Production of Sulfate Radical and Hydroxyl Radical by Reaction of Ozone with Peroxymonosulfate: A Novel Advanced Oxidation Process

Environmental Science and Technology

Volumn 49, Issue 12, 2015, Pages 73307339-

  Yang, Yi ^a   Jiang, Jin ^a   Lu, Xinglin ^a   Ma, Jun ^a   Liu, Yongze ^a  

^a HARBIN INSTITUTE OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANIC ACIDS; OZONE; PROBES; RATE CONSTANTS;

ADVANCED OXIDATION PROCESSES; CARBONATE RADICAL; CHEMICAL PROBES; HYDROXYL RADICALS; PEROXYMONOSULFATE; RELATIVE CONTRIBUTION; SECOND-ORDER RATE CONSTANTS; SULFATE RADICALS;

BIOLOGICAL MATERIALS;

ATRAZINE; HUMIC ACID; HYDROXYL RADICAL; NITROBENZENE; OZONE; PEROXYMONOSULFATE; RADICAL; SULFATE; SULFATE RADICAL; UNCLASSIFIED DRUG; PEROXIDE; SOLUTION AND SOLUBILITY; WATER POLLUTANT;

ANION; CHEMICAL REACTION; DECOMPOSITION; EFFICIENCY MEASUREMENT; EXPERIMENTAL STUDY; HUMIC ACID; HYDROXYL RADICAL; OXIDATION; OZONE; PROBE; REACTION KINETICS; SULFATE;

ARTICLE; CHEMICAL REACTION KINETICS; CONTROLLED STUDY; DEGRADATION; OXIDATION; PH; RATE CONSTANT; ANALYSIS; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION; SOLUTION AND SOLUBILITY; WATER POLLUTANT; WATER QUALITY;

ATRAZINE; HYDROGEN-ION CONCENTRATION; HYDROXYL RADICAL; KINETICS; OXIDATION-REDUCTION; OZONE; PEROXIDES; SOLUTIONS; SULFATES; WATER POLLUTANTS, CHEMICAL; WATER QUALITY;

EID: 84934972259     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es506362e     Document Type: Article

References (52)

1. von Gunten, U. Ozonation of drinking water: Part I. Oxidation kinetics and product formation Water Res. 2003, 37 (7) 1443-1467
2. Huber, M. M.; GÖbel, A.; Joss, A.; Hermann, N.; LÖffler, D.; McArdell, C. S.; Ried, A.; Siegrist, H.; Ternes, T. A.; von Gunten, U. Oxidation of pharmaceuticals during ozonation of municipal wastewater effluents: A pilot study Environ. Sci. Technol. 2005, 39 (11) 4290-4299
3. Lee, Y.; Gerrity, D.; Lee, M.; Bogeat, A. E.; Salhi, E.; Gamage, S.; Trenholm, R. A.; Wert, E. C.; Snyder, S. A.; von Gunten, U. Prediction of micropollutant elimination during ozonation of municipal wastewater effluents: Use of kinetic and water specific information Environ. Sci. Technol. 2013, 47 (11) 5872-5881
4. Buxton, G. V.; Greenstock, C. L.; Helman, W. P.; Ross, A. B. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals J. Phys. Chem. Ref. Data 1988, 17 (2) 513-886
5. Staehelin, J.; Hoigne, J. Decomposition of ozone in water: Rate of initiation by hydroxide ions and hydrogen peroxide Environ. Sci. Technol. 1982, 16 (10) 676-681
6. Merényi, G.; Lind, J.; Naumov, S.; von Sonntag, C. Reaction of ozone with hydrogen peroxide (peroxone process): A revision of current mechanistic concepts based on thermokinetic and quantum-chemical considerations Environ. Sci. Technol. 2010, 44 (9) 3505-3507
7. Sonntag, C.; von Gunten, U. Chemistry of ozone in water and wastewater treatment: From basic principles to applications; IWA publishing: New York, 2012.
8. Lutze, H. V.; Bircher, S.; Rapp, I.; Kerlin, N.; Bakkour, R.; Geisler, M.; von Sonntag, C.; Schmidt, T. C. Degradation of chlorotriazine pesticides by sulfate radicals and the influence of organic matter Environ. Sci. Technol. 2015, 49 (3) 1673-1680
9. Hori, H.; Yamamoto, A.; Hayakawa, E.; Taniyasu, S.; Yamashita, N.; Kutsuna, S.; Kiatagawa, H.; Arakawa, R. Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant Environ. Sci. Technol. 2005, 39 (7) 2383-2388
10. Antoniou, M. G.; de la Cruz, A. A.; Dionysiou, D. D. Degradation of microcystin-LR using sulfate radicals generated through photolysis, thermolysis and e- transfer mechanisms Appl. Catal., B 2010, 96 (3-4) 290-298
11. Neta, P.; Huie, R. E.; Ross, A. B. Rate constants for reactions of inorganic radicals in aqueous solution J. Phys. Chem. Ref. Data 1988, 17 (3) 1027-1284
12. Madhavan, V.; Levanon, H.; Neta, P. Decarboxylation by SO4•- radicals Radiat. Res. 1978, 76 (1) 15-22
13. Peyton, G. R. The free-radical chemistry of persulfate-based total organic-carbon analyzers Mar. Chem. 1993, 41 (1-3) 91-103
14. Criquet, J.; Leitner, N. K. V. Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis Chemosphere 2009, 77 (2) 194-200
15. Yoon, S.-H.; Jeong, S.; Lee, S. Oxidation of bisphenol A by UV/S2O: Comparison with UV/H2O2 Environ. Technol. 2011, 33 (1) 123-128
16. Gara, P. M. D.; Bosio, G. N.; Gonzalez, M. C.; Mártire, D. O. Kinetics of the sulfate radical-mediated photo-oxidation of humic substances Int. J. Chem. Kinet. 2008, 40 (1) 19-24
17. Anipsitakis, G. P.; Dionysiou, D. D. Radical generation by the interaction of transition metals with common oxidants Environ. Sci. Technol. 2004, 38 (13) 3705-3712
18. Guan, Y.-H.; Ma, J.; Li, X.-C.; Fang, J.-Y.; Chen, L.-W. Influence of pH on the formation of sulfate and hydroxyl radicals in the UV/peroxymonosulfate system Environ. Sci. Technol. 2011, 45 (21) 9308-9314
19. Zhang, T.; Zhu, H.; Croué, J.-P. Production of sulfate radical from peroxymonosulfate induced by a magnetically separable CuFe2O4 spinel in water: Efficiency, stability, and mechanism Environ. Sci. Technol. 2013, 47 (6) 2784-2791
20. He, X.; de la Cruz, A. A.; Dionysiou, D. D. Destruction of cyanobacterial toxin cylindrospermopsin by hydroxyl radicals and sulfate radicals using UV-254nm activation of hydrogen peroxide, persulfate and peroxymonosulfate J. Photochem. Photobiol., A: Chem. 2013, 251, 160-166
21. Cong, J.; Wen, G.; Huang, T.; Deng, L.; Ma, J. Study on enhanced ozonation degradation of para-chlorobenzoic acid by peroxymonosulfate in aqueous solution Chem. Eng. J. 2015, 264, 399-403
22. Hong, S.; Elimelech, M. Chemical and physical aspects of natural organic matter (NOM) fouling of nanofiltration membranes J. Membr. Sci. 1997, 132 (2) 159-181
23. Lee, Y.; Yoon, J.; von Gunten, U. Spectrophotometric determination of ferrate (Fe(Vl)) in water by ABTS Water Res. 2005, 39 (10) 1946-1953
24. Hoigné, J. Chemistry of aqueous ozone and transformation of pollutants by ozonation and advanced oxidation processes. In Quality and Treatment of Drinking Water II; Springer: New York, 1998; pp 83-141.
25. Bader, H.; Hoigné, J. Determination of ozone in water by the indigo method Water Res. 1981, 15 (4) 449-456
26. Lipari, F.; Swarin, S. J. Determination of formaldehyde and other aldehydes in automobile exhaust with an improved 2,4-dinitrophenylhydrazine method J. Chromatogr. A 1982, 247 (2) 297-306
27. Hoigné, J.; Bader, H. Rate constants of reactions of ozone with organic and inorganic compounds in water-I: Non-dissociating organic compounds Water Res. 1983, 17 (2) 173-183
28. Elovitz, M. S.; von Gunten, U. Hydroxyl radical/ozone ratios during ozonation processes. I. The Rct concept Ozone Sci. Eng. 1999, 21 (3) 239-260
29. Acero, J. L.; Stemmler, K.; von Gunten, U. Degradation kinetics of atrazine and its degradation products with ozone and OH radicals: A predictive tool for drinking water treatment Environ. Sci. Technol. 2000, 34 (4) 591-597
30. Balci, B.; Oturan, N.; Cherrier, R.; Oturan, M. A. Degradation of atrazine in aqueous medium by electrocatalytically generated hydroxyl radicals. A kinetic and mechanistic study Water Res. 2009, 43 (7) 1924-1934
31. Manoj, P.; Prasanthkumar, K. P.; Manoj, V. M.; Aravind, U. K.; Manojkumar, T. K.; Aravindakumar, C. T. Oxidation of substituted triazines by sulfate radical anion (SO4•-) in aqueous medium: A laser flash photolysis and steady state radiolysis study J. Phys. Org. Chem. 2007, 20 (2) 122-129
32. Khan, J. A.; He, X.; Shah, N. S.; Khan, H. M.; Hapeshi, E.; Fatta-Kassinos, D.; Dionysiou, D. D. Kinetic and mechanism investigation on the photochemical degradation of atrazine with activated H2O2, S2O82- and HSO5- Chem. Eng. J. 2014, 252, 393-403
33. Lind, J.; Merényi, G.; Johansson, E.; Brinck, T. Reaction of peroxyl radicals with ozone in water J. Phys. Chem. A 2003, 107 (5) 676-681
34. Sein, M. M.; Golloch, A.; Schmidt, T. C.; von Sonntag, C. No marked kinetic isotope effect in the peroxone (H2O2/D2O2+O3) reaction: Mechanistic consequences ChemPhysChem 2007, 8 (14) 2065-2067
35. Ball, D. L.; Edwards, J. O. The kinetics and mechanism of the decomposition of Caro's acid. I J. Am. Chem. Soc. 1956, 78 (6) 1125-1129
36. Brodovitch, J.-C.; Percival, P. W.; Poteryko, D. Determination of the dissociation constant of D2O2 in D2O by a conventional method and via muonium kinetics Can. J. Chem. 1988, 66 (9) 2410-2411
37. Sehested, K.; Corfitzen, H.; Holcman, J.; Hart, E. J. Decomposition of ozone in aqueous acetic acid solutions (pH 0-4) J. Phys. Chem. 1992, 96 (2) 1005-1009
38. Fischbacher, A.; von Sonntag, J.; von Sonntag, C.; Schmidt, T. C. The •OH radical yield in the H2O2 + O3 (peroxone) reaction Environ. Sci. Technol. 2013, 47 (17) 9959-9964
39. Flyunt, R.; Leitzke, A.; Mark, G.; Mvula, E.; Reisz, E.; Schick, R.; von Sonntag, C. Determination of •OH, O2•-, and hydroperoxide yields in ozone reactions in aqueous solution J. Phys. Chem. B 2003, 107 (30) 7242-7253
40. Buffle, M.-O.; von Gunten, U. Phenols and amine induced HO• generation during the initial phase of natural water ozonation Environ. Sci. Technol. 2006, 40 (9) 3057-3063
41. Canonica, S.; Kohn, T.; Mac, M.; Real, F. J.; Wirz, J.; von Gunten, U. Photosensitizer method to determine rate constants for the reaction of carbonate radical with organic compounds Environ. Sci. Technol. 2005, 39 (23) 9182-9188
42. Grebel, J. E.; Pignatello, J. J.; Mitch, W. A. Effect of halide ions and carbonates on organic contaminant degradation by hydroxyl radical-based advanced oxidation processes in saline waters Environ. Sci. Technol. 2010, 44 (17) 6822-6828
43. Yang, Y.; Pignatello, J. J.; Ma, J.; Mitch, W. A. Comparison of halide impacts on the efficiency of contaminant degradation by sulfate and hydroxyl radical-based advanced oxidation processes (AOPs) Environ. Sci. Technol. 2014, 48 (4) 2344-2351
44. Dogliotti, L.; Hayon, E. Flash photolysis of per[oxydi]sulfate ions in aqueous solutions. The sulfate and ozonide radical anions J. Phys. Chem. 1967, 71 (8) 2511-2516
45. Huie, R. E.; Clifton, C. L. Temperature dependence of the rate constants for reactions of the sulfate radical, SO4-, with anions J. Phys. Chem. 1990, 94 (23) 8561-8567
46. Lutze, H. V.; Kerlin, N.; Schmidt, T. C. Sulfate radical-based water treatment in presence of chloride: Formation of chlorate, inter-conversion of sulfate radicals into hydroxyl radicals and influence of bicarbonate Water Res. 2015, 72, 349-360
47. Staehelin, J.; Hoigne, J. Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reactions Environ. Sci. Technol. 1985, 19 (12) 1206-1213
48. Naumov, S.; von Sonntag, C. Standard Gibbs free energies of reactions of ozone with free radicals in aqueous solution: Quantum-chemical calculations Environ. Sci. Technol. 2011, 45 (21) 9195-9204
49. Westerhoff, P.; Aiken, G.; Amy, G.; Debroux, J. Relationships between the structure of natural organic matter and its reactivity towards molecular ozone and hydroxyl radicals Water Res. 1999, 33 (10) 2265-2276
50. Elovitz, M. S.; von Gunten, U.; Kaiser, H. P. Hydroxyl radical/ozone ratios during ozonation processes. II. The effect of temperature, pH, alkalinity, and DOM properties Ozone: Sci. Eng. 2000, 22 (2) 123-150
51. Das, T. N. Reactivity and role of SO5•- radical in aqueous medium chain oxidation of sulfite to sulfate and atmospheric sulfuric acid generation J. Phys. Chem. A 2001, 105 (40) 9142-9155
52. Matthew, B. M.; Anastasio, C. A chemical probe technique for the determination of reactive halogen species in aqueous solution: Part 1-bromide solutions Atmos. Chem. Phys. 2006, 6, 2423-2437