Continuous representation of the proton and electron kinetic parameters in the pH-potential space for water oxidation on hematite

Journal of Physical Chemistry C

Volumn 119, Issue 12, 2015, Pages 6619-6625

  Haghighat, Shima ^a   Dawlaty, Jahan M ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRODES; ELECTROLYTES; ELECTRON TRANSITIONS; HEMATITE; KINETICS; THERMODYNAMIC STABILITY;

ELECTROCHEMICAL REACTIONS; ELECTROLYTE SYSTEMS; ELECTRON TRANSFER; OXIDATION MECHANISMS; OXIDE ELECTRODES; PROTONATION EQUILIBRIA; THERMODYNAMIC LIMITS; WATER ELECTROLYSIS;

GRAPHIC METHODS;

EID: 84925967752     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b00053     Document Type: Article

References (44)

1. Kinoshita, K. Electrochemical Oxygen Technology; The ECS Series of Texts and Monographs; John Wiley & Sons: New York, 1992.
2. Bard, A. J.; Fox, M. A. Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen Acc. Chem. Res. 1995, 28, 141-145
3. Bockris, J. O.; Otagawa, T. Mechanism of Oxygen Evolution on Perovskites J. Phys. Chem. 1983, 87, 2960-2971
4. Nocera, D. G. The Artificial Leaf Acc. Chem. Res. 2012, 45, 767-776
5. Walter, M. G.; Warren, E. L.; McKone, J. R.; Boettcher, S. W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Solar Water Splitting Cells Chem. Rev. (Washington, DC, U.S.) 2010, 110, 6446-6473
6. Trasatti, S. Transition Metal Oxides: Versatile Materials for Electrocatalysis. In The Electrochemistry of Novel Materials; Lipkowski, J.; Ross, P., Eds.; Frontiers of Electrochemistry; VCH: New York, 1994.
7. Liao, P.; Keith, J. A.; Carter, E. A. Water Oxidation on Pure and Doped Hematite (0001) Surfaces: Prediction of Co and Ni as Effective Dopants for Electrocatalysis J. Am. Chem. Soc. 2012, 134, 13296-13309
8. 3 Composite Photoelectrodes with Low Onset Potential for Solar Water Oxidation Phys. Chem. Chem. Phys. 2014, 16, 1327-1332
9. Matsumoto, Y.; Sato, E. Electrocatalytic Properties of Transition Metal Oxides for Oxygen Evolution Reaction Mater. Chem. Phys. 1986, 14, 397-426
10. 3 Improves the Rate and Selectivity of Photoelectrochemical Water Oxidation J. Am. Chem. Soc. 2014, 136, 1694-1697
11. Conway, B. E.; Gileadi, E. Kinetic Theory of Pseudo-Capacitance and Electrode Reactions at Appreciable Surface Coverage Trans. Faraday Soc. 1962, 58, 2493-2509
12. Damjanovic, A.; Dey, A.; Bockris, J. Kinetics of Oxygen Evolution and Dissolution on Platinum Electrodes Electrochim. Acta 1966, 11, 791-814
13. Bockris, J. O. Kinetics of Activation Controlled Consecutive Electrochemical Reactions: Anodic Evolution of Oxygen J. Chem. Phys. 1956, 24, 817-827
14. 2 Electrocatalysts J. Am. Chem. Soc. 2012, 134, 1519-1527
15. Kushner-Lenhoff, M. N.; Blakemore, J. D.; Schley, N. D.; Crabtree, R. H.; Brudvig, G. W. Effects of Aqueous Buffers on Electrocatalytic Water Oxidation with an Iridium Oxide Material Electrodeposited in Thin Layers from an Organometallic Precursor Dalton Trans. 2013, 42, 3617-3622
16. Klahr, B. M.; Hamann, T. W. Current and Voltage Limiting Processes in Thin Film Hematite Electrodes J. Phys. Chem. C 2011, 115, 8393-8399
17. 3) J. Phys. Chem. C 2013, 117, 4040-4047
18. Pourbaix, M. Atlas of Electrochemical Equilibria in Aqueous Solutions; National Association of Corrosion Engineers: Houston, TX, 1974.
19. Minguzzi, A.; Fan, F.-R. F.; Vertova, A.; Rondinini, S.; Bard, A. J. Dynamic Potential-pH Diagrams Application to Electrocatalysts for Water Oxidation Chem. Sci. 2012, 3, 217-229
20. Bockris, J.; Reddy, A. Modern Electrochemistry: An Introduction to an Interdisciplinary Area; Springer: Boston, MA, 1973; Vol. 2.
21. Gileadi, E. Electrode Kinetics for Chemists, Chemical Engineers, and Materials Scientists; VCH: New York, 1993.
22. Bamford, C.; Tipper, C.; Compton, R. Electrode Kinetics: Principles and Methodology; Comprehensive Chemical Kinetics Series; Elsevier Science: New York, 1986.
23. Trasatti, S.; Lodi, G. Oxygen and Chlorine Evolution at Conductive Metallic Oxide Anodes; Studies in Physical and Theoretical Chemistry; Elsevier: Amsterdam, 1981.
24. Angelinetta, C.; Falciola, M.; Trasatti, S. Heterogenous Acid-Base Equilibria and Reaction Order of Oxygen Evolution on Oxide Electrodes J. Electroanal. Chem. Interfacial Electrochem. 1986, 205, 347-353
25. Smith, R. D. L.; Prévot, M. S.; Fagan, R. D.; Zhang, Z.; Sedach, P. A.; Siu, M. K. J.; Trudel, S.; Berlinguette, C. P. Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis Science 2013, 340, 60-63
26. Buono-Core, G.; Tejos, M.; Lara, J.; Aros, F.; Hill, R. Solid-State Photochemistry of a Cu(II)β-Diketonate Complex: The Photochemical Formation of High Quality Films of Copper(II) Oxide Mater. Res. Bull. 1999, 34, 2333-2340
27. Faurie-Wisniewski, D.; Geiger, F. M. Synthesis and Characterization of Chemically Pure Nanometer-Thin Zero-Valent Iron Films and Their Surfaces J. Phys. Chem. C 2014, 118, 23256-23263
28. 4 Electrodes in Alkaline Solutions: Hydrogen Evolution J. Appl. Electrochem. 1998, 28, 1291-1297
29. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2 nd ed.; Wiley: New York, 2001.
30. Tilak, B.; Conway, B. Analytical Relations Between Reaction Order and Tafel Slope Derivatives for Electrocatalytic Reactions Involving Chemisorbed Intermediates Electrochim. Acta 1992, 37, 51-63
31. Daghetti, A.; Lodi, G.; Trasatti, S. Interfacial Properties of Oxides Used as Anodes in the Electrochemical Technology Mater. Chem. Phys. 1983, 8, 1-90
32. Lodi, G.; Sivieri, E.; de Battisti, A.; Trasatti, S. Ruthenium Dioxide-Based Film Electrodes J. Appl. Electrochem. 1978, 8, 135-143
33. 3 Anode: Mechanistic Considerations from Molecular Orbital Theory J. Electrochem. Soc. 1989, 136, 158-166
34. Yamaguchi, A.; Inuzuka, R.; Takashima, T.; Hayashi, T.; Hashimoto, K.; Nakamura, R. Regulating Proton-Coupled Electron Transfer for Efficient Water Splitting by Manganese Oxides at Neutral pH Nat. Commun. 2014, 5, 1-6
35. Koper, M. T. Theory of Multiple Proton-Electron Transfer Reactions and its Implications for Electrocatalysis Chem. Sci. 2013, 4, 2710-2723
36. 2-Evolution Catalyst J. Am. Chem. Soc. 2013, 135, 10492-10502
37. Schrauben, J. N.; Hayoun, R.; Valdez, C. N.; Braten, M.; Fridley, L.; Mayer, J. M. Titanium and Zinc Oxide Nanoparticles are Proton-Coupled Electron Transfer Agents Science 2012, 336, 1298-1301
38. Venkataraman, C.; Soudackov, A. V.; Hammes-Schiffer, S. Theoretical Formulation of Nonadiabatic Electrochemical Proton-Coupled Electron Transfer at Metal- Solution Interfaces J. Phys. Chem. C 2008, 112, 12386-12397
39. Matthews, D.; Bockris, J. The Mechanism of Charge Transfer from Metal Electrodes to Ions in Solution; Modern Aspects of Electrochemistry Series; Springer: New York, 1971.
40. Bediako, D. K.; Surendranath, Y.; Nocera, D. G. Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel Borate Thin Film Electrocatalyst J. Am. Chem. Soc. 2013, 135, 3662-3674
41. Norskov, J.; Bligaard, T.; Logadottir, A.; Bahn, S.; Hansen, L.; Bollinger, M.; Bengaard, H.; Hammer, B.; Sljivancanin, Z.; Mavrikakis, M.; Xu, Y.; Dahl, S.; Jacobsen, C. Universality in Heterogeneous Catalysis J. Catal. 2002, 209, 275-278
42. Ludlow, M. K.; Soudackov, A. V.; Hammes-Schiffer, S. Electrochemical Proton-Coupled Electron Transfer of an Osmium Aquo Complex: Theoretical Analysis of Asymmetric Tafel Plots and Transfer Coefficients J. Am. Chem. Soc. 2010, 132, 1234-1235
43. Costentin, C.; Robert, M.; Savéant, J.-M. Electrochemical Concerted Proton and Electron Transfers. Potential-Dependent Rate Constant, Reorganization Factors, Proton Tunneling and Isotope Effects J. Electroanal. Chem. 2006, 588, 197-206
44. Surendranath, Y.; Kanan, M. W.; Nocera, D. G. Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH J. Am. Chem. Soc. 2010, 132, 16501-16509