Technical Note: A fully automated purge and trap GC-MS system for quantification of volatile organic compound (VOC) fluxes between the ocean and atmosphere

Ocean Science

Volumn 11, Issue 2, 2015, Pages 313-321

  Andrews, S J ^a   Hackenberg, S C ^a   Carpenter, L J ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AIR-SEA INTERACTION; DESORPTION; DIURNAL ACTIVITY; FLUX MEASUREMENT; HALOGEN; TEMPERATURE EFFECT; VOLATILE ORGANIC COMPOUND;

PACIFIC OCEAN; PACIFIC OCEAN (TROPICAL);

EID: 84928817977     PISSN: 18120784     EISSN: 18120792     Source Type: Journal    
DOI: 10.5194/os-11-313-2015     Document Type: Article

References (48)

1. Asare, N. K., Turley, C. M., Nightingale, P. D., and Nimmo, M.: Microbially-mediated methyl iodide production in water samples from an estuarine system, J. Environ., 1, 75-83, 2012.
2. Beale, R., Liss, P. S., Dixon, J. L., and Nightingale, P. D.: Quantification of oxygenated volatile organic compounds in seawater by membrane inlet-proton transfer reaction/mass spectrometry, Anal. Chim. Acta, 706, 128-134, doi:10.1016/j.aca.2011.08.023, 2011.
3. Bouteiller, A. L., Blanchot, J., and Rodier, M.: Size distribution patterns of phytoplankton in the western Pacific: towards a generalization for the tropical open ocean, Deep-Sea Res. Pt. A, 39, 805-823, doi:10.1016/0198-0149(92)90123-B, 1992.
4. Butler, J. H., King, D. B., Lobert, J. M., Montzka, S. A., Yvon-Lewis, S. A., Hall, B. D., Warwick, N. J., Mondeel, D. J., Aydin, M., and Elkins, J.W.: Oceanic distributions and emissions of short-lived halocarbons, Global Biogeochem. Cy., 21, GB1023, doi:10.1029/2006GB002732, 2007.
5. Carpenter, L., Malin, G., Liss, P., and Kupper, F.: Novel biogenic iodine-containing trihalomethanes and other short-lived halocarbons in the coastal East Atlantic, Global Biogeochem. Cy., 14, 1191-1204, 2000.
6. Carpenter, L. J. and Liss, P. S.: On temperate sources of bromoform and other reactive organic bromine gases, J. Geophys. Res.-Atmos., 105, 20539-20547, 2000.
7. Chance, R., Baker, A. R., Küpper, F. C., Hughes, C., Kloareg, B., and Malin, G.: Release and transformations of inorganic iodine by marine macroalgae, Estuar. Coast. Shelf S., 82, 406-414, 2009.
8. Davis, D., Chen, G., Kasibhatla, P., Jefferson, A., Tanner, D., Eisele, F., Lenschow, D., Neff, W., and Berresheim, H.: DMS oxidation in the Antarctic marine boundary layer: Comparison of model simulations and held observations of DMS, DMSO, DMSO2, H2SO4.g/, MSA.g/, and MSA.p/, J. Geophys. Res.Atmos., 103, 1657-1678, 1998.
9. DEFRA: The Water Supply (Water Quality) Regulations 2000, available at: http://dwi.defra.gov.uk/stakeholders/guidance-and-codes-of-practice/WS(WQ)-regs-england2010.pdf (last access: 11 December 2014), 2000.
10. Goodwin, K., North, W., and Lidstrom, M.: Production of bromoform and dibromomethane by giant kelp: factors affecting release and comparison to anthropogenic bromine sources, Limnol. Oceanogr., 42, 1725-1734, 1997.
11. Groszko, W. and Moore, R.: A semipermeable membrane equilibrator for halomethanes in seawater, Chemosphere, 36, 3083-3092, doi:10.1016/S0045-6535(98)00019-8, 1998.
12. Happell, J. and Wallace, D.: Methyl iodide in the Greenland/ Norwegian Seas and the tropical Atlantic Ocean: evidence for photochemical production, Geophys. Res. Lett., 23, 2105-2108, 1996.
13. Hughes, C., Malin, G., Turley, C., Keely, B., Nightingale, P., and Liss, P.: The production of volatile iodocarbons by biogenic marine aggregates, Limnol. Oceanogr., 53, 867-872, 2008.
14. Johnson, J. E.: Evaluation of a seawater equilibrator for shipboard analysis of dissolved oceanic trace gases, Anal. Chim. Acta, 395, 119-132, doi:10.1016/S0003-2670(99)00361-X, 1999.
15. Jones, C. and Carpenter, L.: Solar photolysis of CH2I2, CH2ICl, and CH2IBr in water, saltwater, and seawater, Environ. Sci. Technol., 39, 6130-6137, 2005.
16. Jones, C., Hornsby, K., Sommariva, R., Dunk, R., Von Glasow, R., McFiggans, G., and Carpenter, L.: Quantifying the contribution of marine organic gases to atmospheric iodine, Geophys. Res. Lett., 37, L18804, doi:10.1029/2010GL043990, 2010.
17. Jones, C. E., Hornsby, K. E., Dunk, R. M., Leigh, R. J., and Carpenter, L. J.: Coastal measurements of short-lived reactive iodocarbons and bromocarbons at Roscoff, Brittany during the RHaMBLe campaign, Atmos. Chem. Phys., 9, 8757-8769, doi:10.5194/acp-9-8757-2009, 2009.
18. Jones, C. E., Andrews, S. J., Carpenter, L. J., Hogan, C., Hopkins, F. E., Laube, J. C., Robinson, A. D., Spain, T. G., Archer, S. D., Harris, N. R. P., Nightingale, P. D., O'Doherty, S. J., Oram, D. E., Pyle, J. A., Butler, J. H., and Hall, B. D.: Results from the first national UK inter-laboratory calibration for very short-lived halocarbons, Atmos. Meas. Tech., 4, 865-874, doi:10.5194/amt-4-865-2011, 2011.
19. Kameyama, S., Tanimoto, H., Inomata, S., Tsunogai, U., Ooki, A., Takeda, S., Obata, H., Tsuda, A., and Uematsu, M.: Highresolution measurement of multiple volatile organic compounds dissolved in seawater using equilibrator inlet-proton transfer reaction-mass spectrometry (EI-PTR-MS), Mar. Chem., 122, 59-73, doi:10.1016/j.marchem.2010.08.003, 2010.
20. Kameyama, S., Yoshida, S., Tanimoto, H., Inomata, S., Suzuki, K., and Yoshikawa-Inoue, H.: High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010-2011, J. Oceanogr., 70, 225-239, 2014.
21. Kiene, R. P. and Slezak, D.: Low dissolved DMSP concentrations in seawater revealed by small-volume gravity filtration and dialysis sampling, Limnol. Oceanogr.-Meth., 4, 80-95, 2006.
22. Ledyard, K. M. and Dacey, J. W.: Dimethylsulfide production from dimethylsulfoniopropionate by a marine bacterium, Mar. Ecol.-Prog. Ser., 110, 95-103, 1994.
23. Leedham, E. C., Hughes, C., Keng, F. S. L., Phang, S.-M., Malin, G., and Sturges, W. T.: Emission of atmospherically significant halocarbons by naturally occurring and farmed tropical macroalgae, Biogeosciences, 10, 3615-3633, doi:10.5194/bg-10-3615-2013, 2013.
24. Leifer, I., Patro, R. K., and Bowyer, P.: A study on the temperature variation of rise velocity for large clean bubbles, J. Atmos. Ocean. Tech., 17, 1392-1402, 2000.
25. Lidster, R. T., Hamilton, J. F., Lee, J. D., Lewis, A. C., Hopkins, J. R., Punjabi, S., Rickard, A. R., and Young, J. C.: The impact of monoaromatic hydrocarbons on OH reactivity in the coastal UK boundary layer and free troposphere, Atmos. Chem. Phys., 14, 6677-6693, doi:10.5194/acp-14-6677-2014, 2014.
26. Loose, B., Stute, M., Alexander, P., and Smethie, W. M.: Design and deployment of a portable membrane equilibrator for sampling aqueous dissolved gases,Water Resour. Res., 45, W00D34, doi:10.1029/2008WR006969, 2009.
27. McFiggans, G., Bale, C. S. E., Ball, S. M., Beames, J. M., Bloss,W. J., Carpenter, L. J., Dorsey, J., Dunk, R., Flynn, M. J., Furneaux, K. L., Gallagher, M. W., Heard, D. E., Hollingsworth, A. M., Hornsby, K., Ingham, T., Jones, C. E., Jones, R. L., Kramer, L. J., Langridge, J. M., Leblanc, C., LeCrane, J.-P., Lee, J. D., Leigh, R. J., Longley, I., Mahajan, A. S., Monks, P. S., Oetjen, H., Orr-Ewing, A. J., Plane, J. M. C., Potin, P., Shillings, A. J. L., Thomas, F., von Glasow, R., Wada, R., Whalley, L. K., and Whitehead, J. D.: Iodine-mediated coastal particle formation: an overview of the Reactive Halogens in the Marine BoundaryLayer (RHaMBLe) Roscoff coastal study, Atmos. Chem. Phys., 10, 2975-2999, doi:10.5194/acp-10-2975-2010, 2010.
28. Montzka, S., Reimann, S., O'Doherty, S., Engel, A., Krüger, K., and Sturges, W.: Ozone-depleting substances (ODSs) and related chemicals, World Meteorological Organization, Geneva, Switzerland, 1-112, 2011.
29. Ordöñez, C., Lamarque, J.-F., Tilmes, S., Kinnison, D. E., Atlas, E. L., Blake, D. R., Sousa Santos, G., Brasseur, G., and Saiz-Lopez, A.: Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423-1447, doi:10.5194/acp-12-1423-2012, 2012.
30. Quack, B., Atlas, E., Petrick, G., Stroud, V., Schauffler, S., and Wallace, D.: Oceanic bromoform sources for the tropical atmosphere, Geophys. Res. Lett, 31, L23S05, doi:10.1029/2004GL020597, 2004.
31. Quack, B., Peeken, I., Petrick, G., and Nachtigall, K.: Oceanic distribution and sources of bromoform and dibromomethane in the Mauritanian upwelling, J. Geophys. Res.-Oceans, 112, C10006, doi:10.1029/2006JC003803, 2007.
32. Raimund, S., Quack, B., Bozec, Y., Vernet, M., Rossi, V., Garçon, V., Morel, Y., and Morin, P.: Sources of short-lived bromocarbons in the Iberian upwelling system, Biogeosciences, 8, 1551-1564, doi:10.5194/bg-8-1551-2011, 2011.
33. Read, K. A., Mahajan, A. S., Carpenter, L. J., Evans, M. J., Faria, B. V. E., Heard, D. E., Hopkins, J. R., Lee, J. D., Moller, S. J., Lewis, A. C., Mendes, L., McQuaid, J. B., Oetjen, H., Saiz-Lopez, A., Pilling, M. J., and Plane, J. M. C.: Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean, Nature, 453, 1232-1235, 2008.
34. Richter, U. and Wallace, D.: Production of methyl iodide in the tropical Atlantic Ocean, Geophys. Res. Lett., 31, L23S03, doi:10.1029/2004GL020779, 2004.
35. Saiz-Lopez, A., Lamarque, J.-F., Kinnison, D. E., Tilmes, S., Ordöñez, C., Orlando, J. J., Conley, A. J., Plane, J. M. C., Mahajan, A. S., Sousa Santos, G., Atlas, E. L., Blake, D. R., Sander, S. P., Schauffler, S., Thompson, A. M., and Brasseur, G.: Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere, Atmos. Chem. Phys., 12, 3939-3949, doi:10.5194/acp-12-3939-2012, 2012.
36. Saltzman, E. S., De Bruyn, W. J., Lawler, M. J., Marandino, C. A., and McCormick, C. A.: A chemical ionization mass spectrometer for continuous underway shipboard analysis of dimethylsulfide in near-surface seawater, Ocean Sci., 5, 537-546, doi:10.5194/os-5-537-2009, 2009.
37. Sander, R.: Compilation of Henry's law constants for inorganic and organic species of potential importance in environmental chemistry, Max-Planck Institute of Chemistry, 1999.
38. Santos, G. S. and Rast, S.: A global model study of natural bromine sources and the effects on tropospheric chemistry using MOZART4, J. Atmos. Chem., 70, 69-89, doi:10.1007/s10874-013-9252-y, 2013.
39. Schall, C., Laturnus, F., and Heumann, K.: Biogenic volatile organoiodine and organobromine compounds released from polar macroalgae, Chemosphere, 28, 1315-1324, 1994.
40. Sturges, W., Sullivan, C., Schnell, R., Heidt, L., and Pollock, W.: Bromoalkane production by Antarctic ice algae, Tellus B, 45, 120-126, 1993.
41. Thompson, T., Fawell, J., Kunikane, S., Jackson, D., Appleyard, S., Callan, P., Bartram, J., and Kingston, P.: Chemical Safety of Drinking-Water, World Health Organization, 2007.
42. Tokarczyk, R. and Moore, R.: Production of volatile organohalogens by phytoplankton cultures, Geophys. Res. Lett., 21, 285-288, 1994.
43. US EPA: Title 40 -Protection of Environment, Code of Federal Regulations (annual edition), 2010.
44. von Glasow, R., von Kuhlmann, R., Lawrence, M. G., Platt, U., and Crutzen, P. J.: Impact of reactive bromine chemistry in the troposphere, Atmos. Chem. Phys., 4, 2481-2497, doi:10.5194/acp-4-2481-2004, 2004.
45. Yang, M., Beale, R., Liss, P., Johnson, M., Blomquist, B., and Nightingale, P.: Air-sea fluxes of oxygenated volatile organic compounds across the Atlantic Ocean, Atmos. Chem. Phys., 14, 7499-7517, doi:10.5194/acp-14-7499-2014, 2014.
46. Yang, X., Cox, R., Warwick, N., Pyle, J., Carver, G., O'Connor, F., and Savage, N.: Tropospheric bromine chemistry and its impacts on ozone: a model study, J. Geophys. Res., 110, D23311, doi:10.1029/2005JD006244, 2005.
47. Zuend, A., Marcolli, C., Luo, B. P., and Peter, T.: A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients, Atmos. Chem. Phys., 8, 4559-4593, doi:10.5194/acp-8-4559-2008, 2008.
48. Zuend, A., Marcolli, C., Booth, A. M., Lienhard, D. M., Soonsin, V., Krieger, U. K., Topping, D. O., McFiggans, G., Peter, T., and Seinfeld, J. H.: New and extended parameterization of the thermodynamic model AIOMFAC: calculation of activity coefficients for organic-inorganic mixtures containing carboxyl, hydroxyl, carbonyl, ether, ester, alkenyl, alkyl, and aromatic functional groups, Atmos. Chem. Phys., 11, 9155-9206, doi:10.5194/acp-11-9155-2011, 2011.