Hydrogen storage materials: Room-temperature wet-chemistry approach toward mixed-metal borohydrides

Angewandte Chemie - International Edition

Volumn 54, Issue 4, 2015, Pages 1236-1239

  Jaroń, Tomasz ^a   Orłowski, Piotr A ^b   Wegner, Wojciech ^b   Fijałkowski, Karol J ^a   Leszczyński, Piotr J ^a   Grochala, Wojciech ^a  

^a UNIVERSITY OF WARSAW   (Poland)

^b UNIVERSITY OF WARSAW   (Poland)

Author keywords

Alkali metal halides; Borohydrides; Hydrogen storage; Organic solvents; Weakly coordinating anions

Indexed keywords

ALKALI HALIDES; ALKALI METALS; HYDROGEN; METAL HALIDES; METALS; ORGANIC SOLVENTS; STORAGE (MATERIALS); TRANSITION METALS; ZINC;

BOROHYDRIDES; HYDROGEN DISCHARGE; HYDROGEN EVOLUTION; METATHESIS REACTIONS; ORGANIC CATIONS; ROOM TEMPERATURE; SYNTHETIC METHODS; WEAKLY COORDINATING ANIONS;

HYDROGEN STORAGE;

EID: 84921029733     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201408456     Document Type: Article

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43. 2 is sufficient to perform the solvent-mediated metathesis [Equations (6)-(8)], it is still relatively low, especially for M = Li, which hampers the ion-exchange reaction. The necessity to use the salts of weakly coordinating anions is the greatest strength and simultaneously a hidden weakness of the method proposed here. This is because the [Cat][An] by-product is quite unreactive (recall hard and soft acids and bases: soft prefers soft). More research is needed to understand how [Cat][An] could be returned to the production cycle to give a virtually waste-free technology.
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