VOC-OHM: A new technique for rapid measurements of ambient total OH reactivity and volatile organic compounds using a single proton transfer reaction mass spectrometer

International Journal of Mass Spectrometry

Volumn 374, Issue , 2014, Pages 55-63

  Kumar, V ^a   Sinha, V ^a  

^a INDIAN INSTITUTE OF SCIENCE EDUCATION AND RESEARCH MOHALI   (India)

Author keywords

Air; CRM; Hydroxyl; OH reactivity; PTR MS; VOC

Indexed keywords

EID: 84910058574     PISSN: 13873806     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijms.2014.10.012     Document Type: Article

References (31)

1. D.E. Heard, and M.J. Pilling Measurement of OH and HO2 in the troposphere Chem. Rev. 103 2003 5163 5198
2. J. Lelieveld, F.J. Dentener, W. Peters, and M.C. Krol On the role of hydroxyl radicals in the self-cleansing capacity of the troposphere Atmos. Chem. Phys. 4 2004 2337 2344
3. M.L. Parry, O.F. Canziani, J.P. Palutikof, P.J. van der Linden, and C.E. Hanson Climate Change 2007: Impacts, Adaptation and Vulnerability: Contribution of Working Group II to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change 2007 Cambridge University Press
4. H. Levy Normal atmosphere: large radical and formaldehyde concentrations predicted Science 173 1971 141 143
5. V. Sinha, J. Williams, J. Lelieveld, T.M. Ruuskanen, M.K. Kajos, J. Patokoski, H. Hellen, H. Hakola, D. Mogensen, M. Boy, J. Rinne, and M. Kulmala OH reactivity measurements within a boreal forest: evidence for unknown reactive emissions Environ. Sci. Technol. 44 2010 6614 6620
6. P. Di Carlo, W.H. Brune, M. Martinez, H. Harder, R. Lesher, X. Ren, T. Thornberry, M.A. Carroll, V. Young, P.B. Shepson, D. Riemer, E. Apel, and C. Campbell Missing OH reactivity in a forest: evidence for unknown reactive biogenic VOCs Science 304 2004 722 725
7. T.A. Kovacs, W.H. Brune, H. Harder, M. Martinez, J.B. Simpas, G.J. Frost, E. Williams, T. Jobson, C. Stroud, V. Young, A. Fried, and B. Wert Direct measurements of urban OH reactivity during Nashville SOS in summer 1999 J. Environ. Monit. 5 2003 68 74
8. V. Sinha, J. Williams, J.M. Diesch, F. Drewnick, M. Martinez, H. Harder, E. Regelin, D. Kubistin, H. Bozem, Z. Hosaynali-Beygi, H. Fischer, M.D. Andrés-Hernández, D. Kartal, J.A. Adame, and J. Lelieveld Constraints on instantaneous ozone production rates and regimes during DOMINO derived using in-situ OH reactivity measurements Atmos. Chem. Phys. 12 2012 7269 7283
9. A. Hofzumahaus, F. Rohrer, K. Lu, B. Bohn, T. Brauers, C.-C. Chang, H. Fuchs, F. Holland, K. Kita, Y. Kondo, X. Li, S. Lou, M. Shao, L. Zeng, A. Wahner, and Y. Zhang Amplified trace gas removal in the troposphere Science 324 2009 1702 1704
10. T. Ingham, A. Goddard, L.K. Whalley, K.L. Furneaux, P.M. Edwards, C.P. Seal, D.E. Self, G.P. Johnson, K.A. Read, J.D. Lee, and D.E. Heard A flow-tube based laser-induced fluorescence instrument to measure OH reactivity in the troposphere Atmos. Meas. Tech. 2 2009 465 477
11. T. Kovacs, and W. Brune Total OH Loss Rate Measurement J. Atmos. Chem. 39 2001 105 122
12. Y. Sadanaga, A. Yoshino, K. Watanabe, A. Yoshioka, Y. Wakazono, Y. Kanaya, and Y. Kajii Development of a measurement system of OH reactivity in the atmosphere by using a laser-induced pump and probe technique Rev. Sci. Instrum. 75 2004 2648 2655
13. V. Sinha, J. Williams, J.N. Crowley, and J. Lelieveld The Comparative Reactivity Method - a new tool to measure total OH Reactivity in ambient air Atmos. Chem. Phys. 2008 2213 2227
14. A.C. Nölscher, V. Sinha, S. Bockisch, T. Klüpfel, and J. Williams Total OH reactivity measurements using a new fast Gas Chromatographic Photo-Ionization Detector (GC-PID) Atmos. Meas. Tech. 5 2012 2981 2992
15. W. Lindinger, A. Hansel, and A. Jordan On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) medical applications, food control and environmental research Int. J. Mass Spectrom. Ion Process. 173 1998 191 241
16. J. de Gouw, and C. Warneke Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry Mass Spectrom. Rev. 26 2007 223 257
17. V. Sinha, T.G. Custer, T. Kluepfel, and J. Williams The effect of relative humidity on the detection of pyrrole by PTR-MS for OH reactivity measurements Int. J. Mass spectrom. 282 2009 108 111
18. V. Sinha, V. Kumar, and C. Sarkar Chemical composition of pre-monsoon air in the Indo-Gangetic Plain measured using a new air quality facility and PTR-MS: high surface ozone and strong influence of biomass burning Atmos. Chem. Phys. 14 2014 5921 5941
19. T.J. Dillon, M.E. Tucceri, K. Dulitz, A. Horowitz, L. Vereecken, and J.N. Crowley Reaction of hydroxyl radicals with C4H5N (Pyrrole): temperature and pressure dependent rate coefficients J. Phys. Chem. A 116 2012 6051 6058
20. R. Atkinson, S.M. Aschmann, A.M. Winer, and W.P.L. Carter Rate constants for the gas phase reactions of OH radicals and O3 with pyrrole at 295 ± 1 K and atmospheric pressure Atmos. Environ. (1967) 18 1984 2105 2107
21. A.R. Curtis, and W.P. Sweetenham Facsimile/Chekmat Users Manual, AERE Report R-12805 1988 Her Majesty's Stationary Office England
22. A.C. Nölscher, J. Williams, V. Sinha, T. Custer, W. Song, A.M. Johnson, R. Axinte, H. Bozem, H. Fischer, N. Pouvesle, G. Phillips, J.N. Crowley, P. Rantala, J. Rinne, M. Kulmala, D. Gonzales, J. Valverde-Canossa, A. Vogel, T. Hoffmann, H.G. Ouwersloot, J. Vilà-Guerau de Arellano, and J. Lelieveld Summertime total OH reactivity measurements from boreal forest during HUMPPA-COPEC 2010 Atmos. Chem. Phys. 12 2012 8257 8270
23. C. Dolgorouky, V. Gros, R. Sarda-Esteve, V. Sinha, J. Williams, N. Marchand, S. Sauvage, L. Poulain, J. Sciare, and B. Bonsang Total OH reactivity measurements in Paris during the 2010 MEGAPOLI winter campaign Atmos. Chem. Phys. 12 2012 9593 9612
24. R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, J. Troe, and I. Subcommittee Evaluated kinetic and photochemical data for atmospheric chemistry: volume II - gas phase reactions of organic species Atmos. Chem. Phys. 6 2006 3625 4055
25. C. Ammann, A. Brunner, C. Spirig, and A. Neftel Technical note: Water vapour concentration and flux measurements with PTR-MS Atmos. Chem. Phys. 6 2006 4643 4651
26. C.N. Hewitt, and A.V. Jackson Handbook of Atmospheric Science: Principles and Applications 2003 Wiley
27. S. Kato, T. Sato, and Y. Kajii A method to estimate the contribution of unidentified VOCs to OH reactivity Atmos. Environ. 45 2011 5531 5539
28. R. Atkinson, and J. Arey Atmospheric degradation of volatile organic compounds Chem. Rev. 103 2003 4605 4638
29. R. Atkinson, S.M. Aschmann, and W.P.L. Carter Kinetics of the reactions of O3 and OH radicals with furan and thiophene at 298 ± 2 K Int. J. Chem. Kinet. 15 1983 51 61
30. E. Boscaini, T. Mikoviny, A. Wisthaler, E.v. Hartungen, and T.D. Märk Characterization of wine with PTR-MS Int. J. Mass spectrom. 239 2004 215 219
31. F. Biasioli, F. Gasperi, C. Yeretzian, and T.D. Märk PTR-MS monitoring of VOCs and BVOCs in food science and technology Trends Anal. Chem. 30 2011 968 977