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Volumn 4, Issue 9, 2014, Pages 3034-3038

Iridium, rhodium, and ruthenium catalysts for the "aldehyde-water shift" reaction

Author keywords

Aldehyde oxidation; Dehydrogenation; Disproportionation; Homogeneous catalysis; Water

Indexed keywords

WATER;

EID: 84907834082     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs500843a     Document Type: Article
Times cited : (50)

References (29)
  • 18
    • 84907853250 scopus 로고    scopus 로고
    • note
    • For synthetic details, see Supporting Information.
  • 19
    • 84907853249 scopus 로고    scopus 로고
    • note
    • 2rapidly decomposes to heterogeneous material.
  • 20
    • 84907853248 scopus 로고    scopus 로고
    • note
    • For example, if 4 mmol of aldehyde is converted to products, and 3 mmol (75%) of the observed product is carboxylic acid, 1 mmol of the carboxylic acid product results from disproportionation, and 2 mmol result from AWS.
  • 28
    • 84907853247 scopus 로고    scopus 로고
    • note
    • Rh(bpy) was also tested utilizing propionaldehyde as substrate. This led to aldol products.
  • 29
    • 84907853246 scopus 로고    scopus 로고
    • note
    • 31% aldol product was also observed using Ir(bpy) with propionaldehyde as substrate. This was not observed using acetaldehyde in the presence of Ir(bpy).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.