Iridium oxidation as observed by surface interrogation scanning electrochemical microscopy

Journal of Physical Chemistry C

Volumn 119, Issue 15, 2015, Pages 8147-8154

  Arroyo Currás, Netzahualcóyotl ^a   Bard, Allen J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYTIC EQUIPMENT; ELECTROCATALYSIS; ELECTROCATALYSTS; IRON COMPOUNDS; MICROELECTRODES; OXYGEN EVOLUTION REACTION; PRECIOUS METALS; REACTION KINETICS; SCANNING ELECTRON MICROSCOPY; SCANNING PROBE MICROSCOPY; SODIUM HYDROXIDE; SURFACE STRUCTURE; TEA;

DETECTION AND QUANTIFICATIONS; MONOLAYER COVERAGE; OXIDATION PROCESS; OXYGEN EVOLUTION REACTION (OER); POLYCRYSTALLINE IRIDIUM; SCANNING ELECTROCHEMICAL MICROSCOPY; SURFACE INTERROGATION; ULTRA MICROELECTRODES;

IRIDIUM COMPOUNDS;

EID: 84928009488     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b00106     Document Type: Article

References (42)

1. Trotochaud, L.; Ranney, J. K.; Williams, K. N.; Boettcher, S. W. Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution J. Am. Chem. Soc. 2012, 134, 17253-17261
2. Damjanovic, A.; Dey, A.; Bockris, J. O. Kinetics of Oxygen Evolution and Dissolution on Platinum Electrodes Electrochim. Acta 1966, 11, 791-814
3. Matsumoto, Y.; Sato, E. Electrocatalytic Properties of Transition Metal Oxides for Oxygen Evolution Reaction Mater. Chem. Phys. 1986, 14, 397-426
4. Cook, T. R.; Dogutan, D. K.; Reece, S. Y.; Surendranath, Y.; Teets, T. S.; Nocera, D. G. Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Chem. Rev. 2010, 110, 6474-6502
5. McCrory, C. C. L.; Jung, S.; Peters, J. C.; Jaramillo, T. F. Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction J. Am. Chem. Soc. 2013, 135, 16977-16987
6. nd ed.; CRC Press: Boca Raton, 2012; pp 525-568.
7. Beer, H. B. The Invention and Industrial Development of Metal Anodes J. Electrochem. Soc. 1980, 127, 303C-307C
8. Ardizzone, S.; Trasatti, S. Interfacial Properties of Oxides with Technological Impact in Electrochemistry Adv. Colloid Interface 1996, 64, 173-251
9. Papeschi, G.; Bordi, S.; Carlà, M.; Criscione, L.; Ledda, F. An Iridium-Iridium Oxide Electrode for In Vivo Monitoring of Blood p H Changes J. Med. Eng. Technol. 1981, 5, 86-87
10. Macur, R. Iridium-Iridium Oxide Electrode for Measuring p H of Blood and Other Fluids. US Patent: US3726777 A, April 10, 1973.
11. Buckley, D. N.; Burke, L. D. The Oxygen Electrode. Part 6. Oxygen Evolution and Corrosion at Iridium Anodes J. Chem. Soc., Faraday Trans. 1 1976, 72, 2431-2440
12. Mozota, J.; Conway, B. E. Surface and Bulk Processes at Oxidized Iridium Electrodes. I. Monolayer Stage and Transition to Reversible Multilayer Oxide Film Behavior Electrochim. Acta 1983, 28, 1-8
13. Stonehart, P.; Kozlowska, H. A.; Conway, B. E. Potentiodynamic Examination of Electrode Kinetics for Electroactive Adsorbed Species: Applications to the Reduction of Noble Metal Surface Oxide Proc. R. Soc. A 1969, 310, 541-563
14. Chen, H.; Trasatti, S. Cathodic Behavior of Iridium Dioxide Electrodes in Alkaline Solution. Part I. Electrochemical Surface Characterization J. Appl. Electrochem. 1993, 23, 559-566
15. Koetz, R.; Lewerenz, H. J.; Brueesch, P.; Stucki, S. Oxygen Evolution on Ruthenium and Iridium Electrodes. XPS-Studies J. Electroanal. Chem. 1983, 150, 209-216
16. Koetz, R.; Neff, H.; Stucki, S. Anodic Iridium Oxide Films. XPS Studies of Oxidation State Changes and Molecular Oxygen Evolution J. Electrochem. Soc. 1984, 131, 72-77
17. Minguzzi, A.; Lugaresi, O.; Locatelli, C.; Rondinini, S.; D'Acapito, F.; Achilli, E.; Ghigna, P. Fixed Energy X-Ray Absorption Voltammetry Anal. Chem. 2013, 85, 7009-7013
18. Skoog, D. A.; Holler, F. J.; Crouch, S. R. Principles of Instrumental Analysis, 6 th ed.; Cengage Learning: Belmont, 2006.
19. Minguzzi, A.; Lugaresi, O.; Achilli, E.; Locatelli, C.; Vertova, A.; Ghigna, P.; Rondinini, S. Observing the Oxidation State Turnover in Heterogeneous Iridium-Based Water Oxidation Catalysts Chem. Sci. 2014, 5, 3591-3597
20. Rodriguez-Lopez, J.; Alpuche-Aviles, M.; Bard, A. J. Interrogation of Surfaces for the Quantification of Adsorbed Species on Electrodes: Oxygen on Gold and Platinum in Neutral Media J. Am. Chem. Soc. 2008, 130, 16985-16995
21. 4 Semiconductor Electrode: Quantification of Hydroxyl Radicals during Water Oxidation J. Phys. Chem. C 2013, 117, 12093-12102
22. Rodriguez-Lopez, J. Surface Interrogation Mode of Scanning Electrochemical Microscopy (SI-SECM): An Approach to the Study of Adsorption and (Electro) Catalysis at Electrodes. In Electroanalytical Chemistry: A Series of Advances; CRC Press: Boca Raton, 2012; Vol. 24, pp 287-351.
23. Rodríguez-López, J.; Minguzzi, A.; Bard, A. J. Reaction of Various Reductants with Oxide Films on Pt Electrodes as Studied by the Surface Interrogation Mode of Scanning Electrochemical Microscopy (SI-SECM): Possible Validity of a Marcus Relationship J. Phys. Chem. C 2010, 114, 18645-18655
24. Augustynski, J.; Koudelka, M.; Sanchez, J.; Conway, B. E. ESCA Study of the State of Iridium and Oxygen in Electrochemically and Thermally Formed Iridium Oxide Films J. Electroanal. Chem. 1984, 160, 233-248
25. Vertova, A.; Borgese, L.; Capelletti, G.; Locatelli, C.; Minguzzi, A.; Pezzoni, C.; Rondinini, S. Cavity Microelectrodes for the Voltammetric Investigation of Electrocatalysts: the Electroreduction of Volatile Organic Halides on Micro-Sized Silver Powders J. Appl. Electrochem. 2008, 38, 973-978
26. Dahms, H.; Bockris, J.O'M. The Relative Electrocatalytic Activity of Noble Metals in the Oxidation of Ethylene J. Electrochem. Soc. 1964, 111, 728-736
27. Bechtold, T.; Burtscher, E.; Gmeiner, D.; Bobleter, O. The Redox-Catalysed Reduction of Dispersed Organic Compounds: Investigations on the Electrochemical Reduction of Insoluble Organic Compounds in Aqueous Systems J. Electroanal. Chem. 1991, 306, 169-183
28. Arroyo-Currás, N.; Hall, J. W.; Dick, J. E.; Jones, R. A.; Bard, A. J. An Alkaline Flow Battery Based on the Coordination Chemistry of Iron and Cobalt J. Electrochem. Soc. 2015, 162, A378-A383
29. Denuault, G.; Mirkin, M. V.; Bard, A. J. Direct Determination of Diffusion Coefficients by Chronoamperometry at Microdisk Electrodes J. Electroanal. Chem. 1991, 308, 27-38
30. Bard, A. J.; Mirkin, M. V. Scanning Electrochemical Microscopy, 2nd ed.; CRC Press: Boca Raton, 2012; pp 25.
31. Wen, Y. H.; Zhang, H. M.; Qian, P.; Zhou, H. T.; Zhao, P.; Yi, B. L.; Yang, Y. S. A Study of the Fe(III)/Fe(II)-Triethanolamine Complex Redox Couple for Redox Flow Battery Application Electrochim. Acta 2005, 51, 3769-3775
32. Angerstein-Kozlowska, H.; Conway, B. E.; Mozota, J. The Role of Ion Adsorption in Surface Oxide Formation and Reduction at Noble Metals: General Features of the Surface Process J. Electroanal. Chem. 1979, 100, 417-446
33. Otten, J. M.; Visscher, W. Anodic Behavior of Iridium. II. Oxygen Coverage J. Electroanal. Chem. 1974, 55, 13-21
34. Plichon, V.; Petit, M. A. Anodic Electrodeposition of Iridium Oxide Films J. Electroanal. Chem. 1998, 444, 247-252
35. Burke, L. D.; Whelan, D. P. A New Interpretation of the Charge Storage and Electrical Conductivity Behavior of Hydrous Iridium Oxide J. Electroanal. Chem. 1981, 124, 333-337
36. Woods, R. Hydrogen Adsorption on Platinum, Iridium, and Rhodium Electrodes at Reduced Temperatures and the Determination of Real Surface Area J. Electroanal. Chem. 1974, 49, 217-227
37. Guerrini, E.; Trasatti, S. Recent Developments in Understanding Factors of Electrocatalysis Russ. J. Electrochem. 2006, 42, 1017-1025
38. Soliman, K. A.; Kibler, L. A. Variation of the Potential of Zero Charge for a Silver Monolayer Deposited Onto Various Noble Metal Single Crystal Surfaces Electrochim. Acta 2007, 52, 5654-5658
39. Delahay, P. Double Layer and Electrode Kinetics; Interscience Publishers: New York, 1965.
40. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 2001.
41. Ferse, A. Numerical Values of Individual Activity Coefficients of Single-Ion Species in Concentrated Aqueous Electrolyte Solutions and the Attempt of a Qualitative Interpretation on a Model of Electrostatic Interaction J. Solid State Electrochem. 2013, 17, 1321-1332
42. Gileadi, E.; Conway, B. E. Kinetic Theory of Adsorption of Intermediates in Electrochemical Catalysis J. Chem. Phys. 1963, 39, 3420-3430