메뉴 건너뛰기




Volumn 30, Issue 32, 2014, Pages 9828-9837

Hard templating of symmetric and asymmetric carbon thin films with three-dimensionally ordered mesoporosity

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CARBONIZATION; COLLOIDS; DYE-SENSITIZED SOLAR CELLS; FILM THICKNESS; FORMALDEHYDE; PHENOLS; PLASTIC FILMS; POROUS MATERIALS; SCAFFOLDS; SOLAR CELLS; SURFACE ROUGHNESS; ULTRATHIN FILMS;

EID: 84906271997     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la501870h     Document Type: Article
Times cited : (18)

References (56)
  • 1
    • 43949121474 scopus 로고    scopus 로고
    • Mesoporous carbon materials: Synthesis and modification
    • Liang, C. D.; Li, Z. J.; Dai, S. Mesoporous carbon materials: Synthesis and modification Angew. Chem., Int. Ed. 2008, 47, 3696-3717
    • (2008) Angew. Chem., Int. Ed. , vol.47 , pp. 3696-3717
    • Liang, C.D.1    Li, Z.J.2    Dai, S.3
  • 2
    • 84874869737 scopus 로고    scopus 로고
    • Direct synthesis of ordered mesoporous carbons
    • Ma, T. Y.; Liu, L.; Yuan, Z. Y. Direct synthesis of ordered mesoporous carbons Chem. Soc. Rev. 2013, 42, 3977-4003
    • (2013) Chem. Soc. Rev. , vol.42 , pp. 3977-4003
    • Ma, T.Y.1    Liu, L.2    Yuan, Z.Y.3
  • 3
    • 77952328395 scopus 로고    scopus 로고
    • Templated nanoscale porous carbons
    • Xia, Y.; Yang, Z.; Mokaya, R. Templated nanoscale porous carbons Nanoscale 2010, 2, 639-659
    • (2010) Nanoscale , vol.2 , pp. 639-659
    • Xia, Y.1    Yang, Z.2    Mokaya, R.3
  • 5
    • 0041558883 scopus 로고    scopus 로고
    • Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation
    • Ryoo, R.; Joo, S. H.; Jun, S. Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation J. Phys. Chem. B 1999, 103, 7743-7746
    • (1999) J. Phys. Chem. B , vol.103 , pp. 7743-7746
    • Ryoo, R.1    Joo, S.H.2    Jun, S.3
  • 6
    • 0033533975 scopus 로고    scopus 로고
    • Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors
    • Lee, J.; Yoo, S.; Hyeon, T.; Oh, S. M.; Kim, K. B. Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors Chem. Commun. 1999, 2177-2178
    • (1999) Chem. Commun. , pp. 2177-2178
    • Lee, J.1    Yoo, S.2    Hyeon, T.3    Oh, S.M.4    Kim, K.B.5
  • 7
    • 33646461429 scopus 로고    scopus 로고
    • Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction
    • Liang, C. D.; Dai, S. Synthesis of mesoporous carbon materials via enhanced hydrogen-bonding interaction J. Am. Chem. Soc. 2006, 128, 5316-5317
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 5316-5317
    • Liang, C.D.1    Dai, S.2
  • 8
    • 8844284402 scopus 로고    scopus 로고
    • Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers
    • Liang, C. D.; Hong, K. L.; Guiochon, G. A.; Mays, J. W.; Dai, S. Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers Angew. Chem., Int. Ed. 2004, 43, 5785-5789
    • (2004) Angew. Chem., Int. Ed. , vol.43 , pp. 5785-5789
    • Liang, C.D.1    Hong, K.L.2    Guiochon, G.A.3    Mays, J.W.4    Dai, S.5
  • 10
    • 27744479232 scopus 로고    scopus 로고
    • Ordered mesoporous polymers and homologous carbon frameworks: Amphiphilic surfactant templating and direct transformation
    • Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Ordered mesoporous polymers and homologous carbon frameworks: Amphiphilic surfactant templating and direct transformation Angew. Chem., Int. Ed. 2005, 44, 7053-7059
    • (2005) Angew. Chem., Int. Ed. , vol.44 , pp. 7053-7059
    • Meng, Y.1    Gu, D.2    Zhang, F.Q.3    Shi, Y.F.4    Yang, H.F.5    Li, Z.6    Yu, C.Z.7    Tu, B.8    Zhao, D.Y.9
  • 11
    • 61849177640 scopus 로고    scopus 로고
    • Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method
    • Jin, J.; Nishiyama, N.; Egashira, Y.; Ueyama, K. Vapor phase synthesis of ultrathin carbon films with a mesoporous monolayer by a soft-templating method Chem. Commun. 2009, 1371-1373
    • (2009) Chem. Commun. , pp. 1371-1373
    • Jin, J.1    Nishiyama, N.2    Egashira, Y.3    Ueyama, K.4
  • 12
    • 3142516345 scopus 로고    scopus 로고
    • Silica-templated continuous mesoporous carbon films by a spin-coating technique
    • Pang, J.; Li, Z.; Wang, D.; Wu, Z.; Joh, V. T.; Yang, Z.; Lu, Y. Silica-templated continuous mesoporous carbon films by a spin-coating technique Adv. Mater. 2004, 16, 884-886
    • (2004) Adv. Mater. , vol.16 , pp. 884-886
    • Pang, J.1    Li, Z.2    Wang, D.3    Wu, Z.4    Joh, V.T.5    Yang, Z.6    Lu, Y.7
  • 14
    • 76949088839 scopus 로고    scopus 로고
    • Robust conductive mesoporous carbon-silica composite films with highly ordered and oriented orthorhombic structures from triblock-copolymer template co-assembly
    • Song, L.; Feng, D.; Campbell, C. G.; Gu, D.; Forster, A. M.; Yager, K. G.; Fredin, N.; Lee, H.-J.; Jones, R. L.; Zhao, D.; Vogt, B. D. Robust conductive mesoporous carbon-silica composite films with highly ordered and oriented orthorhombic structures from triblock-copolymer template co-assembly J. Mater. Chem. 2010, 20, 1691-1701
    • (2010) J. Mater. Chem. , vol.20 , pp. 1691-1701
    • Song, L.1    Feng, D.2    Campbell, C.G.3    Gu, D.4    Forster, A.M.5    Yager, K.G.6    Fredin, N.7    Lee, H.-J.8    Jones, R.L.9    Zhao, D.10    Vogt, B.D.11
  • 15
    • 34548090226 scopus 로고    scopus 로고
    • Fabrication of continuous mesoporous carbon films with face-centered orthorhombic symmetry through a soft templating pathway
    • Tanaka, S.; Katayama, Y.; Tate, M. P.; Hillhouse, H. W.; Miyake, Y. Fabrication of continuous mesoporous carbon films with face-centered orthorhombic symmetry through a soft templating pathway J. Mater. Chem. 2007, 17, 3639-3645
    • (2007) J. Mater. Chem. , vol.17 , pp. 3639-3645
    • Tanaka, S.1    Katayama, Y.2    Tate, M.P.3    Hillhouse, H.W.4    Miyake, Y.5
  • 16
    • 84890821895 scopus 로고    scopus 로고
    • Large area, flexible ordered mesoporous carbon films from soft templating on polymer substrates
    • Xue, J.; Henry, C.; Lee, J.; Vogt, B. D. Large area, flexible ordered mesoporous carbon films from soft templating on polymer substrates RSC. Adv. 2014, 4, 3675-3683
    • (2014) RSC. Adv. , vol.4 , pp. 3675-3683
    • Xue, J.1    Henry, C.2    Lee, J.3    Vogt, B.D.4
  • 17
    • 78650375350 scopus 로고    scopus 로고
    • Recent progress in the synthesis and applications of nanoporous carbon films
    • Tao, Y.; Endo, M.; Inagaki, M.; Kaneko, K. Recent progress in the synthesis and applications of nanoporous carbon films J. Mater. Chem. 2011, 21, 313-323
    • (2011) J. Mater. Chem. , vol.21 , pp. 313-323
    • Tao, Y.1    Endo, M.2    Inagaki, M.3    Kaneko, K.4
  • 18
    • 84863850990 scopus 로고    scopus 로고
    • In Situ SAXS Study on a New Mechanism for Mesostructure Formation of Ordered Mesoporous Carbons: Thermally Induced Self-Assembly
    • Schuster, J.; Köhn, R.; Döblinger, M.; Keilbach, A.; Amenitsch, H.; Bein, T. In Situ SAXS Study on a New Mechanism for Mesostructure Formation of Ordered Mesoporous Carbons: Thermally Induced Self-Assembly J. Am. Chem. Soc. 2012, 134, 11136-11145
    • (2012) J. Am. Chem. Soc. , vol.134 , pp. 11136-11145
    • Schuster, J.1    Köhn, R.2    Döblinger, M.3    Keilbach, A.4    Amenitsch, H.5    Bein, T.6
  • 19
    • 0032558723 scopus 로고    scopus 로고
    • Nanodomain control in copolymer thin films
    • Huang, E.; Rockford, L.; Russell, T. P.; Hawker, C. J. Nanodomain control in copolymer thin films Nature 1998, 395, 757-758
    • (1998) Nature , vol.395 , pp. 757-758
    • Huang, E.1    Rockford, L.2    Russell, T.P.3    Hawker, C.J.4
  • 20
    • 1542285047 scopus 로고    scopus 로고
    • Highly oriented and ordered arrays from block copolymers via solvent evaporation
    • Kim, S. H.; Misner, M. J.; Xu, T.; Kimura, M.; Russell, T. P. Highly oriented and ordered arrays from block copolymers via solvent evaporation Adv. Mater. 2004, 16, 226-231
    • (2004) Adv. Mater. , vol.16 , pp. 226-231
    • Kim, S.H.1    Misner, M.J.2    Xu, T.3    Kimura, M.4    Russell, T.P.5
  • 21
    • 0037008617 scopus 로고    scopus 로고
    • Study of oriented block copolymers films obtained by roll-casting
    • Villar, M. A.; Rueda, D. R.; Ania, F.; Thomas, E. L. Study of oriented block copolymers films obtained by roll-casting Polymer 2002, 43, 5139-5145
    • (2002) Polymer , vol.43 , pp. 5139-5145
    • Villar, M.A.1    Rueda, D.R.2    Ania, F.3    Thomas, E.L.4
  • 22
    • 47149104239 scopus 로고    scopus 로고
    • Synthesis of ordered mesoporous carbon thin films at various temperatures in vapor infiltration method
    • Kataoka, S.; Yamamoto, T.; Inagi, Y.; Endo, A.; Nakaiwa, M.; Ohmori, T. Synthesis of ordered mesoporous carbon thin films at various temperatures in vapor infiltration method Carbon 2008, 46, 1358-1367
    • (2008) Carbon , vol.46 , pp. 1358-1367
    • Kataoka, S.1    Yamamoto, T.2    Inagi, Y.3    Endo, A.4    Nakaiwa, M.5    Ohmori, T.6
  • 23
    • 75749095613 scopus 로고    scopus 로고
    • Challenges in fabrication of mesoporous carbon films with ordered cylindrical pores via phenolic oligomer self-assembly with triblock copolymers
    • Song, L.; Feng, D.; Fredin, N. J.; Yager, K. G.; Jones, R. L.; Wu, Q.; Zhao, D.; Vogt, B. D. Challenges in fabrication of mesoporous carbon films with ordered cylindrical pores via phenolic oligomer self-assembly with triblock copolymers ACS Nano 2010, 4, 189-198
    • (2010) ACS Nano , vol.4 , pp. 189-198
    • Song, L.1    Feng, D.2    Fredin, N.J.3    Yager, K.G.4    Jones, R.L.5    Wu, Q.6    Zhao, D.7    Vogt, B.D.8
  • 24
    • 79958842202 scopus 로고    scopus 로고
    • Ordered mesoporous carbon composite films containing cobalt oxide and vanadia for electrochemical applications
    • Dai, M.; Song, L.; LaBelle, J. T.; Vogt, B. D. Ordered mesoporous carbon composite films containing cobalt oxide and vanadia for electrochemical applications Chem. Mater. 2011, 23, 2869-2878
    • (2011) Chem. Mater. , vol.23 , pp. 2869-2878
    • Dai, M.1    Song, L.2    Labelle, J.T.3    Vogt, B.D.4
  • 25
    • 39849103614 scopus 로고    scopus 로고
    • Morphological control in colloidal crystal templating of inverse opals, hierarchical structures, and shaped particles
    • Stein, A.; Li, F.; Denny, N. R. Morphological control in colloidal crystal templating of inverse opals, hierarchical structures, and shaped particles Chem. Mater. 2008, 20, 649-666
    • (2008) Chem. Mater. , vol.20 , pp. 649-666
    • Stein, A.1    Li, F.2    Denny, N.R.3
  • 27
    • 33746882097 scopus 로고    scopus 로고
    • Carbons with extremely large volume of uniform mesopores synthesized by carbonization of phenolic resin film formed on colloidal silica template
    • Gierszal, K. P.; Jaroniec, M. Carbons with extremely large volume of uniform mesopores synthesized by carbonization of phenolic resin film formed on colloidal silica template J. Am. Chem. Soc. 2006, 128, 10026-10027
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 10026-10027
    • Gierszal, K.P.1    Jaroniec, M.2
  • 28
    • 0033533764 scopus 로고    scopus 로고
    • Simple silica-particle template synthesis of mesoporous carbons
    • Han, S.; Hyeon, T. Simple silica-particle template synthesis of mesoporous carbons Chem. Commun. 1999, 1955-1956
    • (1999) Chem. Commun. , pp. 1955-1956
    • Han, S.1    Hyeon, T.2
  • 29
    • 0037255559 scopus 로고    scopus 로고
    • The effect of silica template structure on the pore strucure of mesoporous carbons
    • Han, S.; Lee, K. T.; Oh, S. M.; Hyeon, T. The effect of silica template structure on the pore strucure of mesoporous carbons Carbon 2003, 41, 1049-1056
    • (2003) Carbon , vol.41 , pp. 1049-1056
    • Han, S.1    Lee, K.T.2    Oh, S.M.3    Hyeon, T.4
  • 30
    • 16244382535 scopus 로고    scopus 로고
    • Graphitized pitch-based carbons with ordered nanopores synthesized by using colloidal crystals as templates
    • Yoon, S. B.; Chai, G. S.; Kang, S. K.; Yu, J.-S.; Gierszal, K. P.; Jaroniec, M. Graphitized pitch-based carbons with ordered nanopores synthesized by using colloidal crystals as templates J. Am. Chem. Soc. 2005, 127, 4188-4189
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 4188-4189
    • Yoon, S.B.1    Chai, G.S.2    Kang, S.K.3    Yu, J.-S.4    Gierszal, K.P.5    Jaroniec, M.6
  • 31
    • 0035913730 scopus 로고    scopus 로고
    • Colloidal imprinting: A novel approch to the synthesis of mesoporous carbons
    • Li, Z.; Jaroniec, M. Colloidal imprinting: A novel approch to the synthesis of mesoporous carbons J. Am. Chem. Soc. 2001, 123, 9208-9209
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 9208-9209
    • Li, Z.1    Jaroniec, M.2
  • 32
    • 34249738462 scopus 로고    scopus 로고
    • Mass transport and electrod accessibility through periodic self-assembled nanoporous silica thin films
    • Wei, T.-C.; Hillhouse, H. W. Mass transport and electrod accessibility through periodic self-assembled nanoporous silica thin films Langmuir 2007, 23, 5689-5699
    • (2007) Langmuir , vol.23 , pp. 5689-5699
    • Wei, T.-C.1    Hillhouse, H.W.2
  • 33
    • 35148894568 scopus 로고    scopus 로고
    • Silica nanoparticle crystals and ordered coatings using lys-sil and a novel coating device
    • Snyder, M. A.; Lee, J. A.; Davis, T. M.; Scriven, L. E.; Tsapatsis, M. Silica nanoparticle crystals and ordered coatings using lys-sil and a novel coating device Langmuir 2007, 23, 9924-9928
    • (2007) Langmuir , vol.23 , pp. 9924-9928
    • Snyder, M.A.1    Lee, J.A.2    Davis, T.M.3    Scriven, L.E.4    Tsapatsis, M.5
  • 34
    • 0001547193 scopus 로고    scopus 로고
    • Continuous convective assembling of fine particles into two-dimensional arrays on solid surfaces
    • Dimitrov, A. S.; Nagayama, K. Continuous convective assembling of fine particles into two-dimensional arrays on solid surfaces Langmuir 1996, 12, 1303-1311
    • (1996) Langmuir , vol.12 , pp. 1303-1311
    • Dimitrov, A.S.1    Nagayama, K.2
  • 35
    • 80052698402 scopus 로고    scopus 로고
    • Coating process regimes in particulate film production by forced-convection-assisted drag-out
    • Brewer, D. D.; Takumi, S.; Francis, L.; Kumar, S.; Tsapatsis, M. Coating process regimes in particulate film production by forced-convection-assisted drag-out Langmuir 2011, 27, 11660-11670
    • (2011) Langmuir , vol.27 , pp. 11660-11670
    • Brewer, D.D.1    Takumi, S.2    Francis, L.3    Kumar, S.4    Tsapatsis, M.5
  • 36
    • 1842582720 scopus 로고    scopus 로고
    • Controlled, rapid deposition of structured coatings from micro-and nanoparticle suspensions
    • Prevo, B. G.; Velev, O. D. Controlled, rapid deposition of structured coatings from micro-and nanoparticle suspensions Langmuir 2004, 20, 2099-2107
    • (2004) Langmuir , vol.20 , pp. 2099-2107
    • Prevo, B.G.1    Velev, O.D.2
  • 38
    • 56449086208 scopus 로고    scopus 로고
    • Investigation of the deposition of microsphere monolayers for fabrication of microlens arrays
    • Kumnorkaew, P.; Ee, Y. K.; Tansu, N.; Gilchrist, J. F. Investigation of the deposition of microsphere monolayers for fabrication of microlens arrays Langmuir 2008, 24, 12150-12157
    • (2008) Langmuir , vol.24 , pp. 12150-12157
    • Kumnorkaew, P.1    Ee, Y.K.2    Tansu, N.3    Gilchrist, J.F.4
  • 43
    • 80053085404 scopus 로고    scopus 로고
    • Free-standing mesoporous carbon thin films with highly ordered pore architectures for nanodevices
    • Feng, D.; Lv, Y. Y.; Wu, Z. X.; Dou, Y. Q.; Han, L.; Sun, Z. K.; Xia, Y. Y.; Zheng, G. F.; Zhao, D. Y. Free-standing mesoporous carbon thin films with highly ordered pore architectures for nanodevices J. Am. Chem. Soc. 2011, 133, 15148-15156
    • (2011) J. Am. Chem. Soc. , vol.133 , pp. 15148-15156
    • Feng, D.1    Lv, Y.Y.2    Wu, Z.X.3    Dou, Y.Q.4    Han, L.5    Sun, Z.K.6    Xia, Y.Y.7    Zheng, G.F.8    Zhao, D.Y.9
  • 44
    • 0033596348 scopus 로고    scopus 로고
    • Template-directed preparation of macroporous polymers with oriented and crystalline arrays of voids
    • Jiang, P.; Hwang, K. S.; Mittleman, D. M.; Bertone, J. F.; Colvin, V. L. Template-directed preparation of macroporous polymers with oriented and crystalline arrays of voids J. Am. Chem. Soc. 1999, 121, 11630-11637
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 11630-11637
    • Jiang, P.1    Hwang, K.S.2    Mittleman, D.M.3    Bertone, J.F.4    Colvin, V.L.5
  • 46
    • 79955457665 scopus 로고    scopus 로고
    • Impact of film thickness on the morphology of mesoporous carbon films using organic-organic sefl-assembly
    • Vogt, B. D.; Chavez, V. L.; Dai, M.; CArreola, M. R. C.; Song, L.; Feng, D.; Zhao, D.; Perera, G. M.; Stein, G. E. Impact of film thickness on the morphology of mesoporous carbon films using organic-organic sefl-assembly Langmuir 2011, 27, 5607-5615
    • (2011) Langmuir , vol.27 , pp. 5607-5615
    • Vogt, B.D.1    Chavez, V.L.2    Dai, M.3    Carreola, M.R.C.4    Song, L.5    Feng, D.6    Zhao, D.7    Perera, G.M.8    Stein, G.E.9
  • 47
    • 84865473380 scopus 로고    scopus 로고
    • Characterization of the pore structure of three-dimensionally ordered mesoporous carbons using high resolution gas sorption
    • Cychosz, K. A.; Guo, X.; Fan, W.; Cimino, R.; Gor, G. Y.; Tsapatsis, M.; Neimark, A. V.; Thommes, M. Characterization of the pore structure of three-dimensionally ordered mesoporous carbons using high resolution gas sorption Langmuir 2012, 28, 12647-12654
    • (2012) Langmuir , vol.28 , pp. 12647-12654
    • Cychosz, K.A.1    Guo, X.2    Fan, W.3    Cimino, R.4    Gor, G.Y.5    Tsapatsis, M.6    Neimark, A.V.7    Thommes, M.8
  • 48
    • 34848848689 scopus 로고    scopus 로고
    • Mesoporous carbons with KOH activated framework and their hydrogen adsorption
    • Choi, M.; Ryoo, R. Mesoporous carbons with KOH activated framework and their hydrogen adsorption J. Mater. Chem. 2007, 17, 4204-4209
    • (2007) J. Mater. Chem. , vol.17 , pp. 4204-4209
    • Choi, M.1    Ryoo, R.2
  • 52
    • 0033578681 scopus 로고    scopus 로고
    • Ultrasonic deposition of high-selectivity nanoporous carbon membranes
    • Shiflett, M. B.; Foley, H. C. Ultrasonic deposition of high-selectivity nanoporous carbon membranes Science 1999, 285, 1902-1905
    • (1999) Science , vol.285 , pp. 1902-1905
    • Shiflett, M.B.1    Foley, H.C.2
  • 53
    • 34547807187 scopus 로고    scopus 로고
    • Sintered silica colloidal crystals with fully hydroxylated surfaces
    • Van Le, T.; Ross, E. E.; Velarde, T. R. C.; Legg, M. A.; Wirth, M. J. Sintered silica colloidal crystals with fully hydroxylated surfaces Langmuir 2007, 23, 8554-8559
    • (2007) Langmuir , vol.23 , pp. 8554-8559
    • Van Le, T.1    Ross, E.E.2    Velarde, T.R.C.3    Legg, M.A.4    Wirth, M.J.5
  • 54
    • 79952971627 scopus 로고    scopus 로고
    • Transparent electrode with a nanostructured coating
    • Huang, Y. Y.; Terentjev, E. M. Transparent electrode with a nanostructured coating ACS Nano 2011, 5, 2082-2089
    • (2011) ACS Nano , vol.5 , pp. 2082-2089
    • Huang, Y.Y.1    Terentjev, E.M.2
  • 55
    • 79955026362 scopus 로고    scopus 로고
    • Transferred vertically aligned N-doped carbon nanotube arrays: Use in dye-sensitized solar cells as counter electrodes
    • Lee, K. S.; Lee, W. J.; Park, N. G.; Kim, S. O.; Park, J. H. Transferred vertically aligned N-doped carbon nanotube arrays: use in dye-sensitized solar cells as counter electrodes Chem. Commun. 2011, 47, 4264-4266
    • (2011) Chem. Commun. , vol.47 , pp. 4264-4266
    • Lee, K.S.1    Lee, W.J.2    Park, N.G.3    Kim, S.O.4    Park, J.H.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.