Airborne measurements of organosulfates over the continental U.S.

Journal of Geophysical Research

Volumn 120, Issue 7, 2015, Pages 2990-3005

  Liao, Jin ^a,b   Froyd, Karl D ^a,b   Murphy, Daniel M ^a   Keutsch, Frank N ^c,d   Yu, Ge ^c   Wennberg, Paul O ^e,f   St Clair, Jason M ^e   Crounse, John D ^e   Wisthaler, Armin ^g,h   Mikoviny, Tomas ^g,h   Jimenez, Jose L ^b   Campuzano Jost, Pedro ^b   Day, Douglas A ^b   Hu, Weiwei ^b   Ryerson, Thomas B ^a   Pollack, Ilana B ^a,b   Peischl, Jeff ^a,b   Anderson, Bruce E ⁱ   Ziemba, Luke D ⁱ   Blake, Donald R ^j   Meinardi, Simone ^j   Diskin, Glenn ⁱ   more..

^a EARTH SYSTEM RESEARCH LABORATORY   (United States)

^b UNIVERSITY OF COLORADO   (United States)

^c UNIVERSITY OF WISCONSIN MADISON   (United States)

^d HARVARD UNIVERSITY   (United States)

^e CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^f CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^g UNIVERSITY OF INNSBRUCK   (Austria)

^h UNIVERSITY OF OSLO   (Norway)

ⁱ NASA LANGLEY RESEARCH CENTER   (United States)

^j UNIVERSITY OF CALIFORNIA   (United States)

more..

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL PROPERTY; AIRBORNE SENSING; ANTHROPOGENIC SOURCE; ENVIRONMENTAL IMPACT; NOAA SATELLITE; RELATIVE HUMIDITY; SPATIAL DISTRIBUTION; SULFATE; SULFUR DIOXIDE;

UNITED STATES;

EID: 84928622720     PISSN: 01480227     EISSN: 21562202     Source Type: Journal    
DOI: 10.1002/2014JD022378     Document Type: Article

References (77)

1. Bacher, C., G. S. Tyndall, and J. J. Orlando (2001), The atmospheric chemistry of glycolaldehyde, J. Atmos. Chem., 39(2), 171-189, doi:10.1023/A:1010689706869.
2. Bates, K. H., J. D. Crounse, J. M. St. Clair, N. B. Bennett, T. B. Nguyen, J. H. Seinfeld, B. M. Stoltz, and P. O. Wennberg (2014), Gas phase production and loss of isoprene epoxydiols, J. Phys. Chem. A, 118(7), 1238-1246, doi:10.1021/jp4107958.
3. Carn, S. A., et al. (2011), In situ measurements of tropospheric volcanic plumes in Ecuador and Colombia during TC4, J. Geophys. Res., 116, D00J24, doi:10.1029/2010JD014718.
4. Chan, M. N., et al. (2010), Characterization and quantification of isoprene-derived epoxydiols in ambient aerosol in the southeastern United States, Environ. Sci. Technol., 44(12), 4590-4596, doi:10.1021/Es100596b.
5. Charlson, R. J., S. E. Schwartz, J. M. Hales, R. D. Cess, J. A. Coakley, J. E. Hansen, and D. J. Hofmann (1992), Climate forcing by anthropogenic aerosols, Science, 255(5043), 423-430, doi:10.1126/science.255.5043.423.
6. Chebbi, A., and P. Carlier (1996), Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review, Atmos. Environ., 30(24), 4233-4249, doi:10.1016/1352-2310(96)00102-1.
7. Christian, T. J., B. Kleiss, R. J. Yokelson, R. Holzinger, P. J. Crutzen, W. M. Hao, T. Shirai, and D. R. Blake (2004), Comprehensive laboratory measurements of biomass-burning emissions: 2. First intercomparison of open-path FTIR, PTR-MS, and GC- MS/FID/ECD, J. Geophys. Res., 109, D02311, doi:10.1029/2003JD003874.
8. Clegg, S. L., P. Brimblecombe, and A. S. Wexler (1998), Thermodynamic model of the system H+_NH4+_SO42-NO3-H2O at tropospheric temperatures, J. Phys. Chem. A, 102(12), 2137-2154.
9. Colman, J. J., A. L. Swanson, S. Meinardi, B. C. Sive, D. R. Blake, and F. S. Rowland (2001), Description of the analysis of a wide range of volatile organic compounds in whole air samples collected during PEM-tropics A and B, Anal. Chem., 73(15), 3723-3731, doi:10.1021/Ac010027g.
10. Darer, A. I., N. C. Cole-Filipiak, A. E. O’Connor, and M. J. Elrod (2011), Formation and stability of atmospherically relevant isoprene-derived organosulfates and organonitrates, Environ. Sci. Technol., 45(5), 1895-1902, doi:10.1021/Es103797z.
11. DeCarlo, P. F., et al. (2006), Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer, Anal. Chem., 78(24), 8281-8289, doi:10.1021/Ac061249n.
12. De Gouw, J. A., et al. (2009), Airborne measurements of ethene from industrial sources using laser photo-acoustic spectroscopy, Environ. Sci. Technol., 43(7), 2437-2442, doi:10.1021/Es802701a.
13. Eddingsaas, N. C., D. G. VanderVelde, and P. O. Wennberg (2010), Kinetics and products of the acid-catalyzed ring-opening of atmospherically relevant butyl epoxy alcohols, J. Phys. Chem. A, 114(31), 8106-8113, doi:10.1021/Jp103907c.
14. Ehn, M., et al. (2010), Composition and temporal behavior of ambient ions in the boreal forest, Atmos. Chem. Phys., 10(17), 8513-8530, doi:10.5194/acp-10-8513-2010.
15. Fratzke, A. R., and P. J. Reilly (1986), Kinetic-analysis of the disproportionation of aqueous glyoxal, Int. J. Chem. Kinet., 18(7), 757-773, doi:10.1002/kin.550180704.
16. Froyd, K. D., D. M. Murphy, T. J. Sanford, D. S. Thomson, J. C. Wilson, L. Pfister, and L. Lait (2009), Aerosol composition of the tropical upper troposphere, Atmos. Chem. Phys., 9(13), 4363-4385.
17. Froyd, K. D., S. M. Murphy, D. M. Murphy, J. A. de Gouw, N. C. Eddingsaas, and P. O. Wennberg (2010), Contribution of isoprene-derived organosulfates to free tropospheric aerosol mass, Proc. Natl. Acad. Sci. U.S.A., 107(50), 21,360-21,365, doi:10.1073/pnas.1012561107.
18. Galloway, M. M., P. S. Chhabra, A. W. H. Chan, J. D. Surratt, R. C. Flagan, J. H. Seinfeld, and F. N. Keutsch (2009), Glyoxal uptake on ammonium sulphate seed aerosol: Reaction products and reversibility of uptake under dark and irradiated conditions, Atmos. Chem. Phys., 9(10), 3331-3345.
19. x conditions, Atmos. Chem. Phys., 11(21), 10,779-10,790, doi:10.5194/acp-11-10779-2011.
20. Gaston, G. J., T. P. Riedel, Z. Zhang, A. Gold, J. D. Surratt, and J. A. Thornton (2014), Reactive uptake of an isoprene-derived epoxydiol to submicron aerosol particles, Environ. Sci. Technol., 48(19), 11,178-11,186, doi:10.1021/es5034266.
21. Goldstein, A. H., S. M. Fan, M. L. Goulden, J. W. Munger, and S. C. Wofsy (1996), Emissions of ethene, propene, and 1-butene by a midlatitude forest, J. Geophys. Res., 101(D4), 9149-9157, doi:10.1029/96JD00334.
22. Gomez-Gonzalez, Y., et al. (2008), Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(_) electrospray ionization mass spectrometry, J. Mass Spectrom., 43(3), 371-382, doi:10.1002/Jms.1329.
23. Guo, H., et al. (2014), Particle water and pH in the southeastern United States, Atmos. Chem. Phys. Discuss., 14, 27,143-27,193, doi:10.5194/ acpd-14-27143-2014.
24. Hallquist, M., et al. (2009), The formation, properties and impact of secondary organic aerosol: Current and emerging issues, Atmos. Chem. Phys., 9(14), 5155-5236.
25. Hansel, A., A. Jordan, C. Warneke, R. Holzinger, A. Wisthaler, and W. Lindinger (1999), Proton-transfer-reaction mass spectrometry (PTR-MS):On-line monitoring of volatile organic compounds at volume mixing ratios of a few pptv, Plasma Sources Sci. Technol., 8(2), 332-336, doi:10.1088/0963-0252/8/2/314.
26. Hatch, L. E., J. M. Creamean, A. P. Ault, J. D. Surratt, M. N. Chan, J. H. Seinfeld, E. S. Edgerton, Y. X. Su, and K. A. Prather (2011), Measurements of isoprene-derived organosulfates in ambient aerosols by aerosol time-of-flight mass spectrometry-Part 2: Temporal variability and formation mechanisms, Environ. Sci. Technol., 45(20), 8648-8655, doi:10.1021/Es2011836.
27. Heald, C. L., D. J. Jacob, R. J. Park, L. M. Russell, B. J. Huebert, J. H. Seinfeld, H. Liao, and R. J. Weber (2005), A large organic aerosol source in the free troposphere missing from current models, Geophys. Res. Lett., 32, L18809, doi:10.1029/2005GL023831.
28. Hennigan, C. J., J. Izumi, A. P. Sullivan, R. J. Weber, and A. Nenes (2014), A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles, Atmos. Chem. Phys. Discuss., 14, 27,579-27,618, doi:10.5194/acpd-14-27579-2014.
29. Iinuma, Y., C. Muller, T. Berndt, O. Boge, M. Claeys, and H. Herrmann (2007), Evidence for the existence of organosulfates from beta-pinene ozonolysis in ambient secondary organic aerosol, Environ. Sci. Technol., 41(19), 6678-6683, doi:10.1021/Es070938t.
30. Jacobs, M. I., A. I. Darer, and M. J. Elrod (2013), Rate constants and products of the OH reaction with isoprene-derived epoxides, Environ. Sci. Technol., 47(22), 12,868-12,876, doi:10.1021/Es403340g.
31. Jacobs, M. I., W. J. Burke, and M. J. Elrod (2014), Kinetics of the reactions of isoprene-derived hydroxynitrates: Gas phase epoxide formation and solution phase hydrolysis, Atmos. Chem. Phys., 14, 8933-8946, doi:10.5194/acp-14-8933-2014.
32. Kundu, S., T. A. Quraishi, G. Yu, C. Suarez, F. N. Keutsch, and E. A. Stone (2013), Evidence and quantitation of aromatic organosulfates in ambient aerosols in Lahore, Pakistan, Atmos. Chem. Phys., 13(9), 4865-4875, doi:10.5194/acp-13-4865-2013.
33. Lim, H. J., A. G. Carlton, and B. J. Turpin (2005), Isoprene forms secondary organic aerosol through cloud processing: Model simulations, Environ. Sci. Technol., 39(12), 4441-4446, doi:10.1021/Es048039h.
34. 3 levels on isoprenederived secondary organic aerosol formation using conditional sampling approaches, Atmos. Chem. Phys., 13(16), 8457-8470, doi:10.5194/acp-13-8457-2013.
35. McNaughton, C. S., et al. (2007), Results from the DC-8 Inlet Characterization Experiment (DICE): Airborne versus surface sampling of mineral dust and sea salt aerosols, Aerosol Sci. Technol., 41(2), 136-159, doi:10.1080/02786820601118406.
36. McNeill, V. F., J. L. Woo, D. D. Kim, A. N. Schwier, N. J. Wannell, A. J. Sumner, and J. M. Barakat (2012), Aqueous-phase secondary organic aerosol and organosulfate formation in atmospheric aerosols: A modeling study, Environ. Sci. Technol., 46(15), 8075-8081, doi:10.1021/Es3002986.
37. Murphy, D. M. (2007), The design of single particle laser mass spectrometers, Mass Spectrom. Rev., 26(2), 150-165, doi:10.1002/Mas.20113.
38. Murphy, D. M., and D. S. Thomson (1995), Laser ionization mass-spectroscopy of single aerosol-particles, Aerosol Sci. Technol., 22(3), 237-249, doi:10.1080/02786829408959743.
39. Murphy, D. M., D. J. Cziczo, K. D. Froyd, P. K. Hudson, B. M. Matthew, A. M. Middlebrook, R. E. Peltier, A. Sullivan, D. S. Thomson, and R. J. Weber (2006), Single-particle mass spectrometry of tropospheric aerosol particles, J. Geophys. Res., 111, D23S32, doi:10.1029/2006JD007340.
40. Murphy, D. M., D. J. Cziczo, P. K. Hudson, and D. S. Thomson (2007), Carbonaceous material in aerosol particles in the lower stratosphere and tropopause region, J. Geophys. Res., 112, D04203, doi:10.1029/2006JD007297.
41. Nguyen, T. B., M. M. Coggon, R. C. Flagan, and J. H. Seinfeld (2013), Reactive uptake and photo-fenton oxidation of glycolaldehyde in aerosol liquid water, Environ. Sci. Technol., 47(9), 4307-4316, doi:10.1021/Es400538j.
42. Nguyen, T. B., M. M. Coggon, K. H. Bates, X. Zhang, R. H. Schwantes, K. A. Schilling, C. L. Loza, R. C. Flagan, P. O. Wennberg, and J. H. Seinfeld (2014), Organic aerosol formation from the reactive uptake of isoprene epoxydiols (IEPOX) onto non-acidified inorganic seeds, Atmos. Chem. Phys., 14(7), 3497-3510, doi:10.5194/acp-14-3497-2014.
43. Nozière, B., S. Ekstrom, T. Alsberg, and S. Holmstrom (2010), Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols, Geophys. Res. Lett., 37, L05806, doi:10.1029/2009GL041683.
44. Olson, C. N., M. M. Galloway, G. Yu, C. J. Hedman, M. R. Lockett, T. Yoon, E. A. Stone, L. M. Smith, and F. N. Keutsch (2011), Hydroxycarboxylic acid-derived organosulfates: Synthesis, stability, and quantification in ambient aerosol, Environ. Sci. Technol., 45(15), 6468-6474, doi:10.1021/Es201039p.
45. Ortiz-Montalvo, D. L., Y. B. Lim, M. J. Perri, S. P. Seitzinger, and B. J. Turpin (2012), Volatility and yield of glycolaldehyde SOA formed through aqueous photochemistry and droplet evaporation, Aerosol Sci. Technol., 46(9), 1002-1014, doi:10.1080/02786826.2012.686676.
46. Paulot, F., J. D. Crounse, H. G. Kjaergaard, J. H. Kroll, J. H. Seinfeld, and P. O. Wennberg (2009a), Isoprene photooxidation: New insights into the production of acids and organic nitrates, Atmos. Chem. Phys., 9(4), 1479-1501.
47. Paulot, F., J. D. Crounse, H. G. Kjaergaard, A. Kurten, J. M. St. Clair, J. H. Seinfeld, and P. O. Wennberg (2009b), Unexpected epoxide formation in the gas-phase photooxidation of isoprene, Science, 325(5941), 730-733, doi:10.1126/science.1172910.
48. Paulot, F., et al. (2011), Importance of secondary sources in the atmospheric budgets of formic and acetic acids, Atmos. Chem. Phys., 11(5), 1989-2013, doi:10.5194/acp-11-1989-2011.
49. Perri, M. J., S. Seitzinger, and B. J. Turpin (2009), Secondary organic aerosol production from aqueous photooxidation of glycolaldehyde:Laboratory experiments, Atmos. Environ., 43(8), 1487-1497, doi:10.1016/j.atmosenv.2008.11.037.
50. Pierce, T., C. Geron, L. Bender, R. Dennis, G. Tonnesen, and A. Guenther (1998), Influence of increased isoprene emissions on regional ozone modeling, J. Geophys. Res., 103(D19), 25,611-25,629, doi:10.1029/98JD01804.
51. Pope, C. A., R. T. Burnett, M. J. Thun, E. E. Calle, D. Krewski, K. Ito, and G. D. Thurston (2002), Lung cancer, cardiopulmonary mortality, and long-term exposure to fine particulate air pollution, JAMA, J. Am. Med. Assoc., 287(9), 1132-1141, doi:10.1001/jama.287.9.1132.
52. Pratt, K. A., M. N. Fiddler, P. B. Shepson, A. G. Carlton, and J. D. Surratt (2013), Organosulfates in cloud water above the Ozarks’ isoprene source region, Atmos. Environ., 77, 231-238, doi:10.1016/j.atmosenv.2013.05.011.
53. Pye, H. O. T., et al. (2013), Epoxide pathways improve model predictions of isoprene markers and reveal key role of acidity in aerosol formation, Environ. Sci. Technol., 47(19), 11,056-11,064, doi:10.1021/Es402106h.
54. Rudzinski, K. J., L. Gmachowski, and I. Kuznietsova (2009), Reactions of isoprene and sulphoxy radical-anions - a possible source of atmospheric organosulphites and organosulphates, Atmos. Chem. Phys., 9(6), 2129-2140.
55. Ryerson, T. B., et al. (2001), Observations of ozone formation in power plant plumes and implications for ozone control strategies, Science, 292(5517), 719-723, doi:10.1126/science.1058113.
56. Schindelka, J., Y. Iinuma, D. Hoffmann, and H. Herrmann (2013), Sulfate radical-initiated formation of isoprene-derived organosulfates in atmospheric aerosols, Faraday Discuss., 165, 237-259, doi:10.1039/C3fd00042g.
57. Scott, C. E., et al. (2014), The direct and indirect radiative effects of biogenic secondary organic aerosol, Atmos. Chem. Phys., 14(1), 447-470, doi:10.5194/acp-14-447-2014.
58. Shalamzari, M. S., O. Ryabtsova, A. Kahnt, R. Vermeylen, M. F. Herent, J. Quetin-Leclercq, P. Van der Veken, W. Maenhaut, and M. Claeys (2013), Mass spectrometric characterization of organosulfates related to secondary organic aerosol from isoprene, Rapid Commun. Mass Spectrom., 27(7), 784-794, doi:10.1002/Rcm.6511.
59. Smith, J. N., M. J. Dunn, T. M. VanReken, K. Iida, M. R. Stolzenburg, P. H. McMurry, and L. G. Huey (2008), Chemical composition of atmospheric nanoparticles formed from nucleation in Tecamac, Mexico: Evidence for an important role for organic species in nanoparticle growth, Geophys. Res. Lett., 35, L04808, doi:10.1029/2007GL032523.
60. Spaulding, R. S., G. W. Schade, A. H. Goldstein, and M. J. Charles (2003), Characterization of secondary atmospheric photooxidation products:Evidence for biogenic and anthropogenic sources, J. Geophys. Res., 108(D8), 4247, doi:10.1029/2002JD002478.
61. St. Clair, J. M., D. C. McCabe, J. D. Crounse, U. Steiner, and P. O. Wennberg (2010), Chemical ionization tandem mass spectrometer for the in situ measurement of methyl hydrogen peroxide, Rev. Sci. Instrum., 81, doi:10.1063/1.3480552.
62. Surratt, J. D., et al. (2007), Evidence for organosulfates in secondary organic aerosol, Environ. Sci. Technol., 41(2), 517-527, doi:10.1021/Es062081q.
63. Surratt, J. D., et al. (2008), Organosulfate formation in biogenic secondary organic aerosol, J. Phys. Chem. A, 112(36), 8345-8378, doi:10.1021/Jp802310p.
64. Surratt, J. D., A.W. H. Chan, N. C. Eddingsaas, M. N. Chan, C. L. Loza, A. J. Kwan, S. P. Hersey, R. C. Flagan, P. O.Wennberg, and J. H. Seinfeld (2010), Reactive intermediates revealed in secondary organic aerosol formation from isoprene, Proc. Natl. Acad. Sci. U.S.A., 107(15), 6640-6645, doi:10.1073/pnas.0911114107.
65. Tan, Y., Y. B. Lim, K. E. Altieri, S. P. Seitzinger, and B. J. Turpin (2012), Mechanisms leading to oligomers and SOA through aqueous photooxidation:Insights from OH radical oxidation of acetic acid and methylglyoxal, Atmos. Chem. Phys., 12(2), 801-813, doi:10.5194/acp-12-801-2012.
66. Tolocka, M. P., and B. Turpin (2012), Contribution of organosulfur compounds to organic aerosol mass, Environ. Sci. Technol., 46(15), 7978-7983, doi:10.1021/Es300651v.
67. Volkamer, R., J. L. Jimenez, F. San Martini, K. Dzepina, Q. Zhang, D. Salcedo, L. T. Molina, D. R. Worsnop, and M. J. Molina (2006), Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected, Geophys. Res. Lett., 33, L17811, doi:10.1029/ 2006GL026899.
68. Warneck, P. (2005), Multi-phase chemistry of C-2 and C-3 organic compounds in the marine atmosphere, J. Atmos. Chem., 51(2), 119-159, doi:10.1007/s10874-005-5984-7.
69. 2O, J. Geophys. Res., 107(D14), 4207, doi:10.1029/2001JD000451.
70. Worton, D. R., et al. (2013), Observational insights into aerosol formation from isoprene, Environ. Sci. Technol., 47(20), 11,403-11,413, doi:10.1021/Es4011064.
71. Xu, L., et al. (2014), Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States, Proc. Natl. Acad. Sci. U.S.A., 112(1), 37-42.
72. Yao, X. H., P. J. G. Rehbein, C. J. Lee, G. J. Evans, J. Corbin, and C. H. Jeong (2011), A study on the extent of neutralization of sulphate aerosol through laboratory and field experiments using an ATOFMS and a GPIC, Atmos. Environ., 45(34), 6251-6256.
73. Yli-Juuti, T., et al. (2013), Volatility of organic aerosol: Evaporation of ammonium sulfate/succinic acid aqueous solution droplets, Environ. Sci. Technol., 47(21), 12,123-12,130, doi:10.1021/Es401233c.
74. Zhang, H. F., et al. (2012), Organosulfates as tracers for Secondary Organic Aerosol (SOA) formation from 2-methyl-3-buten-2-ol (MBO) in the atmosphere, Environ. Sci. Technol., 46(17), 9437-9446, doi:10.1021/Es301648z.
75. Zhang, Q., et al. (2007a), Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes, Geophys. Res. Lett., 34, L13801, doi:10.1029/2007GL029979.
76. Zhang, Q., J. L. Jimenez, D. R. Worsnop, and M. Canagaratna (2007b), A case study of urban particle acidity and its influence on secondary organic aerosol, Environ. Sci. Technol., 41(9), 3213-3219, doi:10.1021/Es061812j.
77. Ziemba, L. D., et al. (2013), Airborne observations of aerosol extinction by in situ and remote-sensing techniques: Evaluation of particle hygroscopicity, Geophys. Res. Lett., 40, 417-422, doi:10.1029/2012GL054428.