Enhancing electrochemical water-splitting kinetics by polarization-driven formation of near-surface iron(0): An in situ XPS study on perovskite-type electrodes

Angewandte Chemie - International Edition

Volumn 54, Issue 9, 2015, Pages 2628-2632

  Opitz, Alexander K ^a   Nenning, Andreas ^a   Rameshan, Christoph ^c   Rameshan, Raffael ^b,d   Blume, Raoul ^d,e   Hävecker, Michael ^d,e   Knop Gericke, Axel ^d   Rupprechter, Günther ^c   Fleig, Jürgen ^a   Klötzer, Bernhard ^b  

^a VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^b UNIVERSITY OF INNSBRUCK   (Austria)

^c VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^d FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^e HAHN MEITNER INSTITUT   (Germany)

Author keywords

Electrocatalysis; Heterogeneous catalysis; Perovskites; Solid oxide electrolysis cells; Thin film electrodes

Indexed keywords

CATALYSIS; CATHODES; CATHODIC POLARIZATION; ELECTROCATALYSIS; ELECTRODES; ELECTROLYSIS; PEROVSKITE; POLARIZATION; REGENERATIVE FUEL CELLS; SOLID OXIDE FUEL CELLS (SOFC); SURFACE CHEMISTRY; THIN FILMS; X RAY PHOTOELECTRON SPECTROSCOPY;

AMBIENT-PRESSURE X-RAY PHOTOELECTRON SPECTROSCOPIES; CATH-ODE MATERIALS; ELECTROCATALYTIC ACTIVITY; HIGH TEMPERATURE ELECTROLYSIS; IMPEDANCE SPECTROSCOPY; MIXED CONDUCTING OXIDES; SOLID OXIDE ELECTROLYSIS CELLS; THIN-FILM ELECTRODE;

ELECTROCHEMICAL ELECTRODES;

CALCIUM DERIVATIVE; IRON; LANTHANUM; OXIDE; PEROVSKITE; STRONTIUM; TITANIUM; WATER;

CHEMISTRY; ELECTROCHEMICAL ANALYSIS; ELECTRODE; KINETICS; SURFACE PROPERTY; X RAY PHOTOELECTRON SPECTROSCOPY;

CALCIUM COMPOUNDS; ELECTROCHEMICAL TECHNIQUES; ELECTRODES; IRON; KINETICS; LANTHANUM; OXIDES; PHOTOELECTRON SPECTROSCOPY; STRONTIUM; SURFACE PROPERTIES; TITANIUM; WATER;

EID: 84923083984     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201409527     Document Type: Article

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