Single vial sample preparation of markers of nerve agents by dispersive solid-phase extraction using magnetic strong anion exchange resins

Journal of Chromatography A

Volumn 1395, Issue , 2015, Pages 48-56

  Singh, Varoon ^a   Chinthakindi, Sridhar ^a   Purohit, Ajay Kumar ^a   Pardasani, Deepak ^a   Tak, Vijay ^a   Dubey, Devendra Kumar ^a  

^a DEFENCE RESEARCH AND DEVELOPMENT ESTABLISHMENT   (India)

Author keywords

Alkylalkyl phosphonic acids; Alkylphosphonic acids; Chemical warfare agents; Chemical weapons convention; Derivatization; GC MS; Magnetic strong anion exchange resins; Verification

Indexed keywords

CHEMICAL ANALYSIS; CHEMICAL WARFARE; DEGRADATION; DRUG PRODUCTS; ION EXCHANGE RESINS; IRON OXIDES; MAGNETISM; MAGNETITE; NEGATIVE IONS; PHASE SEPARATION; SYNTHESIS (CHEMICAL); VERIFICATION;

ALKYLPHOSPHONIC ACIDS; CHEMICAL WARFARE AGENTS; CHEMICAL WEAPONS CONVENTION; DERIVATIZATIONS; GC-MS; PHOSPHONIC ACIDS; STRONG-ANION EXCHANGE RESINS;

EXTRACTION;

ALKYL ALKYLPHOSPHONIC ACID; ALKYLPHOSPHONIC ACID; ANION EXCHANGE RESIN; PHOSPHONIC ACID DERIVATIVE; POLY(4 VINYLPYRIDINE CO DIVINYLBENZENE); UNCLASSIFIED DRUG; ANION EXCHANGE RESINS; CHEMICAL WARFARE AGENTS; FERRIC COMPOUNDS; FERRIC OXIDE; METAL NANOPARTICLES; WATER;

ACCURACY; ACIDITY; ADSORPTION; ANION EXCHANGE; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DERIVATIZATION; DESORPTION; LIMIT OF DETECTION; LIMIT OF QUANTITATION; POLYMERIZATION; PRIORITY JOURNAL; SOLID PHASE EXTRACTION; SYNTHESIS; TEMPERATURE; ZETA POTENTIAL; CHEMISTRY; ENVIRONMENTAL MONITORING; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; MAGNETIC PHENOMENA; METHODS;

ANION EXCHANGE RESINS; CHEMICAL WARFARE AGENTS; ENVIRONMENTAL MONITORING; FERRIC COMPOUNDS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; LIMIT OF DETECTION; MAGNETIC PHENOMENA; METAL NANOPARTICLES; SOLID PHASE EXTRACTION; WATER;

EID: 84928588653     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2015.03.073     Document Type: Article

References (36)

1. Convention on the Prohibition of the Development, Production, Stockpiling and use of Chemical Weapons and their Destruction, Technical Secretariat of the Organization for Prohibition of Chemical Weapons, The Hague, 1997, accessible through internet . http://www.opcw.org/.
2. Recommended Operating Procedures for Analysis in the Verification of Chemical Disarmament 2011, University of Helsinki, Helsinki. P. Vanninen (Ed.).
3. http://www.opcw.org/news/article/opcw-statement-on-alleged-chemical-weapons-in-syria/.
4. Marrs T.C. Chemical Warfare Agents Toxicology and Treatment 2007, 191-222. John Wiley & Sons Ltd, Chichester, England. 2nd ed. T.C. Marrs, R.L. Maynard, F.R. Sidell (Eds.).
5. Munro N.B., Talmage S.S., Griffin G.D., Waters L.C., Watson A.P., King J.F., Hauschild V. The sources, fate and toxicity of chemical warfare agent degradation products. Environ. Health Prespect. 1999, 107:933-974.
6. OPCW Central Analytical Database, Organization for The Prohibition of Chemical Weapons, The Hague, The Netherlands, Ver. 15, Dec 2012.
7. Subramaniam R., Ästot C., Nilsson C., Östin A. Combination of solid phase extraction and in vial solid phase derivatisation using a strong anion exchange disk for the determination of nerve agent markers. J. Chromatogr. A 2009, 1216:8452-8459.
8. Sng M.T., Ng W.F. In-situ derivatisation of degradation products of chemical warfare agents in water by solid-phase microextraction and gas chromatographic-mass spectrometric analysis. J. Chromatogr. A 1999, 832:173-182.
9. Lakso H.Å., Ng W.F. Determination of chemical warfare agents in natural water samples by solid-phase microextraction. Anal. Chem. 1997, 69:1866-1872.
10. Kanaujia P.K., Pardasani D., Tak V., Purohit A.K., Dubey D.K. Selective enrichment of the degradation products of organophosphorus nerve agents by zirconia based solid-phase extraction. J. Chromatogr. A 2011, 1218:6612-6620.
11. Xu L., Lee H.K. Zirconia hollow fiber: preparation, characterization and microextraction application. Anal. Chem. 2007, 79:5241-5248.
12. Moullec S.L., Truong L., Montauban C., Begos A., Pichon V., Bellier B. Extraction of alkyl methylphosphonic acids from aqueous samples using a conventional polymeric solid-phase extraction sorbent and a molecularly imprinted polymer. J. Chromatogr. A 2007, 1139:171-177.
13. Dubey D.K., Pardasani D., Palit M., Gupta A.K., Jain R. On-matrix derivatisation-extraction of precursors of nitrogen- and sulfur-mustards for verification of chemical weapons convention. J. Chromatogr. A 2005, 1076:27-33.
14. Terzic O. Screening of degradation products, impurities and precursors of chemical warfare agents in water and wet or dry organic liquid samples by in-sorbent tube silylation followed by thermal desorption-gas chromatography-mass spectrometry. J. Chromatogr. A 2010, 1217:4987-4995.
15. Kuitunen M.L. Sample Preparation for Analysis of Chemicals Related to the Chemical Weapons Convention in an Off Site Laboratory 2005, 163. Wiley, Chichester. M. Mesilaakso (Ed.).
16. Black R.M., Muir B. Derivatisation reactions in the chromatographic analysis of chemical warfare agents and their degradation products. J. Chromatogr. A 2003, 1000:253-281.
17. Aguilar-Arteaga K., Rodriguez J.A., Barrado E. Magnetic solids in analytical chemistry: a review. Anal. Chim. Acta 2010, 674:157-165.
18. Li X.S., Zhu G.T., Luo Y.B., Yuan B.F., Feng Y.Q. Synthesis and applications of functionalized magnetic materials in sample preparation. TrAC Trend Anal. Chem. 2013, 45:233-247.
19. Xie L., Jiang R., Zhu F., Liu H., Ouyang G. Application of functionalized magnetic nanoparticles in sample preparation. Anal. Bioanal. Chem. 2013, 406:377-399.
20. Chatfield S.N., Croft M.Y., Dang T., Murby E.J., Yu G.Y.G., Wells R.J. Simultaneous extraction and methylation of acidic analytes adsorbed onto ion exchange resins using supercritical carbon dioxide containing methyl iodide. Anal. Chem. 1995, 67:945-951.
21. Atapattu S.N., Rosenfield J.M. Solid phase analytical derivatisation as a sample preparation method. J. Chromatogr. A 2013, 1296:204-213.
22. Singh V., Garg P., Chinthakindi S., Tak V., Dubey D.K. Extraction and derivatisation of chemical weapons convention relevant aminoalcohols on magnetic cation-exchange resins. J. Chromatogr. A 2014, 1329:10-16.
23. Pardasani D., Kanaujia P.K., Purohit A.K., Shrivastava A.R., Dubey D.K. Magnetic multi-walled carbon nanotubes assisted dispersive solid phase extraction of nerve agents and their markers from muddy water. Talanta 2011, 86:248-255.
24. Vargantwar P.H., Brannock M.C., Smith S.D., Spontak R.J. Midblock sulfonation of a model long-chain poly(p-tert-butylstyrene-b-styrene-b-p-tert-butylstyrene) triblock copolymer. J. Mater. Chem. 2012, 22:25262-25271.
25. Kosolapoff G.M., Mair L. Organic Phosphorus Compounds 1976, vol. 7:9-22. Wiley, New York.
26. Potec I., Kielczewska A., Konopski L., Oleska G., Krukowska H.N., Legocki J. Alkyl methylphosphonic acids, the degradation products of organophosphorous CWA preparation and direct quantitative GC-FID analysis. Cent. Eur. J. Chem. 2010, 8:1251-1265.
27. Landfester K. The generation of nanoparticles in miniemulsions. Adv. Mater. 2001, 13:765-768.
28. Ma G.H., Fukutomi T. Studies on the preparation and characterization of poly(4-vinylpyridine) microgel. I. Preparation with polymer emulsifier. J. Appl. Polym. Sci. 2003, 43:1451-1457.
29. http://www.chem.agilent.com/library/brochures/5989-9334en.pdf.
30. Fritz J.S. Factors affecting selectivity in ion chromatography. J. Chromatogr. A 2005, 1085:8-17.
31. Evaluation of Results, 24th Official OPCW Proficiency Test, vols. 1 and 2 Technical Secretariat Verification Division, The Hague (August 2009).
32. Lee H.S.N., Sng M.T., Basheer C., Lee H.K. Determination of degradation products of chemical warfare agents in water using hollow fibre-protected liquid-phase microextraction with in-situ derivatisation followed by gas chromatography-mass spectrometry. J. Chromatogr. A 2007, 1148:8-15.
33. Park Y.K., Chung W.Y., Kim B., Kye Y., Shin M., Kim D. Ion-pair single-drop microextraction determinations of degradation products of chemical warfare agents in water. Chromatographia 2013, 76:679-685.
34. Kanaujia P.K., Pardasani D., Gupta A.K., Kumar R., Srivastava R.K., Dubey D.K. Extraction of acidic degradation products of organophosphorus chemical warfare agents: comparison between silica and mixed-mode strong anion-exchange cartridges. J. Chromatogr. A 2007, 1161:98-104.
35. Work Instruction for the Preparation of Samples for OPCW Proficiency Tests, QDOC/LAB/WI/PT02, Organization for Prohibition of Chemical Weapons, The Hague, Netherland, 28th March 2013.
36. Evaluation of Results, 34th Official OPCW Proficiency Test, vols. 1, 2 and 3 Technical Secretariat Verification Division, The Hague (March 2014).