Cu(II)-mediated atom transfer radical polymerization of methyl methacrylate via a strategy of thermo-regulated phase-separable catalysis in a liquid/liquid biphasic system: Homogeneous catalysis, facile heterogeneous separation, and recycling

Macromolecular Rapid Communications

Volumn 35, Issue 18, 2014, Pages 1615-1621

  Pan, Jinlong ^a   Zhang, Bingjie ^a   Jiang, Xiaowu ^a   Zhang, Lifen ^a   Cheng, Zhenping ^a   Zhu, Xiulin ^a  

^a SOOCHOW UNIVERSITY   (China)

Author keywords

ATRP; Heterogeneous separation; Homogeneous catalysis; Recycling; Thermo regulated phase separable catalysis (TPSC)

Indexed keywords

ACRYLIC MONOMERS; BROMINE COMPOUNDS; CATALYSIS; CATALYSTS; COPPER COMPOUNDS; ESTERS; FREE RADICAL REACTIONS; MOLECULAR WEIGHT DISTRIBUTION; POLYMERIZATION; RECYCLING; SEPARATION; XYLENE;

BIPHASIC SYSTEMS; CONTROLLED MOLECULAR WEIGHT; DIFFERENT LAYERS; HOMOGENEOUS CATALYSIS; HOMOGENEOUS CONDITIONS; METHYL METHACRYLATES; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; THERMO-REGULATED PHASE-SEPARABLE CATALYSIS (TPSC);

ATOM TRANSFER RADICAL POLYMERIZATION;

4-XYLENE; COPPER; CUPROUS ION; LIGAND; MACROGOL DERIVATIVE; METHACRYLIC ACID METHYL ESTER; SOLVENT; XYLENE;

CATALYSIS; CHEMICAL MODEL; CHEMISTRY; KINETICS; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; TEMPERATURE;

CATALYSIS; COPPER; KINETICS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; METHYLMETHACRYLATE; MODELS, CHEMICAL; MOLECULAR WEIGHT; POLYETHYLENE GLYCOLS; POLYMERIZATION; SOLVENTS; TEMPERATURE; XYLENES;

EID: 84908037394     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.201400277     Document Type: Article

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