Ag11(SG)7: A new cluster identified by mass spectrometry and optical spectroscopy

Journal of Physical Chemistry C

Volumn 118, Issue 37, 2014, Pages 21722-21729

  Baksi, Ananya ^a   Bootharaju, M S ^a   Chen, Xi ^b   Hakkinen H ^b   Pradeep, T ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTRA; ABSORPTION SPECTROSCOPY; COPPER COMPOUNDS; DENSITY FUNCTIONAL THEORY; ELECTRODEPOSITION; ELECTROPHORESIS; ELECTROSPRAY IONIZATION; LIGHT ABSORPTION; MASS SPECTROMETRY; MERCURY COMPOUNDS; METAL IONS; POTABLE WATER; SODIUM BOROHYDRIDE; ULTRAVIOLET SPECTROSCOPY;

ABSORPTION FEATURES; DETECTION LIMITS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; HIGH YIELD SYNTHESIS; MOLECULAR FORMULA; OPTICAL SPECTROSCOPY; POLYACRYLAMIDE GEL ELECTROPHORESIS; UV-VIS ABSORPTION SPECTRA;

SILVER COMPOUNDS;

EID: 84920278136     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp508124b     Document Type: Article

References (56)

1. Jin, R. Quantum Sized, Thiolate-Protected Gold Nanoclusters Nanoscale 2010, 2, 343-362
2. Wilcoxon, J. P.; Abrams, B. L. Synthesis, Structure and Properties of Metal Nanoclusters Chem. Soc. Rev. 2006, 35, 1162-1194
3. Parker, J. F.; Fields-Zinna, C. A.; Murray, R. W. The Story of a Monodisperse Gold Nanoparticle: Au25L18 Acc. Chem. Res. 2010, 43, 1289-1296
4. Walter, M.; Akola, J.; Lopez-Acevedo, O.; Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Whetten, R. L.; Gronbeck, H.; Hakkinen, H. A Unified View of Ligand-Protected Gold Clusters As Superatom Complexes Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 9157-9162
5. Udayabhaskararao, T.; Pradeep, T. New Protocols for the Synthesis of Stable Ag and Au Nanocluster Molecules J. Phys. Chem. Lett. 2013, 4, 1553-1564
6. Diez, I.; Ras, R. H. A. Fluorescent Silver Nanoclusters Nanoscale 2011, 3, 1963-1970
7. Wei, W.; Lu, Y.; Chen, W.; Chen, S. One-Pot Synthesis, Photoluminescence, and Electrocatalytic Properties of Subnanometer-Sized Copper Clusters J. Am. Chem. Soc. 2011, 133, 2060-2063
8. Yuan, X.; Luo, Z.; Zhang, Q.; Zhang, X.; Zheng, Y.; Lee, J. Y.; Xie, J. Synthesis of Highly Fluorescent Metal (Ag, Au, Pt, and Cu) Nanoclusters by Electrostatically Induced Reversible Phase Transfer ACS Nano 2011, 5, 8800-8808
9. Zhang, J.; Wang, X.; Fu, Y.; Han, Y.; Cheng, J.; Zhang, Y.; Li, W. Highly Active Subnano Palladium Clusters Embedded in i-Motif DNA Langmuir 2013, 29, 14345-14350
10. Adhikari, B.; Banerjee, A. Facile Synthesis of Water-Soluble Fluorescent Silver Nanoclusters and HgII Sensing Chem. Mater. 2010, 22, 4364-4371
11. Negishi, Y.; Arai, R.; Niihori, Y.; Tsukuda, T. Isolation and Structural Characterization of Magic Silver Clusters Protected by 4-(tert -Butyl)benzyl Mercaptan Chem. Commun. 2011, 47 (20) 5693-5695
12. 8 Clusters by Interfacial Synthesis Angew. Chem., Int. Ed. 2010, 49, 3925-3929
13. Krishnadas, K. R.; Udayabhaskararao, T.; Choudhury, S.; Goswami, N.; Pal, S. K.; Pradeep, T. Luminescent AgAu Alloy Clusters Derived from Ag Nanoparticles: Manifestations of Tunable AuI-CuI Metallophilic Interactions Eur. J. Inorg. Chem. 2014, 2014, 908-916
14. 3+ Sensing Chem. Commun. 2011, 47, 2661-2663
15. 25 Nanoclusters via pH Controlled CO Reduction Chem. Mater. 2013, 25, 946-952
16. 7 Quantum Cluster for Selective Adsorption of Cationic Dyes Langmuir 2013, 29, 8125-8132
17. 9 Quantum Cluster through a Solid-State Route J. Am. Chem. Soc. 2010, 132, 16304-16307
18. 60 Cluster Nano Lett. 2012, 12, 5861-5866
19. Zhou, T.; Rong, M.; Cai, Z.; Yang, C. J.; Chen, X. Sonochemical Synthesis of Highly Fluorescent Glutathione-Stabilized Ag Nanoclusters and S2-Sensing Nanoscale 2012, 4, 4103-4106
20. Chakraborty, I.; Udayabhaskararao, T.; Deepesh, G. K.; Pradeep, T. Sunlight Mediated Synthesis and Antibacterial Properties of Monolayer Protected Silver Clusters J. Mater. Chem. B 2013, 1, 4059-4064
21. Xavier, P. L.; Chaudhari, K.; Baksi, A.; Pradeep, T. Protein-Protected Luminescent Noble Metal Quantum Clusters: an Emerging Trend in Atomic Cluster Nanoscience Nano Rev. 2012, 3, 14767
22. Chakraborty, I.; Udayabhaskararao, T.; Pradeep, T. Luminescent Sub-Nanometer Clusters for Metal Ion Sensing: a New Direction in Nanosensors J. Hazard. Mater. 2012, 211-212, 396-403
23. 25 Cluster and Optical Properties J. Am. Chem. Soc. 2008, 130, 5883-5885
24. 18] J. Am. Chem. Soc. 2008, 130, 3754-3755
25. 24 Angew. Chem., Int. Ed. 2012, 51, 13114-13118
26. Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. Total Structure Determination of Thiolate-Protected Au38 Nanoparticles J. Am. Chem. Soc. 2010, 132, 8280-8281
27. Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Kornberg, R. D. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution Science 2007, 318, 430-433
28. 18 Cluster J. Am. Chem. Soc. 2014, 136, 5000-5005
29. + Core Chem. Commun. 2013, 49, 300-302
30. Yang, H.; Wang, Y.; Zheng, N. Stabilizing Subnanometer Ag(0) Nanoclusters by Thiolate and Diphosphine Ligands and Their Crystal Structures Nanoscale 2013, 5, 2674-2677
31. 32 Nanoparticles with Single-Crystal Structures Nat. Commun. 2013, 4, 2422
32. Desireddy, A.; Conn, B. E.; Guo, J.; Yoon, B.; Barnett, R. N.; Monahan, B. M.; Kirschbaum, K.; Griffith, W. P.; Whetten, R. L.; Landman, U.; Bigioni, T. P. Ultrastable Silver Nanoparticles Nature 2013, 501, 399-402
33. 40 Clusters: A Combined Circular Dichroism and Mass Spectrometry Study J. Am. Chem. Soc. 2010, 132, 16783-16789
34. 18 Nanoclusters ACS Nano 2010, 4, 4691-4700
35. 25 Clusters with Bulky Calix[4]arene Functionalities J. Phys. Chem. Lett. 2014, 5, 585-589
36. 25 Clusters ACS Nano 2014, 8, 139-152
37. Negishi, Y.; Nobusada, K.; Tsukuda, T. Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between Gold(I)-Thiolate Complexes and Thiolate-Protected Gold Nanocrystals J. Am. Chem. Soc. 2005, 127, 5261-5270
38. Niihori, Y.; Matsuzaki, M.; Pradeep, T.; Negishi, Y. Separation of Precise Compositions of Noble Metal Clusters Protected with Mixed Ligands J. Am. Chem. Soc. 2013, 135, 4946-4949
39. 7 Clusters J. Am. Chem. Soc. 2009, 131, 16672-16674
40. Yuan, X.; Setyawati, M. I.; Tan, A. S.; Ong, C. N.; Leong, D. T.; Xie, J. Highly Luminescent Silver Nanoclusters with Tunable Emissions: Cyclic Reduction-Decomposition Synthesis and Antimicrobial Properties NPG Asia Mater. 2013, 5, e39
41. 11 Nanoscale 2013, 5, 5637-5643
42. Udayabhaskararao, T.; Bootharaju, M. S.; Pradeep, T. Thiolate-Protected Ag32 Clusters: Mass Spectral Studies of Composition and Insights into the Ag-Thiolate Structure from NMR Nanoscale 2013, 5, 9404-9411
43. 4-: A Silver-Thiolate Superatom Complex Nanoscale 2012, 4, 4269-4274
44. 30 Nanoclusters J. Mater. Chem. A 2013, 1, 10148-10154
45. Chakraborty, I.; Udayabhaskararao, T.; Pradeep, T. High Temperature Nucleation and Growth of Glutathione Protected [Similar]Ag75 Clusters Chem. Commun. 2012, 48, 6788-6790
46. Mathew, A.; Pradeep, T. Noble Metal Clusters: Applications in Energy, Environment, and Biology Part. Part. Syst. Charact. 2014, n/a-n/a
47. Habeeb Muhammed, M. A.; Verma, P. K.; Pal, S. K.; Retnakumari, A.; Koyakutty, M.; Nair, S.; Pradeep, T. Luminescent Quantum Clusters of Gold in Bulk by Albumin-Induced Core Etching of Nanoparticles: Metal Ion Sensing, Metal-Enhanced Luminescence, and Biolabeling Chem.-Eur. J. 2010, 16, 10103-10112
48. Liu, Y.; Ai, K.; Cheng, X.; Huo, L.; Lu, L. Gold-Nanocluster-Based Fluorescent Sensors for Highly Sensitive and Selective Detection of Cyanide in Water Adv. Funct. Mater. 2010, 20, 951-956
49. Kumar, S.; Bolan, M. D.; Bigioni, T. P. Glutathione-Stabilized Magic-Number Silver Cluster Compounds J. Am. Chem. Soc. 2010, 132, 13141-13143
50. Bellon, P.; Manassero, M.; Sansoni, M. Crystal and Molecular Structure of Triiodoheptakis[tris(p -fluorophenyl)phosphine]undecagold J. Chem. Soc., Dalton Trans. 1972, 14, 1481-7
51. 2 and CO to Small Gold, Silver, and Binary Silver-Gold Cluster Anions from Temperature Dependent Reaction Kinetics Measurements J. Phys. Chem. A 2009, 113, 2724-2733
52. De, H. J.; Veldeman, N.; Claes, P.; Janssens, E.; Andersson, M.; Lievens, P. Carbon Monoxide Adsorption on Silver Doped Gold Clusters J. Phys. Chem. A 2011, 115, 2103-2109
53. + (n + m = 5): Theory and Experiment Phys. Chem. Chem. Phys. 2011, 12, 7865-7873
54. 18 Nanoclusters and Identification of Perimeter Sites as Active Centers ACS Nano 2012, 6, 6014-6022
55. 24 Nanocluster Catalysts for CO Oxidation: a Comparison of Ligand-on and -off Catalysts Nanoscale 2013, 5, 5912-5918
56. 18 Nanoclusters J. Am. Chem. Soc. 2014, 136, 6111-6122