Hydrometallurgical process for the recovery of metal values from spent lithium-ion batteries in citric acid media

Waste Management and Research

Volumn 32, Issue 11, 2014, Pages 1083-1093

  Chen, Xiangping ^a   Zhou, Tao ^a  

^a CENTRAL SOUTH UNIVERSITY   (China)

Author keywords

citric acid media; Leaching; recovery; selective precipitation; solvent extraction; spent lithium ion batteries

Indexed keywords

CITRIC ACID; HYDROMETALLURGY; IONS; LEACHING; LITHIUM; MANGANESE; MANGANESE COMPOUNDS; METAL RECOVERY; RECOVERY; SODIUM COMPOUNDS; SOLVENT EXTRACTION; UNDERWATER MINERAL RESOURCES;

ACID CONCENTRATIONS; EXPERIMENTAL CONDITIONS; HYDROMETALLURGICAL PROCESS; NICKEL AND COBALTS; OPTIMAL CONDITIONS; RECOVERY PERCENTAGES; SELECTIVE PRECIPITATION; SPENT LITHIUM-ION BATTERIES;

LITHIUM-ION BATTERIES;

AMMONIA; CITRIC ACID; COBALT; DIMETHYLGLYOXIME; LITHIUM; LITHIUM ION; MANGANESE; NICKEL; SODIUM; SODIUM DIHYDROGEN PHOSPHATE; METAL;

AQUEOUS SOLUTION; CITRIC ACID; CONCENTRATION (COMPOSITION); LEACHING; LITHIUM; METALLURGY; PRECIPITATION (CHEMISTRY);

ARTICLE; ELECTRIC BATTERY; LEACHING; METAL EXTRACTION; METAL RECOVERY; METALLURGY; PH; PRECIPITATION; SAPONIFICATION; SCANNING ELECTRON MICROSCOPY; TEMPERATURE; CHEMISTRY; POWER SUPPLY; PROCEDURES; RECYCLING;

CITRIC ACID; ELECTRIC POWER SUPPLIES; LITHIUM; METALS; RECYCLING;

EID: 84910651093     PISSN: 0734242X     EISSN: 10963669     Source Type: Journal    
DOI: 10.1177/0734242X14557380     Document Type: Article

References (30)

1. Borgstedt HU, Guminski C. IUPAC-NIST solubility data series. 75. Nonmetals in liquid alkali metals. Journal of Physical and Chemical Reference Data. 2001 ; 30: 835-1158
2. Castillo S, Ansart F, Laberty-Robert C, et al. Advances in the recovering of spent lithium battery compounds. Journal of Power Sources. 2002 ; 112: 247-254
3. Chang H, Wu W, Tu G, et al. Extraction of light rare earth in the system of P2O4-HCl-H3Cit. Chinese Rare Earths. 2008 ; 29: 18-21
4. Chen L, Tang X, Zhang Y, et al. Process for the recovery of cobalt oxalate from spent lithium-ion batteries. Hydrometallurgy. 2011 ; 108: 80-86
5. Contestabile M, Panero S, Scrosati B. A laboratory-scale lithium battery recycling process. Journal of Power Sources. 1999 ; 83: 75-78
6. Dorella G, Mansur MB. A study of the separation of cobalt from spent Li-ion battery residues. Journal of Power Sources. 2007 ; 170: 210-215
7. Ferreira DA, Prados LMZ, Majuste D, et al. Hydrometallurgical separation of aluminium, cobalt, copper and lithium from spent Li-ion batteries. Journal of Power Sources. 2009 ; 187: 238-246
8. Fouad OA, Farghaly FI, Bahgat M. A novel approach for synthesis of nanocrystalline γ-LiAlO2 from spent lithium-ion batteries. Journal of Analytical and Applied Pyrolysis. 2007 ; 78: 65-69
9. Hu C, Guo J, Wen J, et al. Preparation and electrochemical performance of nano-Co3O4 anode materials from spent Li-ion batteries for lithium-ion batteries. Journal of Material Science and Technology. 2013 ; 29: 215-220
10. Kang J, Senanayake G, Sohn J, et al. Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex 272. Hydrometallurgy. 2010 ; 100: 168-171
11. Lain MJ. Recycling of lithium cells and batteries. Journal of Power Sources. 2001 ; 97: 736-738
12. Lee CK, Rhee KI. Preparation of LiCoO2 from spent lithium-ion batteries. Journal of Power Sources. 2002 ; 109: 17-21
13. Lee CK, Rhee KI. Reductive leaching of cathodic active materials from lithium ion battery wastes. Hydrometallurgy. 2003 ; 68: 510-518
14. Li CR, Wang HC, Zhang X, et al. Recovery of hydrochloric acid from arginine production process solution by diffusion dialysis. Membrane Science and Technology. 2012 ; 32: 102-106
15. Li L, Chen R, Sun F, et al. Preparation of LiCoO2 films from spent lithium-ion batteries by a combined recycling process. Hydrometallurgy. 2011 ; 108: 220-225
16. Li L, Dunn JB, Zhang XX, et al. Recovery of metals from spent lithium-ion batteries with organic acids as leaching reagents and environmental assessment. Journal of Power Sources. 2013 ; 233: 180-189
17. Li L, Ge J, Chen R, et al. Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium ion batteries. Waste Management. 2010a ; 30: 2615-2621
18. Li L, Ge J, Wu F. Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant. Journal of Hazardous Materials. 2010b ; 176: 288-292
19. Li L, Zhai L, Zhang X, et al. Recovery of valuable metals from spent lithium-ion batteries by ultrasonic-assisted leaching process. Journal of Power Sources. 2014 ; 262: 380-385
20. Lupi C, Pasquali M. Electrolytic nickel recovery from lithium-ion batteries. Minerals Engineering. 2003 ; 16: 537-542
21. Mantuano DP, Dorella G, Elias RCA, et al. Analysis of a hydrometallurgical route to recover base metals from spent rechargeable batteries by liquid-liquid extraction with Cyanex 272. Journal of Power Sources. 2006 ; 159: 1510-1518
22. Martin D, Garcia MA, Diaz G, et al. A new zinc extraction application: spent domestic batteries treatment plant. Proceedings of the international solvent extraction conference ISEC'99 ; 1999 Barcelona ; 1999. 201.
23. Mishra D, Kim DJ, Ralph DE, et al. Bioleaching of metals from spent lithium ion batteries using Acidithiobacillus ferrooxidans. Waste Management. 2008 ; 28: 333-338
24. Nan J, Han D, Zuo X. Recovery of metal values from spent lithium-ion batteries with chemical deposition and solvent extraction. Journal of Power Sources. 2005 ; 152: 278-284
25. Paulino JH, Busnardo NG, Afonso JC. Recovery of valuable elements from spent Li-batteries. Journal of Hazardous Materials. 2008 ; 150: 843-849
26. Shin SM, Kim NH, Sohn JS, et al. Development of a metal recovery process from Li-ion battery wastes. Hydrometallurgy. 2005 ; 79: 172-181
27. Swain B, Jeong J, Lee JC, et al. Separation of cobalt and lithium from mixed sulphate solution using Na-Cyanex 272. Hydrometallurgy. 2006 ; 84: 130-138
28. Swain B, Jeong J, Lee J, et al. Hydrometallurgical process for recovery of cobalt from waste cathodic active material generated during manufacturing of lithium ion batteries. Journal of Power Sources. 2007 ; 167: 536-544
29. Zeng GS, Deng XR, Luo SL, et al. A copper-catalyzed bioleaching process for enhancement of cobalt dissolution from spent lithium-ion batteries. Journal of Hazardous Materials. 2012 ; 199: 164-169
30. Zhang P, Yokoyama T, Itabashi O, et al. Hydrometallurgical process for recovery of metal values from spent nickel-metal hydride secondary batteries. Hydrometallurgy. 1998 ; 50: 61-75