimizing water utilization in hydrolysis of sodium borohydride: the role of sodium metaborate hydrates Int J Hydrogen Energy 32 2007 4717 4722
39. E.Y. Marrero-Alfonso, J.R. Gray, T.A. Davis, and M.A. Matthews Hydrolysis of sodium borohydride with steam Int J Hydrogen Energy 32 2007 4723 4728