A measurement of total reactive nitrogen, NOy, together with NO2, NO, and O3 via cavity ring-down spectroscopy

Environmental Science and Technology

Volumn 48, Issue 16, 2014, Pages 9609-9615

  Wild, Robert J ^a,b   Edwards, Peter M ^a,b,e   Dubé, William P ^a,b   Baumann, Karsten ^c   Edgerton, Eric S ^c   Quinn, Patricia K ^d   Roberts, James M ^b   Rollins, Andrew W ^a,b   Veres, Patrick R ^a,b   Warneke, Carsten ^a,b   Williams, Eric J ^b   Yuan, Bin ^a,b   Brown, Steven S ^b  

^a UNIVERSITY OF COLORADO   (United States)

^b EARTH SYSTEM RESEARCH LABORATORY   (United States)

^c Atmospheric Research and Analysis Inc   (United States)

^d NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^e UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; DISSOCIATION; NITROGEN; NITROGEN COMPOUNDS; QUARTZ;

AMBIENT MEASUREMENT; BIOGENIC EMISSION; CAVITY RING-DOWN SPECTROSCOPY; MEASUREMENT CHANNELS; OIL AND GAS PRODUCTION; STANDARD MEASUREMENTS; THERMAL CONVERTERS; THERMAL DISSOCIATION;

NITROGEN OXIDES;

NITROGEN; NITROGEN DIOXIDE; NITROGEN OXIDE; OZONE; SILICON DIOXIDE; TOTAL REACTIVE NITROGEN; UNCLASSIFIED DRUG; ORGANIC COMPOUND;

AMBIENT AIR; ARTICLE; CAVITY RING DOWN SPECTROSCOPY; CHEMOLUMINESCENCE; DIODE LASER; DISSOCIATION; EXHAUST GAS; HIGH TEMPERATURE; MEASUREMENT ACCURACY; MEASUREMENT PRECISION; RURAL AREA; SPECTROSCOPY; THERMAL DISSOCIATION; UNITED STATES; WINTER; DEVICES; ENVIRONMENTAL MONITORING; EQUIPMENT DESIGN; HUMIDITY; PROCEDURES;

ALABAMA; ENVIRONMENTAL MONITORING; EQUIPMENT DESIGN; HUMIDITY; LASERS, SEMICONDUCTOR; NITROGEN; NITROGEN DIOXIDE; NITROGEN OXIDES; ORGANIC CHEMICALS; OZONE; SPECTRUM ANALYSIS; UTAH;

EID: 84906230476     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es501896w     Document Type: Article

References (26)

1. y in the atmosphere J. Atmos. Chem. 1985, 3, 435-468
2. y measurement techniques J. Geophys. Res.: Atmos. 1998, 103, 22261-22280
3. y Blue Ribbon panel J. Geophys. Res.: Atmos. 1996, 101, 2049-2052
4. y J. Geophys. Res.: Atmos. 1997, 102, 10759-10776
5. Neuman, J. A.; Huey, L. G.; Ryerson, T. B.; Fahey, D. W. Study of Inlet Materials for Sampling Atmospheric Nitric Acid Environ. Sci. Technol. 1999, 33, 1133-1136
6. 5 via pulsed cavity ring-down spectroscopy. Rev. Sci. Instrum. 2006, 77.
7. Wooldridge, P. J.; Perring, A. E.; Bertram, T. H.; Flocke, F. M.; Roberts, J. M.; Singh, H. B.; Huey, L. G.; Thornton, J. A.; Wolfe, G. M.; Murphy, J. G.; Fry, J. L.; Rollins, A. W.; LaFranchi, B. W.; Cohen, R. C. Total Peroxy Nitrates (PNs) in the atmosphere: the Thermal Dissociation-Laser Induced Fluorescence (TD-LIF) technique and comparisons to speciated PAN measurements Atmos. Meas. Tech. 2010, 3, 593-607
8. 3 Atmos. Meas. Tech. 2013, 6, 971-980
9. Pérez, I. M.; Wooldridge, P. J.; Cohen, R. C. Laboratory evaluation of a novel thermal dissociation chemiluminescence method for in situ detection of nitrous acid Atmos. Environ. 2007, 41, 3993-4001
10. Thaler, R. D.; Mielke, L. H.; Osthoff, H. D. Quantification of Nitryl Chloride at Part Per Trillion Mixing Ratios by Thermal Dissociation Cavity Ring-Down Spectroscopy Anal. Chem. 2011, 83, 2761-2766
11. 3 J. Geophys. Res.: Atmos. 2002, 107, ACH 4-1-ACH 4-14
12. 2 Chem. Phys. Lett. 2003, 367, 1-9
13. 2 mixing ratios in ambient air Analyst 2005, 130, 1595-1600
14. 2 with Quantification and Elimination of Interferences Environ. Sci. Technol. 2006, 40, 7868-7873
15. 2 detector for enhanced sensitivity. Rev. Sci. Instrum. 2009, 80.
16. x Based on Blue Diode Laser Cavity Ring-Down Spectroscopy. Environ. Sci. Technol. 2009, 43, 7831-7836, PMID: 19921901.
17. Washenfelder, R. A.; Wagner, N. L.; Dubé, W. P.; Brown, S. S. Measurement of Atmospheric Ozone by Cavity Ring-down Spectroscopy Environ. Sci. Technol. 2011, 45, 2938-2944
18. 3 from aircraft Atmos. Meas. Tech. 2011, 4, 1227-1240
19. Rollins, A. W.; Smith, J. D.; Wilson, K. R.; Cohen, R. C. Real Time In Situ Detection of Organic Nitrates in Atmospheric Aerosols Environ. Sci. Technol. 2010, 44, 5540-5545
20. 3 kinetics J. Geophys. Res.: Atmos. 1986, 91, 5159-5172
21. Reisen, F.; Arey, J. Atmospheric Reactions Influence Seasonal PAH and Nitro-PAH Concentrations in the Los Angeles Basin Environ. Sci. Technol. 2005, 39, 64-73
22. Axson, J. L.; Washenfelder, R. A.; Kahan, T. F.; Young, C. J.; Vaida, V.; Brown, S. S. Absolute ozone absorption cross section in the Huggins Chappuis minimum (350-470 nm) at 296 K Atmos. Chem. Phy. 2011, 11, 11581-11590
23. Slusher, D. L.; Huey, L. G.; Tanner, D. J.; Flocke, F. M.; Roberts, J. M. A thermal dissociation-chemical ionization mass spectrometry (TD-CIMS) technique for the simultaneous measurement of peroxyacyl nitrates and dinitrogen pentoxide. J. Geophys. Res.: Atmos. 2004, 109.
24. Roberts, J. M.; Veres, P.; Warneke, C.; Neuman, J. A.; Washenfelder, R. A.; Brown, S. S.; Baasandorj, M.; Burkholder, J. B.; Burling, I. R.; Johnson, T. J.; Yokelson, R. J.; de Gouw, J. Measurement of HONO, HNCO, and other inorganic acids by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS): application to biomass burning emissions Atmos. Meas. Tech. 2010, 3, 981-990
25. Helmig, D.; Thompson, C. R.; Evans, J.; Boylan, P.; Hueber, J.; Park, J.-H. Highly Elevated Atmospheric Levels of Volatile Organic Compounds in the Uintah Basin, Utah Environ. Sci. Technol. 2014, 48, 4707-4715
26. 2 instrument. Documentation can be found at www.thermo.com/eThermo/CMA/PDFs/Product/productPDF-20982.pdf.