Highly-ordered magnéli Ti4O7 nanotube arrays as effective anodic material for electro-oxidation

Electrochimica Acta

Volumn 153, Issue , 2015, Pages 316-324

  Geng, Ping ^a   Su, Jingyang ^a   Miles, Caroline ^a,b   Comninellis, Christos ^b   Chen, Guohua ^a  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b EPFL   (Switzerland)

Author keywords

Electro oxidation; Magn li titanium sub oxides; Ti4O7; TiO2 nanotube arrays

Indexed keywords

ANODES; ANODIC OXIDATION; CATHODIC POLARIZATION; CHARGE TRANSFER; CRYSTALLINITY; CYCLIC VOLTAMMETRY; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTROOXIDATION; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; NANOTUBES; OXIDE MINERALS; SCANNING ELECTRON MICROSCOPY; TITANIUM DIOXIDE; X RAY PHOTOELECTRON SPECTROSCOPY;

CHEMICAL OXYGEN DEMAND REMOVALS; DEGRADATION COEFFICIENTS; ELECTROCHEMICAL BEHAVIORS; ELECTROCHEMICAL PERFORMANCE; ELECTROCHEMICAL WINDOW; INTERFACIAL CHARGE TRANSFER RESISTANCE; TI4O7; TIO2 NANOTUBE ARRAYS;

CHEMICAL OXYGEN DEMAND;

EID: 84917706779     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.11.178     Document Type: Article

References (42)

1. F.C. Walsh, R.G.A. Wills, The continuing development of Magnéli phase titanium sub-oxides and Ebonex® electrodes, Electrochim. Acta 55 (2010) 6342-6351.
2. J.R. Smith, F.C. Walsh, R.L. Clarke, Electrodes based on Magnéli phase titanium oxides: the properties and applications of Ebonex® materials, J. Appl. Electrochem. 28 (1998) 1021-1033.
3. A.A. Gusev, G.E. Avvakumov, Ceramic electrodes based on Magneli phases of titanium oxides, Sci. Sintering 39 (2007) 51-57.
4. 2n-1 nanowires: Formation, optical, and transport properties, Appl. Phys. Lett. 92 (2008) 203117.
5. 7-supported PEMFC catalysts at high potentials, J. Electrochem. Soc. 155 (2008) B321-B326.
6. 2 electrocatalysts for application in SPE electrolysers, Electrochim. Acta 54 (2009) 6292-6299.
7. D. Portehault, V. Maneeratana, C. Candolfi, N. Deschler, I. Veremchuk, Y. Grin, C. Sanchez, M. Antonietti, Facile general route toward tunable Magneli nanostructures and their use as thermoelectric metal oxide/carbon nanocomposites, ACS Nano 5 (2011) 9052-9061.
8. 2n-1 and their photocatalytic activity under visible light, Appl. Catal. B: Environ. 88 (2009) 160-164.
9. n-1 (n = 2, 3, 4, 6), J. Am. Chem. Soc. 134 (2012) 10894-10898.
10. 3 atmosphere, Mater. Lett. 79 (2012) 42-44.
11. 2n-1, ECS Electrochem. Lett. 2 (2013) A21-A24.
12. 7 electrode for oxygen reduction reaction and its implication for zinc-air rechargeable batteries, Electrochim. Acta 55 (2010) 5891-5898.
13. T. Ioroi, T. Akita, S. Yamazaki, Z. Siroma, N. Fujiwara, K. Yasuda, Corrosionresistant PEMFC cathode catalysts based on a Magneli-phase titanium oxide support synthesized by pulsed UV laser irradiation, J. Electrochem. Soc. 158 (2011) C329-C334.
14. T. Ioroi, T. Akita, M. Asahi, S. Yamazaki, Z. Siroma, N. Fujiwara, K. Yasuda, Platinum-titanium alloy catalysts on a Magnéli-phase titanium oxide support for improved durability in polymer electrolyte fuel cells, J. Power Sources 223 (2013) 183-189.
15. G. Chen, S.R. Bare, T.E. Mallouk, Development of supported bifunctional electrocatalysts for unitized regenerative fuel cells, J. Electrochem. Soc. 149 (2002) A1092-A1099.
16. S.T. Nguyen, J.M. Lee, Y. Yang, X. Wang, Excellent durability of substoichiometric titanium oxide as a catalyst support for Pd in alkaline direct ethanol fuel cells, Ind. Eng. Chem. Res. 51 (2012) 9966-9972.
17. 2n-1 as corrosion-resistant PEM fuel cell catalyst support, J Solid State Electrochem. 16 (2012) 2515-2521.
18. G. Chen, E.A. Betterton, R.G. Arnold, Electrolytic oxidation of trichloroethylene using a ceramic anode, J. Appl. Electrochem. 29 (1999) 961-970.
19. D. Bejan, J.D. Malcolm, L. Morrison, N.J. Bunce, Mechanistic investigation of the conductive ceramic Ebonex® as an anode material, Electrochim. Acta 54 (2009) 5548-5556.
20. D. Bejan, E. Guinea, N.J. Bunce, On the nature of the hydroxyl radicals produced at boron-doped diamond and Ebonex® anodes, Electrochim. Acta 69 (2012) 275-281.
21. A.A. Gusev, G.E. Avvakumov, Conducting ceramic anodes based on titanium oxides, Chemistry for Sustainable Development 12 (2004) 313-318.
22. 2 nanotube arrays by an anodization method and their applications, Chem. Commun. 48 (2012) 6456-6471.
23. J. Iniesta, P.A. Michaud, M. Panizza, G. Cerisola, A. Aldaz, C. Comninellis, Electrochemical oxidation of phenol at boron-doped diamond electrode, Electrochim. Acta 46 (2001) 3573-3578.
24. 2-BDD heterojunction and its application as a photocatalyst for the simultaneous oxidation of an Azo dye and reduction of Cr(VI), Environ. Sci. Technol. 42 (2008) 3791-3796.
25. C. Comninellis, C. Pulgarin, Anodic oxidation of phenol for waste water treatment, J. Appl. Electrochem. 21 (1991) 703-708.
26. A.A. Gusev, G.E. Avvakumov, Synthesis of Ti4O7 Magneli phase using mechanical activation, Sci. Sintering 35 (2003) 141-145.
27. I.T. Chashechnikova, V.M. Vorotyntsev, V.V. Borovik, G.I. Golodets, I.V. Plyuto, A.P. Shpak, Strong metal-carrier interaction in cobalt- and nickel-titanium dioxide co-hydrogenation catalysts, Theor. Exp. Chem. 28 (1993) 176-178.
28. S. Tominaka, Y. Tsujimoto, Y. Matsushita, K. Yamaura, Synthesis of nanostructured reduced titanium oxide: Crystal structure transformation maintaining nanomorphology, Angew. Chem. Int. Ed. 50 (2011) 7418-7421.
29. L. Smart, E. Moore, Solid State Chemistry, Chapman and Hall, New York, 1992.
30. K. Yoshida, T. Kawai, T. Nambara, S. Tanemura, K. Saitoh, N. Tanaka, Direct observation of oxygen atoms in rutile titanium dioxide by spherical aberration corrected high-resolution transmission electron microscopy, Nanotechnology 17 (2006) 3944-3950.
31. J.E. Graves, D. Pletcher, R.L. Clarke, F.C. Walsh, The electrochemistry of Magnéli phase titanium oxide ceramic electrodes Part I. The deposition and properties of metal coatings, J. Appl. Electrochem. 21 (1991) 848-857.
32. 2 nanotube layers as highly efficient photocatalysts, Small 3 (2007) 300-304.
33. 2 nanotubes, Electrochem. Commun. 9 (2007) 2822-2826.
34. 2 particles, Phys. Rev. Lett. 77 (1996) 3427-3430.
35. 2 nanotubes arrays, Nano Lett. 7 (2006) 69-74.
36. 2 nanotubes, Angew. Chem. Int. Ed. 44 (2005) 7463-7465.
37. V. Linkov, L. Petrik, G. Vaivars, A. Maluleke, G. Gericke, Ceramic-based materials for electrochemical applications, Macromol. Symp. 178 (2002) 153-168.
38. J. Su, H. Yu, X. Quan, S. Chen, H. Wang, Hierarchically porous silicon with significantly improved photocatalytic oxidation capability for phenol degradation, Appl. Catal. B: Environ. 138-139 (2013) 427-433.
39. 2 heterojunction arrays for effective photoelectrocatalysis under simulated solar light irradiation, Appl. Catal. B: Environ. 90 (2009) 242-248.
40. Y. Zhao, H. Yu, X. Quan, S. Chen, H. Zhao, Y. Zhang, Preparation and characterization of vertically columnar boron doped diamond array electrode, Appl. Surf. Sci. 303 (2014) 419-424.
41. X. Chen, G. Chen, F. Gao, P.L. Yue, High-performance Ti/BDD electrodes for pollutant oxidation, Environ. Sci. & Technol. 37 (2003) 5021-5026.
42. G.Y. Chen, C.C. Waraksa, H.G. Cho, D.D. Macdonald, T.E. Mallouk, EIS studies of porous oxygen electrodes with discrete particles I. Impedance of oxide catalyst supports, J. Electrochem. Soc. 150 (2003) E423-E428.