A comprehensive mechanistic picture of the isomerizing alkoxycarbonylation of plant oils

Journal of the American Chemical Society

Volumn 136, Issue 48, 2014, Pages 16871-16881

  Roesle, Philipp ^a   Caporaso, Lucia ^b   Schnitte, Manuel ^a   Goldbach, Verena ^a   Cavallo, Luigi ^b,c   Mecking, Stefan ^a  

^a UNIVERSITY OF KONSTANZ   (Germany)

^b UNIVERSITY OF SALERNO   (Italy)

^c KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYLATION; ETHYLENE; MONOUNSATURATED FATTY ACIDS; SUBSTRATES;

ALCOHOLYSIS REACTIONS; ALKOXYCARBONYLATION; DOUBLE BOND POSITIONS; ENERGY DIFFERENCES; IDENTICAL CONDITIONS; METHANOL MOLECULES; METHOXYCARBONYLATION; STERICALLY DEMANDING;

ISOMERIZATION;

2 PROPANOL; ALCOHOL; ETHYLENE; FATTY ACID ESTER; HYDROCARBON; METHANOL; MONOUNSATURATED FATTY ACID; PALLADIUM COMPLEX; PHOSPHINE; PROPANOL; SUNFLOWER OIL; UNSATURATED FATTY ACID; ALKENE; CARBON MONOXIDE; ORGANOMETALLIC COMPOUND; PALLADIUM; VEGETABLE OIL;

ALCOHOLYSIS; ALKOXYCARBONYLATION; ARTICLE; CARBONYLATION; CATALYSIS; CHEMICAL BOND; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ISOMERIZATION; LIPID COMPOSITION; METHANOLYSIS; METHOXYCARBONYLATION; PRESSURE; PROTON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM;

ALKENES; CARBON MONOXIDE; CATALYSIS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PALLADIUM; PLANT OILS; STEREOISOMERISM;

EID: 84915820411     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja508447d     Document Type: Article

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