Nickel-catalyzed cross-coupling of photoredox-generated radicals: Uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings

Journal of the American Chemical Society

Volumn 137, Issue 15, 2015, Pages 4896-4899

  Gutierrez, Osvaldo ^a   Tellis, John C ^a   Primer, David N ^a   Molander, Gary A ^a   Kozlowski, Marisa C ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; COUPLINGS; DENSITY FUNCTIONAL THEORY; NICKEL; TRANSITION METALS;

ALKYL RADICALS; CROSS-COUPLINGS; DUAL CATALYSIS; DYNAMIC KINETIC RESOLUTION; ENANTIOSELECTIVE; REACTION PATHWAYS; REDUCTIVE COUPLINGS; REDUCTIVE ELIMINATION;

CATALYSIS;

ALKYL GROUP; BROMIDE; LIGAND; NICKEL; RADICAL; BORON DERIVATIVE; FREE RADICAL; ORGANOMETALLIC COMPOUND;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; COMPLEX FORMATION; CROSS COUPLING REACTION; CYCLIZATION; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; DISSOCIATION; ENANTIOSELECTIVITY; ENERGY; OXIDATION REDUCTION REACTION; OXIDATION REDUCTION STATE; REACTION ANALYSIS; SOLVATION; STEREOCHEMISTRY; STEREOCONVERGENCE; CHEMISTRY; CONFORMATION; KINETICS; PHOTOCHEMISTRY; QUANTUM THEORY; STEREOISOMERISM; SYNTHESIS;

BORON COMPOUNDS; CATALYSIS; FREE RADICALS; KINETICS; MOLECULAR CONFORMATION; NICKEL; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PHOTOCHEMICAL PROCESSES; QUANTUM THEORY; STEREOISOMERISM;

EID: 84928492420     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja513079r     Document Type: Article

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