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The N-phenyl substrate 1a-Ph reacted with 2-fluorostyrene (40%, 34% ee) and (Z)-β-trimethylsilylstyrene (8%, 40% ee) albeit in low yields and enantioselectivities.
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84937593352
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note
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Regardless of the significant difference in the catalytic activity, we speculate that the nature of the asymmetric induction process would not change depending on the cobalt precatalyst because the ee value of the model reaction is rather independent of the precatalyst (see Table S2, Supporting Information).
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