New phosphorus ligands for the rhodium-catalyzed isomerization/hydroformylation of internal octenes

Angewandte Chemie - International Edition

Volumn 40, Issue 9, 2001, Pages 1696-1698

  Selent, Detlef ^a   Hess, Dieter ^b   Wiese, Klaus Diether ^b   Röttger, Dirk ^b   Kunze, Christine ^c   Börner, Armin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b OXENO Olefinchemie GmbH   (Germany)

^c NONE

Author keywords

Homogeneous catalysis; Hydroformylation; Isomerization; P ligands; Rhodium

Indexed keywords

CATALYST ACTIVITY; ISOMERIZATION; RHODIUM COMPOUNDS;

HYDROFORMYLATION;

PHOSPHORUS COMPOUNDS;

ALKENE; PLASTICIZER;

ARTICLE; COMPLEX FORMATION; HYDROGENATION; ISOMERISM; STEREOCHEMISTRY; SYNTHESIS; THERMODYNAMICS;

EID: 0035805350     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010504)40:9<1696::AID-ANIE16960>3.0.CO;2-2     Document Type: Article

References (10)

1. C. D. Frohning, C. W. Kohlpaintner in Applied Homogeneous Catalysis with Organometallic Compounds, Vol. 1 (Eds.: B. Cornils, W. A. Herrmann), Wiley-VCH, Weinheim, 1996, pp. 3-25.
2. a) L. A. van der Veen, P. C. J. Kamer, P. W. N. M. van Leeuwen, Angew. Chem. 1999, 111, 349-351; Angew. Chem. Int. Ed. 1999, 38, 336-338;
3. a) L. A. van der Veen, P. C. J. Kamer, P. W. N. M. van Leeuwen, Angew. Chem. 1999, 111, 349-351; Angew. Chem. Int. Ed. 1999, 38, 336-338;
4. b) L. A. van der Veen, P. C. J. Kamer, P. W. N. M. van Leeuwen, Organometallics 1999, 18, 4765-4777.
5. D. Selent, K.-D. Wiese, D. Röttger, A. Börner, Angew. Chem. 2000, 112, 1694-1696; Angew. Chem. Int. Ed. 2000, 39, 1639-1641.
6. D. Selent, K.-D. Wiese, D. Röttger, A. Börner, Angew. Chem. 2000, 112, 1694-1696; Angew. Chem. Int. Ed. 2000, 39, 1639-1641.
7. E. Billig, A. G. Abatjoglou, D. R. Bryant (UCC Corp.), EP 0214622, 1987 [Chem. Abstr. 1987, 107, 25126m].
8. E. Billig, A. G. Abatjoglou, D. R. Bryant (UCC Corp.), EP 0214622, 1987 [Chem. Abstr. 1987, 107, 25126m].
9. The new compounds were obtained as a mixture of diastereomers and were fully characterized. The experimental details are given in the Supporting Information.
10. Industrial di-n-butene was also used consisting of a mixture of internal and structural isomers of octene. For the individual ligands the selectivities towards conversion into terminal aldehydes are comparable to the values given in Table 1.