Molybdenum carbide-based electrocatalysts for CO tolerance in proton exchange membrane fuel cell anodes

Electrochimica Acta

Volumn 142, Issue , 2014, Pages 307-316

  Hassan, Ayaz ^a   Paganin, Valdecir Antonio ^a   Carreras, Alejo ^b   Ticianelli, Edson Antonio ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

^b Universidad Nacional de Córdoba and IFEG CONICET Ciudad Universitaria   (Argentina)

Author keywords

CO tolerance; Molybdenum carbide; PEMFC; stability; Ultra sonication

Indexed keywords

ANODES; CARBIDES; CARBON; CATALYST SUPPORTS; CONVERGENCE OF NUMERICAL METHODS; CYCLIC VOLTAMMETRY; ELECTROCATALYSTS; ELECTROLYSIS; ENERGY DISPERSIVE SPECTROSCOPY; MASS SPECTROMETRY; MOLYBDENUM; PLATINUM; POLARIZATION; SCANNING ELECTRON MICROSCOPY; STABILITY; TRANSMISSION ELECTRON MICROSCOPY; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY; X RAY DIFFRACTION;

CO TOLERANCE; ELECTROCHEMICAL CHARACTERIZATIONS; ENERGY DISPERSIVE SPECTROSCOPIES (EDS); MOLYBDENUM CARBIDE; POLARIZATION MEASUREMENTS; PROTON EXCHANGE MEMBRANE FUEL CELL (PEMFCS); ULTRA-SONICATION; X-RAY ABSORPTION NEAR-EDGE STRUCTURE; PROTON EXCHANGE MEMBRANES;

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

EID: 84906770574     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.07.142     Document Type: Article

References (37)

1. J. Kunze, and U. Stimming Electrochemical versus heat-engine energy technology: a tribute to Wilhelm Ostwald's visionary statements Angewandte Chemie International Edition 48 2009 9230
2. J.J. Baschuk, and X. Li Carbon monoxide poisoning of proton exchange membrane fuel cells International Journal of Energy Research 25 2001 695
3. F. Hajbolouri, B. Andreaus, G.G. Scherer, and A. Wokaun CO Tolerance of commercial Pt and PtRu gas diffusion electrodes in polymer electrolyte fuel cells Fuel Cells; From Fundamentals to Systems 4 2004 160
4. H. Yu, Z. Hou, B. Yi, and Z. Lin Composite anode for CO tolerance proton exchange membrane fuel cell Journal of Power Sources 105 2002 52
5. J. Patt, D.J. Moon, C. Phillips, and L. Thompson Molybdenum carbide catalysts for water-gas shift Catalysis Letter 65 2000 193
6. 2C nanoparticles Green Chemistry 7 2005 784
7. S.T. Oyama Preparation and catalytic properties of transition metal carbides and nitrides Catalysis Today 15 1992 179
8. R.B. Levy, and M. Boudart The kinetics and mechanism of spillover Journal of Catalysis 32 1974 304
9. E.C. Weigert, N.A. Smith, B.G. Willis, A. Amorelli, and J.G. Chen PVD synthesis and characterization of Pt-modified molybdenum carbides as potential electrocatalysts Electrochemical and Solid-State Letters 8 2005 A337
10. T. Matsumoto, T. Komatsu, H. Nakano, K. Arai, Y. Nagashima, E. Yoo, T. Yamazaki, M. Kijima, H. Shimizu, Y. Takasawa, and J. Nakamura Efficient usage of highly dispersed Pt on carbon nanotubes for electrode catalysts of polymer electrolyte fuel cells Catalysis Today 90 2004 277
11. 2 anode catalyst for intermediate-temperature fuel cells Journal of the Electrochemical Society 154 2007 B53
12. O. Guillén-Villafuerte, R. Guil-Lopez, E. Nieto, G. García, J.L. Rodríguez, E. Pastor, and J.L.G. Fierro Electrocatalytic performance of different Mo-phases obtained during the preparation of innovative Pt-MoC catalysts for DMFC anode International Journal of Hydrogen Energy 37 2012 7171
13. 2C) electrocatalysts Journal of Power Sources 193 2009 501
14. T. Hyeon, M. Fang, and K.S. Suslick Nanostructured molybdenum carbide: Sonochemical synthesis and catalytic properties Journal of American Chemical Society 118 1996 5492
15. K.S. Suslick, T. Hyeon, and M. Fang Nanostructured materials generated by high-intensity ultrasound: Sonochemical synthesis and catalytic studies Chemistry of Materials 8 1996 2172
16. L.G.S. Pereira, V.A. Paganin, and E.A. Ticianelli Investigation of the CO tolerance mechanism at several Pt-based bimetallic anode electrocatalysts in a PEM fuel cell Electrochimica Acta 54 2009 1992
17. E.I. Santiago, V.A. Paganin, M. Carmo, E.R. Gonzalez, and E.A. Ticianelli Studies of CO tolerance on modified gas diffusion electrodes containing ruthenium dispersed on carbon Journal of Electroanalytical Chemistry 575 2005 53
18. G.A. Camara, M.J. Giz, V.A. Paganin, and E.A. Ticianelli Correlation of electrochemical and physical properties of PtRu alloy electrocatalysts for PEM fuel cells Journal of Electroanalytical Chemistry 537 2002 21
19. V. Radmilovic, H.A. Gasteiger, and P.N. Rose Structure and chemical composition of a supported Pt-Ru electrocatalyst for methanol oxidation Journal of Catalysis 154 1995 98
20. L.G.S. Pereira, F.R. Santos, M.E. Pereira, V.A. Paganin, and E.A. Ticianelli CO tolerance effects of tungsten-based PEMFC anodes Electrochimica Acta 51 2006 4061
21. A.C. Garcia, V.A. Paganin, and E.A. Ticianelli CO tolerance of PdPt/C and PdPtRu/C anodes for PEMFC Electrochimica Acta 53 2008 4309
22. E.I. Santiago, G.A. Camara, and E.A. Ticianelli CO tolerance on PtMo/C electrocatalysts prepared by the formic acid method Electrochimica Acta 48 2003 3527
23. S. Zhang, X. Yuan, J.N.C. Hin, H. Wang, K.A. Friedrich, and M. Schulze A review of platinum-based catalyst layer degradation in proton exchange membrane fuel cells Journal of Power Sources 194 2009 588
24. R.L. Borup, J.R. Davey, F.H. Garzon, D.L. Wood, and M.A. Inbody PEM fuel cell electrocatalyst durability measurements Journal of Power Sources 163 2006 76
25. J.A. Schaidle, N.M. Schweitzer, O.T. Ajenifujah, and L.T. Thompson On the preparation of molybdenum carbide-supported metal catalysts Journal of Catalysis 289 2012 210
26. 2C/CNTs nanocomposites as efficient electrocatalyst supports for oxygen reduction reaction Industrial and Engineering Chemistry Research 49 2010 4169
27. A.E. Russell, and A. Rose X-ray absorption spectroscopy of low temperature fuel cell catalysts Chemical Reviews 104 2004 4613
28. 2 oxidation Bulletin of Korean Chemical Society 32 2011 3660
29. A. Witkowska, E. Principi, A. Di Cicco, S. Dsoke, R. Marassi, L. Olivi, M. Centazzo, and V.R. Albertini Temperature and potential-dependent structural changes in a Pt cathode electrocatalyst viewed by in situ XAFS Journal of Non-Crystalline Solids 354 2008 4227
30. T.C.M. Nepel, P.P. Lopes, V.A. Paganin, and E.A. Ticianelli CO tolerance of proton exchange membrane fuel cells with Pt/C and PtMo/C anodes operating at high temperatures: A mass spectrometry investigation Electrochimica Acta 88 2013 217
31. A. Hassan, A. Carreras, J. Trincavelli, and E.A. Ticianelli Effect of heat treatment on the activity and stability of carbon-supported PtMo alloy electrocatalysts for hydrogen oxidation in proton exchange membrane fuel cells Journal of Power Sources 247 2014 712
32. 2C catalysts: Water gas shift reaction Journal of Catalysis 272 2010 235
33. O.T. Holton, and J.W. Stevenson The role of platinum in proton exchange membrane fuel cells Platinum Metals Review 57 2013 259
34. A. Manasilp, and E. Gulari Selective CO oxidation over;1; Pt/alumina catalysts for fuel cell applications Applied Catalysis B: Environmental 37 2002 17
35. L.C. Ordóñez, P. Roquero, P.J. Sebastian, and J. Ramírez Carbon-supported platinum-molybdenum electro-catalysts for methanol oxidation Catalysis Today 107 2005 46
36. N.P. Lebedeva, and G.J.M. Janseen On the preparation and stability of bimetallic PtMo/C anodes for proton-exchange membrane fuel cells Journal of Electrochimica Acta 51 2005 29
37. S. Mukerjee, S.J. Lee, E.A. Ticianelli, J. McBreen, B.N. Grgur, N.M. Markovic, P.N. Ross, J.R. Giallombardo, and E.S. De Castro Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst Electrochemical and Solid-State Letters 2 1999 12