Electron injection dynamics in high-potential porphyrin photoanodes

Accounts of Chemical Research

Volumn 48, Issue 5, 2015, Pages 1423-1431

  Milot, Rebecca L ^a,b   Schmuttenmaer, Charles A ^a  

^a YALE UNIVERSITY   (United States)

^b UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84929587018     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar500363q     Document Type: Article

References (52)

1. ORegan, B.; Grätzel, M. A Low-Cost, High-Efficiency Solar-Cell Based on Dye-Sensitized Colloidal TiO2 Films Nature 1991, 353, 737-740
2. Hagfeldt, A.; Boschloo, G.; Sun, L. C.; Kloo, L.; Pettersson, H. Dye-Sensitized Solar Cells Chem. Rev. 2010, 110, 6595-6663
3. Kousksou, T.; Bruel, P.; Jamil, A.; El Rhafiki, T.; Zeraouli, Y. Energy Storage: Applications and Challenges Sol. Energy Mater. Sol. Cells 2014, 120, 59-80
4. McConnell, I.; Li, G. H.; Brudvig, G. W. Energy Conversion in Natural and Artificial Photosynthesis Chem. Biol. 2010, 17, 434-447
5. Young, K. J.; Martini, L. A.; Milot, R. L.; Snoeberger, R. C., III; Batista, V. S.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. Light-Driven Water Oxidation for Solar Fuels Coord. Chem. Rev. 2012, 256, 2503-2520
6. Swierk, J. R.; Mallouk, T. E. Design and Development of Photoanodes for Water-Splitting Dye-Sensitized Photoelectrochemical Cells Chem. Soc. Rev. 2013, 42, 2357-2387
7. Duan, L. L.; Tong, L. P.; Xu, Y. H.; Sun, L. C. Visible Light-Driven Water Oxidation-From Molecular Catalysts to Photoelectrochemical Cells Energy Environ. Sci. 2011, 4, 3296-3313
8. Baxter, J. B.; Richter, C.; Schmuttenmaer, C. A. Ultrafast Carrier Dynamics in Nanostructures for Solar Fuels Annu. Rev. Phys. Chem. 2014, 65, 423-447
9. McNamara, W. R.; Snoeberger, R. C.; Li, G.; Schleicher, J. M.; Cady, C. W.; Poyatos, M.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. Acetylacetonate Anchors for Robust Functionalization of TiO2 Nanoparticles with Mn(II)-Terpyridine Complexes J. Am. Chem. Soc. 2008, 130, 14329-14338
10. Milot, R. L.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles J. Phys. Chem. C 2013, 117, 21662-21670
11. Moore, G. F.; Konezny, S. J.; Song, H. E.; Milot, R. L.; Blakemore, J. D.; Lee, M. L.; Batista, V. S.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. Bioinspired High-Potential Porphyrin Photoanodes J. Phys. Chem. C 2012, 116, 4892-4902
12. Moore, G. F.; Blakemore, J. D.; Milot, R. L.; Hull, J. F.; Song, H. E.; Cai, L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. A Visible Light Water-Splitting Cell with a Photoanode Formed by Codeposition of a High-Potential Porphyrin and an Iridium Water-Oxidation Catalyst Energy Environ. Sci. 2011, 4, 2389-2392
13. Martini, L. A.; Moore, G. F.; Milot, R. L.; Cai, L. Z.; Sheehan, S. W.; Schmuttenmaer, C. A.; Brudvig, G. W.; Crabtree, R. H. Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups J. Phys. Chem. C 2013, 117, 14526-14533
14. Negre, C. F. A.; Milot, R. L.; Martini, L. A.; Ding, W.; Crabtree, R. H.; Schmuttenmaer, C. A.; Batista, V. S. Efficiency of Interfacial Electron Transfer from Zn-Porphyrin Dyes into TiO2 Correlated to the Linker Single Molecule Conductance J. Phys. Chem. C 2013, 117, 24462-24470
15. Williams, M. R. C.; Aschaffenburg, D. J.; Ofori-Okai, B. K.; Schmuttenmaer, C. A. Intermolecular Vibrations in Hydrophobic Amino Acid Crystals: Experiments and Calculations J. Phys. Chem. B 2013, 117, 10444-10461
16. Markelz, A. G. Terahertz Dielectric Sensitivity to Biomolecular Structure and Function IEEE J. Sel. Top. Quantum Electron. 2008, 14, 180-190
17. Beard, M. C.; Turner, G. M.; Schmuttenmaer, C. A. Terahertz Spectroscopy J. Phys. Chem. B 2002, 106, 7146-7159
18. Schmuttenmaer, C. A. Exploring Dynamics in the Far-Infrared with Terahertz Spectroscopy Chem. Rev. 2004, 104, 1759-1779
19. Němec, H.; Kužel, P.; Sundström, V. Charge Transport in Nanostructured Materials for Solar Energy Conversion Studied by Time-Resolved Terahertz Spectroscopy J. Photochem. Photobiol., A 2010, 215, 123-139
20. Turner, G. M.; Beard, M. C.; Schmuttenmaer, C. A. Carrier Localization and Cooling in Dye-Sensitized Nanocrystalline Titanium Dioxide J. Phys. Chem. B 2002, 106, 11716-11719
21. Tiwana, P.; Docampo, P.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. Electron Mobility and Injection Dynamics in Mesoporous ZnO, SnO2, and TiO2 Films Used in Dye-Sensitized Solar Cells ACS Nano 2011, 5, 5158-5166
22. Beard, M. C.; Turner, G. M.; Schmuttenmaer, C. A. Subpicosecond Carrier Dynamics in Low-Temperature Grown GaAs as Measured by Time-Resolved Terahertz Spectroscopy J. Appl. Phys. 2001, 90, 5915-5923
23. Ardo, S.; Meyer, G. J. Photodriven Heterogeneous Charge Transfer with Transition-Metal Compounds Anchored to TiO2 Semiconductor Surfaces Chem. Soc. Rev. 2009, 38, 115-164
24. Lloyd-Hughes, J.; Jeon, T. I. A Review of the Terahertz Conductivity of Bulk and Nano-Materials J. Infrared, Millimeter, Terahertz Waves 2012, 33, 871-925
25. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Acedemic Press: New York, 1992.
26. Hodge, J. A.; Hill, M. G.; Gray, H. B. Electrochemistry of Nonplanar Zinc(II) Tetrakis(Pentafluorophenyl)porphyrins Inorg. Chem. 1995, 34, 809-812
27. Yang, S. I.; Seth, J.; Strachan, J. P.; Gentemann, S.; Kim, D.; Holten, D.; Lindsey, J. S.; Bocian, D. F. Ground and Excited State Electronic Properties of Halogenated Tetraarylporphyrins. Tuning the Building Blocks for Porphyrin-Based Photonic Devices J. Porphyrins Phthalocyanines 1999, 3, 117-147
28. Yeon, K. Y.; Jeong, D.; Kim, S. K. Intrinsic Lifetimes of the Soret Bands of the Free-Base Tetraphenylporphine (H2TPP) and Cu(II)TPP in the Condensed Phase Chem. Commun. 2010, 46, 5572-5574
29. Rodriguez, J.; Holten, D. Ultrafast Vibrational Dynamics of a Photoexcited Metalloporphyrin J. Chem. Phys. 1989, 91, 3525-3531
30. Liu, X.; Yeow, E. K. L.; Velate, S.; Steer, R. P. Photophysics and Spectroscopy of the Higher Electronic States of Zinc Metalloporphyrins: A Theoretical and Experimental Study Phys. Chem. Chem. Phys. 2006, 8, 1298-1309
31. Listorti, A.; Lopez-Duarte, I.; Martinez-Diaz, M. V.; Torres, T.; DosSantos, T.; Barnes, P. R. F.; Durrant, J. R. Zn(II) versus Ru(II) Phthalocyanine-Sensitised Solar Cells. A Comparison between Singlet and Triplet Electron Injectors Energy Environ. Sci. 2010, 3, 1573-1579
32. Ai, X.; Anderson, N. A.; Guo, J. C.; Lian, T. Q. Electron Injection Dynamics of Ru Polypyridyl Complexes on SnO2 Nanocrystalline Thin Films J. Phys. Chem. B 2005, 109, 7088-7094
33. Milot, R. L. Interfacial Electron Transfer and Transient Photoconductivity Studied with Terahertz Spectroscopy. Ph.D. Thesis, Yale University, 2014.
34. Gouterman, M.: Optical Spectra and Electronic Structure of Porphyrins. In The Porphyrins; Dolphin, D., Ed.; Academic Press: New York, 1978; Vol. III.
35. Cunningham, K. L.; McNett, K. M.; Pierce, R. A.; Davis, K. A.; Harris, H. H.; Falck, D. M.; McMillin, D. R. EPR Spectra, Luminescence Data, and Radiationless Decay Processes of Copper(II) Porphyrins Inorg. Chem. 1997, 36, 608-613
36. Boschloo, G.; Hagfeldt, A. Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells Acc. Chem. Res. 2009, 42, 1819-1826
37. Haque, S. A.; Palomares, E.; Cho, B. M.; Green, A. N. M.; Hirata, N.; Klug, D. R.; Durrant, J. R. Charge Separation versus Recombination in Dye-Sensitized Nanocrystalline Solar Cells: The Minimization of Kinetic Redundancy J. Am. Chem. Soc. 2005, 127, 3456-3462
38. McNamara, W. R.; Snoeberger, R. C.; Li, G. H.; Richter, C.; Allen, L. J.; Milot, R. L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. Hydroxamate Anchors for Water-Stable Attachment to TiO2 Nanoparticles Energy Environ. Sci. 2009, 2, 1173-1175
39. Pechy, P.; Rotzinger, F. P.; Nazeeruddin, M. K.; Kohle, O.; Zakeeruddin, S. M.; Humphrybaker, R.; Grätzel, M. Preparation of Phosphonated Polypyridyl Ligands to Anchor Transition-Metal Complexes on Oxide Surfaces-Application for the Conversion of Light to Electricity with Nanocrystalline TiO2 Films J. Chem. Soc., Chem. Commun. 1995, 65-66
40. Park, H.; Bae, E.; Lee, J. J.; Park, J.; Choi, W. Effect of the Anchoring Group in Ru-bipyridyl Sensitizers on the Photoelectrochemical Behavior of Dye-Sensitized TiO2 Electrodes: Carboxylate versus Phosphonate Linkages J. Phys. Chem. B 2006, 110, 8740-8749
41. McNamara, W. R.; Milot, R. L.; Song, H. E.; Snoeberger, R. C.; Batista, V. S.; Schmuttenmaer, C. A.; Brudvig, G. W.; Crabtree, R. H. Water-Stable, Hydroxamate Anchors for Functionalization of TiO2 Surfaces with Ultrafast Interfacial Electron Transfer Energy Environ. Sci. 2010, 3, 917-923
42. Brewster, T. P.; Konezny, S. J.; Sheehan, S. W.; Martini, L. A.; Schmuttenmaer, C. A.; Batista, V. S.; Crabtree, R. H. Hydroxamate Anchors for Improved Photoconversion in Dye-Sensitized Solar Cells Inorg. Chem. 2013, 52, 6752-6764
43. Koenigsmann, C.; Ripolles, T. S.; Brennan, B. J.; Negre, C. F. A.; Koepf, M.; Durrell, A. C.; Milot, R. L.; Torre, J. A.; Crabtree, R. H.; Batista, V. S.; Brudvig, G. W.; Bisquert, J.; Schmuttenmaer, C. A. Substitution of a Hydroxamic Acid Anchor into the MK-2 Dye for Enhanced Photovoltaic Performance and Water Stability in a DSSC Phys. Chem. Chem. Phys. 2014, 16, 16629-16641
44. Heimer, T. A.; Darcangelis, S. T.; Farzad, F.; Stipkala, J. M.; Meyer, G. J. An Acetylacetonate-Based Semiconductor-Sensitizer Linkage Inorg. Chem. 1996, 35, 5319-5324
45. Altobello, S.; Bignozzi, C. A.; Caramori, S.; Larramona, G.; Quici, S.; Marzanni, G.; Lakhmiri, R. Sensitization of TiO2 with Ruthenium Complexes Containing Boronic Acid Functions J. Photochem. Photobiol., A 2004, 166, 91-98
46. Brennan, B. J.; Portoles, M. J. L.; Liddell, P. A.; Moore, T. A.; Moore, A. L.; Gust, D. Comparison of Silatrane, Phosphonic Acid, and Carboxylic Acid Functional Groups for Attachment of Porphyrin Sensitizers to TiO2 in Photoelectrochemical Cells Phys. Chem. Chem. Phys. 2013, 15, 16605-16614
47. Abuabara, S. G.; Cady, C. W.; Baxter, J. B.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. Ultrafast Photooxidation of Mn(II)-Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles J. Phys. Chem. C 2007, 111, 11982-11990
48. Subbaiyan, N. K.; Wijesinghe, C. A.; DSouza, F. Supramolecular Solar Cells: Surface Modification of Nanocrytalline TiO2 with Coordinating Ligands To Immobilize Sensitizers and Dyads via Metal-Ligand Coordination for Enhanced Photocurrent Generation J. Am. Chem. Soc. 2009, 131, 14646-14647
49. Brumbach, M. T.; Boal, A. K.; Wheeler, D. R. Metalloporphyrin Assemblies on Pyridine-Functionalized Titanium Dioxide Langmuir 2009, 25, 10685-10690
50. Nazeeruddin, M. K.; Humphry-Baker, R.; Grätzel, M.; Murrer, B. A. Efficient Near IR Sensitization of Nanocrystalline TiO2 Films by Ruthenium Phthalocyanines Chem. Commun. 1998, 719-720
51. Nappa, M.; Valentine, J. S. Influence of Axial Ligands on Metalloporphyrin Visible Absorption Spectra-Complexes of Tetraphenylporphinatozinc J. Am. Chem. Soc. 1978, 100, 5075-5080
52. Hintermair, U.; Sheehan, S. W.; Parent, A. R.; Ess, D. H.; Richens, D. T.; Vaccaro, P. H.; Brudvig, G. W.; Crabtree, R. H. Precursor Transformation during Molecular Oxidation Catalysis with Organometallic Iridium Complexes J. Am. Chem. Soc. 2013, 135, 10837-10851