New tracers identify hydraulic fracturing fluids and accidental releases from oil and gas operations

Environmental Science and Technology

Volumn 48, Issue 21, 2014, Pages 12552-12560

  Warner, N R ^a,b   Darrah, T H ^c   Jackson, R B ^a,d   Millot, R ^e   Kloppmann, W ^e   Vengosh, A ^a  

^a DUKE UNIVERSITY   (United States)

^b Lamont Doherty Earth Observatory   (United States)

^c OHIO STATE UNIVERSITY   (United States)

^d STANFORD UNIVERSITY   (United States)

^e BRGM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BORON; EFFLUENT TREATMENT; EFFLUENTS; EXPLORATORY GEOCHEMISTRY; FRACTURING FLUIDS; ISOTOPES; LITHIUM; LITHIUM COMPOUNDS; NATURAL GAS WELL PRODUCTION; PETROLEUM RESERVOIR ENGINEERING; PETROLEUM RESERVOIRS; PRODUCED WATER; SHALE; TRACERS; WASTEWATER DISPOSAL; WASTEWATER TREATMENT;

CONVENTIONAL OIL AND GAS; ENVIRONMENTAL APPLICATIONS; GEOCHEMICAL FINGERPRINTS; HYDRAULIC FRACTURING PROCESS; HYDROCARBON RESOURCES; OIL AND GAS OPERATIONS; TREATMENT AND DISPOSAL; UNCONVENTIONAL OIL AND GAS;

HYDRAULIC FRACTURING;

BORON; FRESH WATER; HYDROCARBON; ISOTOPE; LITHIUM; OIL; STABLE ISOTOPE; SURFACE WATER; TRACER; INDUSTRIAL WASTE; WASTE WATER; WATER POLLUTANT;

FRACTIONATION; GAS WELL; HYDRAULIC FRACTURE; OPERATIONS TECHNOLOGY; VOLUME; WASTEWATER; WATER TREATMENT;

ARTICLE; GAS; GEOCHEMISTRY; HYDRAULIC PERMEABILITY; ION PAIR CHROMATOGRAPHY; IONIZATION; MIDDLE DEVONIAN; OIL AND GAS FIELD; RECYCLING; UNITED STATES; WASTE WATER MANAGEMENT; CHEMISTRY; INDUSTRIAL WASTE; WASTE WATER; WATER POLLUTANT;

PENNSYLVANIA; UNITED STATES; VIRGINIA;

FRESH WATER; INDUSTRIAL WASTE; OIL AND GAS FIELDS; PENNSYLVANIA; WASTE WATER; WATER POLLUTANTS, CHEMICAL; WEST VIRGINIA;

EID: 84908592714     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es5032135     Document Type: Article

References (42)

1. Vidic, R. D.; Brantley, S. L.; Vandenbossche, J. M.; Yoxtheimer, D.; Abad, J. D., Impact of shale gas development on regional water quality. Science 2013, 340, (6134).
2. USEIA. Review of Emerging Resources: U.S. Shale Gas and Shale Oil Plays; U.S. Department of Energy, 2011.
3. Abualfaraj Noura, G. P. L.; Olson Mira, S. Characterization of Marcellus Shale flowback water Environ. Eng. Sci. 2014, 31 (9) 514-524
4. Vengosh, A.; Jackson, R.; Warner, N. R.; Darrah, T.; Kondash, A. A critical review of the risks to water resources from unconventional shale gas development and hydraulic fracturing in the United States Environ. Sci. Technol. 2014, 48 (15) 8334-8348
5. Lutz, B. D.; Lewis, A. N.; Doyle, M. W. Generation, transport, and disposal of wastewater associated with Marcellus Shale gas development Water Resour. Res. 2013, 49 (2) 647-656
6. Haluszczak, L. O.; Rose, A. W.; Kump, L. R. Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA. Appl. Geochem. 2013, 28, 55-61
7. Hladik, M. L.; Focazio, M. J.; Engle, M. Discharges of produced waters from oil and gas extraction via wastewater treatment plants are sources of disinfection by-products to receiving streams Sci. Total Environ. 2014, 466, 1085-1093
8. Wilson, J.; Vanbriesen, J. Source water changes and energy extraction activities in the Monongahela River, 2009-2012 Environ. Sci. Technol. 2013, 47 (21) 12575-12582
9. Warner, N. R.; Christie, C. A.; Jackson, R. B.; Vengosh, A. Impacts of shale gas wastewater disposal on water quality in western Pennsylvania Environ. Sci. Technol. 2013, 47 (20) 11849-11857
10. Osborn, S. G.; Vengosh, A.; Warner, N. R.; Jackson, R. B. Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing Proc. Natl. Acad. Sci. U. S. A. 2011, 108, 8172-8176
11. Molofsky, L. J.; Connor, J. A.; Wylie, A. S.; Wagner, T.; Farhat, S. K. Evaluation of methane sources in groundwater in northeastern Pennsylvania Groundwater 2013, 51 (3) 333-349
12. Jackson, R. B.; Vengosh, A.; Darrah, T. H.; Warner, N. R.; Down, A.; Poreda, R. J.; Osborn, S. G.; Zhao, K.; Karr, J. D. Increased stray gas abundance in a subset of drinking water wells near Marcellus shale gas extraction Proc. Natl. Acad. Sci. U. S. A. 2013, 110 (28) 11250-11255
13. Darrah, T. H.; Vengosh, A.; Jackson, R. B.; Warner, N. R.; Poreda, R. J. Noble gases identify the mechanisms of fugitive gas contamination in drinking-water wells overlying the Marcellus and Barnett Shales Proc. Natl. Acad. Sci. U. S. A. 2014, 111, 14076-14081
14. Kassotis, C. D.; Tillitt, D. E.; Davis, J. W.; Hormann, A. M.; Nagel, S. C. Estrogen and androgen receptor activities of hydraulic fracturing chemicals and surface and ground water in a drilling-dense region Endocrinology 2013, 155 (3) 897-907
15. Kolesar Kohl, C. A.; Capo, R. C.; Stewart, B. W.; Wall, A. J.; Schroeder, K. T.; Hammack, R. W.; Guthrie, G. D. Strontium isotopes test long-term zonal isolation of injected and Marcellus formation water after hydraulic fracturing Environ. Sci. Technol. 2014, 48 (16) 9867-9873
16. Johnson, J. D.; Graney, J. R.; Capo, R. C.; Stewart, B. W., Identification and quantification of regional brine and road salt sources in watersheds along the New York/Pennsylvania border, U.S.A. Appl. Geochem.
17. Warner, N. R.; Jackson, R. B.; Darrah, T. H.; Osborn, S. G.; Down, A.; Zhao, K.; White, A.; Vengosh, A. Geochemical evidence for possible natural migration of Marcellus formation brine to shallow aquifers in Pennsylvania Proc. Natl. Acad. Sci. U. S. A. 2012, 109 (30) 11961-11966
18. Warner, N. R.; Kresse, T. M.; Hays, P. D.; Down, A.; Karr, J. D.; Jackson, R. B.; Vengosh, A. Geochemical and isotopic variations in shallow groundwater in areas of the Fayetteville Shale development, north-central Arkansas Appl. Geochem. 2013, 35, 207-220
19. Osborn, S. G.; McIntosh, J. C. Chemical and isotopic tracers of the contribution of microbial gas in Devonian organic-rich shales and reservoir sandstones, northern Appalachian Basin Appl. Geochem. 2010, 25 (3) 456-471
20. Osborn, S. G.; McIntosh, J. C.; Hanor, J. S.; Biddulph, D. Iodine-129, 87Sr/86Sr, and trace elemental geochemistry of northern Appalachian Basin brines: Evidence for basinal-scale fluid migration and clay mineral diagenesis Am. J. Sci. 2012, 312 (3) 263-287
21. Dresel, P.; Rose, A. Chemistry and Origin of Oil and Gas Well Brines in Western Pennsylvania: Pennsylvania Geological Survey; Pennsylvania Department of Conservation and Natural Resources, 2010.
22. Vengosh, A.; Starinsky, A.; Kolodny, Y.; Chivas, A. R.; Raab, M. Boron isotope variations during fractional evaporation of sea-water-New constraints on the marine vs nonmarine debate Geology 1992, 20 (9) 799-802
23. Spivack, A. J.; Palmer, M. R.; Edmond, J. M. The sedimentary cycle of the boron isotopes Geochim. Cosmochim. Acta 1987, 51 (7) 1939-1949
24. Vengosh, A.; Starinsky, A.; Kolodny, Y.; Chivas, A. R. Boron isotope geochemistry as a tracer for the evolution of brines and associated hot-springs from the Dead-Sea, Israel Geochim. Cosmochim. Acta 1991, 55 (6) 1689-1695
25. Macpherson, G. L.; Capo, R. C.; Stewart, B. W.; Phan, T. T.; Schroeder, K.; Hammack, R. W. Temperature-dependent Li isotope ratios in Appalachian Plateau and Gulf Coast Sedimentary Basin saline water Geofluids 2014, 10.1111/gfl.12084
26. Raitzsch, M.; Hönisch, B. Cenozoic boron isotope variations in benthic foraminifers Geology 2013, 10.1130/G34031.1
27. Hosterman, J.; Whitlow, S. Clay Mineralogy of Devonian Shales in the Appalachian Basin; U.S. Goelogical Survey, 1983
28. Williams, L. B.; Hervig, R. L.; Holloway, J. R.; Hutcheon, I. Boron isotope geochemistry during diagenesis. Part I. Experimental determination of fractionation during illitization of smectite Geochim. Cosmochim. Acta 2001, 65 (11) 1769-1782
29. Williams, L. B.; Hervig, R. L.; Wieser, M. E.; Hutcheon, I. The influence of organic matter on the boron isotope geochemistry of the gulf coast sedimentary basin, USA Chem. Geol. 2001, 174 (4) 445-461
30. Hayes, T. Sampling and Analysis of Water Streams Associated with the Development of Marcellus Shale Gas. http://catskillcitizens.org/learnmore/20100916IOGAResponsetoDECChesapeake-IOGAResponsetoDEC.pdf.
31. Millot, R.; V, N.; Gaillardet, J. Behaviour of lithium and its isotopes during weathering in the Mackenzie Basin, Canada Geochim. Cosmochim. Acta 2010, 74, 3897-3912
32. Pike, B., Current NETL Water Management R&D Efforts In Drilling Engineering Association Quarterly Forum, 2010; Vol. 2014, http://dea-global.org/wp-content/uploads/2012/01/DEA-Water-Presentation.pdf.
33. Bottomley, D. J.; Katz, A.; Chan, L. H.; Starinsky, A.; Douglas, M.; Clark, I. D.; Raven, K. G. The origin and evolution of Canadian Shield brines: Evaporation or freezing of seawater? New lithium isotope and geochemical evidence from the Slave craton Chem. Geol. 1999, 155 (3-4) 295-320
34. Stueber, A. M.; Walter, L. M.; Huston, T. J.; Pushkar, P. Formation waters from Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on evolution and migration Geochim. Cosmochim. Acta 1993, 57 (4) 763-784
35. Son, J.-H.; Carlson, K. Real-time surrogate analysis for potential oil and gas contamination of drinking water resources Appl. Water Sci. 2014, 1-7
36. Ferrar, K. J.; Michanowicz, D. R.; Christen, C. L.; Mulcahy, N.; Malone, S. L.; Sharma, R. K. Assessments of effluent contaminants from three wastewater treatment plants discharging Marcellus Shale wastewater to surface waters in Pennsylvania Environ. Sci. Technol. 2013, 47 (7) 3472-3481
37. Chapman, E. C.; Capo, R. C.; Stewart, B. W.; Kirby, C. S.; Hammack, R. W.; Schroeder, K. T.; Edenborn, H. M. Geochemical and strontium isotope characterization of produced waters from marcellus shale natural gas extraction Environ. Sci. Technol. 2012, 46 (6) 3545-3553
38. Huh, Y.; Chan, L.-H.; Zhang, L.; Edmond, J. M. Lithium and its isotopes in major world rivers: Implications for weathering and the oceanic budget Geochim. Cosmochim. Acta 1998, 62 (12) 2039-2051
39. Lemarchand, D.; Gaillardet, J.; Lewin, é.; Allègre, C. J. Boron isotope systematics in large rivers: implications for the marine boron budget and paleo-pH reconstruction over the Cenozoic Chem. Geol. 2002, 190 (1-4) 123-140
40. Vengosh, A.; Heumann, K. G.; Juraske, S.; Kasher, R. Boron isotope application for tracing sources of contamination in groundwater Environ. Sci. Technol. 1994, 28 (11) 1968-1974
41. Cluff, M.; Hartsock, A.; MacRae, J.; Carter, K.; Mouser, P. J. Temporal changes in microbial ecology and geochemistry in produced water from hydraulically fractured Marcellus Shale gas wells Environ. Sci. Technol. 2014, 48 (11) 6508-6517
42. Senior, L. A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania Sci. Invest. Rep. (U. S. Geol. Surv.) 2012-13, 2014-5117