Methanol reactivity on silica-supported ceria nanoparticles

Topics in Catalysis

Volumn 57, Issue 14, 2014, Pages 1229-1235

  Uhlrich, John J ^a   Yang, Bing ^a   Shaikhutdinov, Shamil ^a  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

Author keywords

Ceria; Methanol; Model catalysts

Indexed keywords

CATALYSTS; CERIUM COMPOUNDS; INFRARED SPECTROSCOPY; NANOPARTICLES; TEMPERATURE; TEMPERATURE PROGRAMMED DESORPTION;

CATALYTIC PROCESS; CERIA NANOPARTICLES; CERIA PARTICLES; COORDINATED SITES; DEHYDROGENATION OF METHANOL; LOW TEMPERATURES; MODEL CATALYSTS; TEST REACTIONS;

METHANOL;

EID: 84908057468     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11244-014-0296-2     Document Type: Article

References (32)

1. Bernal S, Kaspar J, Trovarelli A (1999) Recent progress in catalysis by ceria and related compounds-preface. Catal Today 50(2):173-443
2. 2-containing materials. Catal Rev-Sci Eng 38(4):439-520
3. Jen HW et al (1999) Characterization of model automotive exhaust catalysts: Pd on ceria and ceria-zirconia supports. Catal Today 50(2):309-328
4. Wachs IE (2005) Recent conceptual advances in the catalysis science of mixed metal oxide catalytic materials. Catal Today 100(1-2):79-94
5. 5: bulk solid, nanosized clusters, species supported on silica and alumina, cluster cations and anions. Dalton Trans 19:3116-3121
6. Ganduglia-Pirovano MV et al (2010) Role of ceria in oxidative dehydrogenation on supported vanadia catalysts. J Am Chem Soc 132(7):2345-2349
7. Migani A et al (2010) Greatly facilitated oxygen vacancy formation in ceria nanocrystallites. Chem Commun 46(32):5936-5938
8. Migani A et al (2010) Dramatic reduction of the oxygen vacancy formation energy in ceria particles: a possible key to their remarkable reactivity at the nanoscale. J Mater Chem 20(46): 10535-10546
9. Loschen C et al (2008) Density functional studies of model cerium oxide nanoparticles. Phys Chem Chem Phys 10(37): 5730-5738
10. 2 films. J Vac Sci Technol B 21(3):1169-1175
11. 2-x nanoparticles. Surf Sci 457(3):L437-L440
12. Qiu L et al (2006) Comparative XPS study of surface reduction for nanocrystalline and microcrystalline ceria powder. Appl Surf Sci 252(14):4931-4935
13. x nanoparticles. J Phys Chem C 113(15):6042-6049
14. 2 adsorption. Langmuir 26(21):16595-16606
15. Murugan B, Ramaswamy AV (2007) Defect-site promoted surface reorganization in nanocrystalline ceria for the low-temperature activation of ethylbenzene. J Am Chem Soc 129(11):3062
16. Zhou K et al (2005) Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planes. J Catal 229(1):206-212
17. Kuhlenbeck H, Shaikhutdinov S, Freund H-J (2013) Well-ordered transition metal oxide layers in model catalysis-a series of case studies. Chem Rev 113(6):3986-4034
18. Mullins DR, Radulovic PV, Overbury SH (1999) Ordered cerium oxide thin films grown on Ru(0001) and Ni(111). Surf Sci 429(1-3):186-198
19. Siokou A, Nix RM (1999) Interaction of methanol with welldefined ceria surfaces: reflection/absorption infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature-programmed desorption study. J Phys Chem B 103(33):6984-6997
20. 2(111) surface: a density functional theory study. J Phys Chem C 111(28):10514-10522
21. Beste A et al (2008) Adsorption and dissociation of methanol on the fully oxidized and partially reduced (111) cerium oxide surface: dependence on the configuration of the cerium 4f electrons. Surf Sci 602(1):162-175
22. Badri A, Binet C, Lavalley J-C (1997) Use of methanol as an IR molecular probe to study the surface of polycrystalline ceria. J Chem Soc, Faraday Trans 93(6):1159-1168
23. Li C et al (1990) Spectroscopic identification of adsorbed species derived from adsorption and decomposition of formic acid, methanol, and formaldehyde on cerium oxide. J Catal 125(2): 445-455
24. Binet C, Daturi M, Lavalley J-C (1999) IR study of polycrystalline ceria properties in oxidised and reduced states. Catal Today 50(2):207-225
25. Ferrizz RM et al (2001) Structure sensitivity of the reaction of methanol on ceria. Langmuir 17(8):2464-2470
26. Mullins DR, Robbins MD, Zhou J (2006) Adsorption and reaction of methanol on thin-film cerium oxide. Surf Sci 600(7): 1547-1558
27. Löffler D et al (2010) Growth and structure of crystalline silica sheet on Ru(0001). Phys Rev Lett 105(14):146104
28. 4] tetrahedra. Phys Chem Chem Phys 14(32):11344-11351
29. Yang B et al (2013) Hydroxylation of metal-supported sheet-like silica films. J Phys Chem C 117(16):8336-8344
30. Wlodarczyk R et al (2013) The atomic structure of an ultrathin Fe-silicate film grown on a metal: a monolayer of clay? J Am Chem Soc 135(51):19222-19228
31. Abbott HL et al (2010) Relating methanol oxidation to the structure of ceria-supported vanadia monolayer catalysts. J Catal 272(1):82-91
32. Fronzi M et al (2009) Stability and morphology of cerium oxide surfaces in an oxidizing environment: a first-principles investigation. J Chem Phys 131(10):104701-104716