Stabilizing single Ni adatoms on a two-dimensional porous titania overlayer at the SrTiO3(110) surface

Journal of Physical Chemistry C

Volumn 118, Issue 34, 2014, Pages 19904-19909

  Wang, Zhiming ^a   Hao, Xianfeng ^a   Gerhold, Stefan ^a   Mares, Petr ^a,d   Wagner, Margareta ^a   Bliem, Roland ^a   Schulte, Karina ^b   Schmid, Michael ^a   Franchini, Cesare ^c   Diebold, Ulrike ^a  

^a VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^b LUND UNIVERSITY   (Sweden)

^c UNIVERSITY OF VIENNA   (Austria)

^d BRNO UNIVERSITY OF TECHNOLOGY   (Czech Republic)

Author keywords

[No Author keywords available]

Indexed keywords

NANOPORES; NICKEL; PHOTOELECTRON SPECTROSCOPY; SCANNING TUNNELING MICROSCOPY; STRONTIUM TITANATES; ADATOMS; STRONTIUM ALLOYS; TITANIUM DIOXIDE;

CONDUCTION-BAND MINIMUM; OXIDE SUPPORTS; POROUS TITANIA; POSITIVELY CHARGED; ROOM TEMPERATURE; SINGLE ADATOM; SURFACE FORMS; WELL-DISPERSED;

ADATOMS; DENSITY FUNCTIONAL THEORY;

EID: 84906873787     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp506234r     Document Type: Article

References (43)

1. Ternes, M.; Heinrich, A. J.; Schneider, W.-D. Spectroscopic Manifestations of the Kondo Effect on Single Adatoms J. Phys.: Condens. Matter. 2009, 21, 053001
2. Wiesendanger, R. Single-atom Magnetometry Curr. Opin. Solid State Mater. Sci. 2011, 15, 1-7
3. Yang, X.-F.; Wang, A.; Qiao, B.; Li, J.; Liu, J.; Zhang, T. Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis Acc. Chem. Res. 2013, 46, 1740-1748
4. 1/FeOx Nat. Chem. 2011, 3, 634-641
5. x Single-Atom Catalyst in Water Gas Shift Reaction J. Am. Chem. Soc. 2013, 135, 15314-15317
6. 3(010) Surface J. Am. Chem. Soc. 2013, 135, 12634-12645
7. 2 Surfaces Science 2009, 326, 826-829
8. 4(001) Phys. Rev. Lett. 2012, 108, 216103
9. Giordano, L.; Pacchioni, G.; Goniakowski, J.; Nilius, N.; Rienks, E. D. L.; Freund, H.-J. Charging of Metal Adatoms on Ultrathin Oxide Films: Au and Pd on FeO/Pt(111) Phys. Rev. Lett. 2008, 101, 026102
10. Nilius, N. Properties of Oxide Thin Films and Their Adsorption Behavior Studied by Scanning Tunneling Microscopy and Conductance Spectroscopy Surf. Sci. Rep. 2009, 64, 595-659
11. 4 Model Catalyst Nat. Mater. 2013, 12, 724-728
12. Martinez, U.; Jerratsch, J.-F.; Nilius, N.; Giordano, L.; Pacchioni, G.; Freund, H.-J. Tailoring the Interaction Strength Between Gold Particles and Silica Thin Films via Work Function Control Phys. Rev. Lett. 2009, 103, 056801
13. Jerratsch, J.-F.; Nilius, N.; Topwal, D.; Martinez, U.; Giordano, L.; Pacchioni, G.; Freund, H.-J. Stabilizing Monomeric Iron Species in a Porous Silica/Mo(112) Film ACS Nano 2010, 4, 863-868
14. Ulrich, S.; Nilius, N.; Freund, H.-J.; Martinez, U.; Giordano, L.; Pacchioni, G. Realization of an Atomic Sieve: Silica on Mo(112) Surf. Sci. 2009, 603, 1145-1149
15. 4 Tetrahedra Phys. Rev. Lett. 2005, 95, 076103
16. 3 Heterointerface Nature 2004, 427, 423-426
17. 3 Nat. Mater. 2005, 4, 816-819
18. 3 Nat. Mater. 2007, 6, 129-134
19. Kudo, A.; Miseki, Y. Heterogeneous Photocatalyst Materials for Water Splitting Chem. Soc. Rev. 2009, 38, 253-278
20. 3 Nature 2011, 469, 189-193
21. 3(110) Proc. Natl. Acad. Sci. U.S.A. 2014, 111, 3933-3937
22. 3(001), the (√13×√13) R33.7° Surface, and Related Structures Phys. Rev. Lett. 2011, 106, 176102
23. 3(110) Nat. Mater. 2010, 9, 245-248
24. 3(111) Surf. Sci. 2009, 603, 2179-2187
25. 3(001), (110), and (111) Surfaces Appl. Phys. Lett. 2011, 98, 051904
26. 3(110) Surface Phys. Rev. Lett. 2013, 111, 056101
27. 3(110) Surface J. Chem. Phys. 2011, 135, 144702
28. 3-A Revised Mechanism Energy Environ. Sci. 2012, 5, 9543-9550
29. 3(110)-(4 × 1) J. Phys. Chem. C 2013, 117, 26060-26069
30. Nyholm, R.; Andersen, J.; Johansson, U.; Jensen, B.; Lindau, I. Beamline I311 at MAX-LAB: a VUV/Soft X-ray Undulator Beamline for High Resolution Electron Spectroscopy Nucl. Instrum. Methods Phys. Res., Sect. A 2001, 467, 520-524
31. + Sputtering Appl. Phys. Lett. 2009, 95, 021912
32. Kresse, G.; Hafner, J. Ab initio Molecular Dynamics for Open-Shell Transition Metals Phys. Rev. B 1993, 48, 13115-13118
33. Kresse, G.; Furthmüller, J. Efficiency of ab-initio Total Energy Calculations for Metals and Semiconductors Using a Plane-Wave Basis Set Comput. Mater. Sci. 1996, 6, 15-50
34. Blöchl, P. E. Projector augmented-wave method Phys. Rev. B 1994, 50, 17953-17979
35. Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized Gradient Approximation Made Simple Phys. Rev. Lett. 1996, 77, 3865-3868
36. Tersoff, J.; Hamann, D. R. Theory and Application for the Scanning Tunneling Microscope Phys. Rev. Lett. 1983, 50, 1998-2001
37. 3(110) Tuned by Ti or Sr Concentration Phys. Rev. B 2011, 83, 155453
38. 3(110) Surface Phys. Rev. Lett. 2011, 107, 036103
39. 0 Configuration and Lightly Doped Compounds J. Phys. Chem. Solids 1996, 57, 1379-1384
40. 3 Phys. Rev. Lett. 2008, 100, 056401
41. 3 Phys. Rev. Lett. 2012, 108, 116802
42. Fang, H.-C.; Li, Z. H.; Fan, K.-N. CO Oxidation Catalyzed by a Single Gold Atom: Benchmark Calculations and the Performance of DFT Methods Phys. Chem. Chem. Phys. 2011, 13, 13358-13369
43. 2 Surfaces Surf. Sci. 2008, 602, 2769-2773