Effects of sepiolite clay on degradation and fire behaviour of a bisphenol A-based epoxy

Composites Part B: Engineering

Volumn 73, Issue , 2015, Pages 139-148

  Zotti, Aldobenedetto ^a   Borriello, Anna ^a   Ricciardi, Mariarosaria ^a   Antonucci, Vincenza ^a   Giordano, Michele ^a   Zarrelli, Mauro ^a  

^a CNR   (Italy)

Author keywords

A. Polymer matrix composites (PMCs); A. Thermosetting resin; B. Thermal properties; Sepiolite

Indexed keywords

ACTIVATION ENERGY; CALORIMETRY; FILLERS; FIRES; FLAME RETARDANTS; MORPHOLOGY; THERMODYNAMIC STABILITY;

BURNING PROCESS; DEGRADATION PROCESS; HEAT RELEASE RATE (HRR); INORGANIC CONTENT; INORGANIC FILLERS; POLYMER MATRIX COMPOSITES (PMCS); SEPIOLITE; SEPIOLITE CLAY;

POLYMER MATRIX COMPOSITES;

EID: 84922824246     PISSN: 13598368     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.compositesb.2014.12.019     Document Type: Article

References (21)

1. B. Ellis Chemistry and technology of epoxy resins 1993 Chapman & Hall London
2. J.P. Pascault, H. Sautereau, J. Verdu, and R.J.J. Williams Thermosetting polymers 2002 Marcel Dekker New York
3. M.R. Ricciardi, V. Antonucci, M. Zarrelli, and M. Giordano Fire behavior and smoke emission of phosphate-based inorganic fire-retarded polyester resin J Fire Mater 36 3 2012 203 215 10.1002/fam.1101
4. C. Formicola, A. De Fenzo, M. Zarrelli, M. Giordano, and V. Antonucci Zinc-based compounds as smoke suppressant agents for an aerospace epoxy matrix Polym Int 60 2 2011 304 311 10.1002/pi.2949
5. A. Nohales, R. Munoz-Espi, P. Felix, and C.M. Gomez Sepiolite-reinforced epoxy nanocomposites: thermal, mechanical, and morphological behavior J Appl Polym Sci 119 1 2011 539 547 10.1002/app.32797
6. A. Martone, C. Formicola, M. Giordano, and M. Zarrelli Reinforcement efficiency of multi-walled carbon nanotube/epoxy nano composites Compos Sci Technol 70 7 2010 1154 1160 10.1016/j.compscitech.2010.03.001
7. S. Duquesne, C. Jama, M. Le Bras, R. Delobel, P. Recourc, and G.M. Gloaguen Elaboration of EVA-nanoclay systems-characterization, thermal behaviour and fire performance Compos Sci Technol 63 8 2003 1141 1148 10.1016/S0266-3538(03)00035-6
8. F. Samyn, S. Bourbigot, C. Jama, and S. Bellayer Fire retardancy of polymer clay nanocomposites: is there an influence of the nanomorphology? Polym Degrad Stab 93 11 2008 2019 2024 10.1016/j.polymdegradstab.2008.02.013
9. Y. Yu, S. Qi, J. Zhan, Z. Wu, X. Yang, and D. Wu Polyimide/sepiolite nanocomposite films: preparation, morphology and properties Mater Res Bull 46 10 2011 1593 1599 10.1016/j.materresbull.2011.06.009
10. M. Suárez, and E. García-Romero Variability of the surface properties of sepiolite Appl Clay Sci 67-68 2012 72 82 10.1016/j.clay.2012.06.003
11. Technical Data Bulletin Epon828. Houston, Momentive; 2005.
12. Technical Data Sheet EPIKURE™ Curing Agent 3200, 3223, 3234 & 3245. Houston, Momentive; 2005.
13. C. Huggett Estimation of rate of heat release by means of oxygen-consumption measurements Fire Mater 4 2 1980 61 65 10.1002/fam.810040202
14. A.B. Zotti, A. Borriello, A. Martone, V. Antonucci, M. Giordano, and M. Zarrelli Effect of sepiolite filler on mechanical behaviour of a bisphenol A-based epoxy system Composites Part B 67 2014 400 409 10.1016/j.compositesb.2014.07.017
15. R.L. Frost, and Z. Ding Controlled rate thermal analysis and differential scanning calorimetry of sepiolites and palygorskites Thermochim Acta 397 1-2 2003 119 128 10.1016/S0040-6031(02)00228-9
16. J.C. Paterson-Jones, V.A. Percy, R.G.F. Giles, and A.M. Stephen The thermal degradation of model compounds of amine-cured epoxide resins. II. The thermal degradation of 1,3-diphenoxypropan-2-ol and 1,3-diphenoxypropene J Appl Polym Sci 17 6 1973 1877 1887 10.1002/app.1973.070170620
17. N. Rose, M. Le Bras, S. Bourbigot, and R. Delobel Thermal oxidative degradation of epoxy resins: evaluation of their heat resistance using invariant kinetic parameters Polym Degrad Stab 45 3 1994 387 397 10.1016/0141-3910(94)90209-7
18. K. Slopiecka, P. Bartocci, and F. Fantozzi Thermogravimetric analysis and Kinetic study of poplar wood pyrolysis Appl Energy 97 2012 491 497 10.1016/j.apenergy.2011.12.056
19. S. Liu, H. Ye, Y. Zhou, J. He, Z. Jiang, and J. Zhao Study on flame-retardant mechanism of polycarbonate containing sulfonate-silsesquioxane-fluoro retardants by TGA and FTIR Polym Degrad Stab 91 8 2006 1808 1814 10.1016/j.polymdegradstab.2005.11.013
20. B. Kandola, and L. Krishnan Fire performance evaluation of different resins for potential application in fire resistant structural marine composites 2014 University of Bolton, Institute for Materials Research and Innovation
21. L.B. Manfredi, E.S. Rodríguez, M. Wladyka-Przybylak, and A. Vázquez Thermal degradation and fire resistance of unsaturated polyester, modified acrylic resins and their composites with natural fibres Polym Degrad Stab 91 2 2006 255 261 10.1016/j.polymdegradstab.2005.05.003