A review of laser-induced breakdown spectroscopy for analysis of geological materials

Applied Spectroscopy Reviews

Volumn 50, Issue 1, 2015, Pages 1-26

  Qiao, Shujun ^a   Ding, Yu ^a   Tian, Di ^a   Yao, Li ^a   Yang, Guang ^a  

^a JILIN UNIVERSITY   (China)

Author keywords

geological materials; Laser induced breakdown spectroscopy; qualitative analysis; quantitative analysis

Indexed keywords

CHEMICAL ANALYSIS; SUBMARINE GEOLOGY;

EXTRATERRESTRIAL MATERIAL; FLUID INCLUSION; GEOLOGICAL MATERIALS; IN-SITU DETECTIONS; LASERINDUCED BREAKDOWN SPECTROSCOPY (LIBS); MARINE SEDIMENTS; QUALITATIVE ANALYSIS; QUALITATIVE AND QUANTITATIVE ANALYSIS;

ATOMIC EMISSION SPECTROSCOPY;

EID: 84906221381     PISSN: 05704928     EISSN: 1520569X     Source Type: Journal    
DOI: 10.1080/05704928.2014.911746     Document Type: Review

References (123)

1. Cremers, D.A., and Radziemski, L.J. (2006) Handbook of Laser-Induced Breakdown Spectroscopy. Wiley: Chichester, UK.
2. Burakov, V., Tarasenko, N., Nedelko, M., Kononov, V., Vasilev, N., and Isakov, S. (2009) Analysis of lead and sulfur in environmental samples by double pulse laser induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 64 (2): 141-146.
3. Pandhija, S., Rai, N., Rai, A.K., and Thakur, S.N. (2010) Contaminant concentration in environmental samples using LIBS and CF-LIBS. Appl. Phys. B, 98 (1): 231-241.
4. Ortiz, P., Vázquez, M., Ortiz, R., Martin, J., Ctvrtnickova, T., Mateo, M., and Nicolas, G. (2010) Investigation of environmental pollution effects on stone monuments in the case of Santa Maria La Blanca, Seville (Spain). Appl. Phys. A, 100 (3): 965-973.
5. Abdel-Kareem, O., Ghoneim, M., and Harith, M. (2011). Investigation of historical metal objects using laser induced breakdown spectroscopy (LIBS) technique. 8th International Conference on Laser Applications, Cairo, Egypt, May 1-5.
6. Nevin, A., Spoto, G., and Anglos, D. (2012) Laser spectroscopies for elemental and molecular analysis in art and archaeology. Appl. Phys. A, 106 (2): 339-361.
7. Ahmed, H.E., Liu, Y., Bousquet, B., Baudelet, M., and Richardson, M. (2013) Investigation of historical Egyptian textile using laser-induced breakdown spectroscopy (LIBS)-A case study. Journal of Textile & Apparel Technology & Management, 8 (2): 1-10.
8. Harmon, R.S., DeLucia, F.C., McManus, C.E., McMillan, N.J., Jenkins, T.F., Walsh, M.E., and Miziolek, A. (2006) Laser-induced breakdown spectroscopy-An emerging chemical sensor technology for real-time field-portable, geochemical, mineralogical, and environmental applications. Appl. Geochem., 21 (5): 730-747.
9. Harmon, R.S., Remus, J., McMillan, N.J., McManus, C., Collins, L., Gottfried, J.L., DeLucia, F.C., and Miziolek, A.W. (2009) LIBS analysis of geomaterials: Geochemical fingerprinting for the rapid analysis and discrimination of minerals. Appl. Geochem., 24 (6): 1125-1141.
10. Rakovský, J., Musset, O., Buoncristiani, J., Bichet, V., Monna, F., Neige, P., and Veis, P. (2012) Testing a portable laser-induced breakdown spectroscopy system on geological samples. Spectrochim. Acta B Atom. Spectros., 74-75: 57-65.
11. Singh, V.K. and Rai, A.K. (2011) Potential of laser-induced breakdown spectroscopy for the rapid identification of carious teeth. Laser. Med. Sci., 26 (3): 307-315.
12. Ye, J., Wan, X., Zhang, Z., Chen, Q., Deng, C., and Zhao, J. (2012). Quantitative analysis of Pb with laser-induced breakdown spectroscopy in human's nail. 2012 Symposium on Photonics and Optoelectronics (SOPO), Shanghai, China, May 21-23.
13. Oztoprak, B.G., Gonzalez, J., Yoo, J., Gulecen, T., Mutlu, N., Russo, R.E., Gundogdu, O., and Demir, A. (2012) Analysis and classification of heterogeneous kidney stones using laser-induced breakdown spectroscopy (LIBS). Appl. Spectros., 66 (11): 1353-1361.
14. Praher, B., Rössler, R., Arenholz, E., Heitz, J., and Pedarnig, J. (2011) Quantitative determination of element concentrations in industrial oxide materials by laser-induced breakdown spectroscopy. Anal. Bioanal. Chem., 400 (10): 3367-3375.
15. Musazzi, S., Golinelli, E., Perini, U., Barberis, F., and Zanetta, G. (2012) Elemental analysis of coal by means of the laser induced breakdown spectroscopy (LIBS) technique. Sensors Applications Symposium (SAS), Brescia, Italy, February 7-9.
16. Kumar, R., Rai, A.K., Alamelu, D., and Aggarwal, S.K. (2013) Monitoring of toxic elements present in sludge of industrial waste using CF-LIBS. Environ. Monit. Assess., 185 (1): 171-180.
17. Balika, L., Focsa, C., Gurlui, S., Pellerin, S., Pellerin, N., Pagnon, D., and Dudeck, M. (2012) Laser-induced breakdown spectroscopy in a running Hall Effect Thruster for space propulsion. Spectrochim. Acta B Atom. Spectros., 74: 184-189.
18. Dreyer, C.B., Spear, J.R., Lynch, K.L., Johnson, L., and Bauer, A.J. (2012) Laser induced breakdown spectroscopy as an in-space sample return canister sterilization method and instrument. LPI Contributions, 1683: 1112.
19. Maruyama, Y., Blacksberg, J., and Charbon, E. (2013) A 1024 × 8700 ps time-gated SPAD line sensor for laser Raman spectroscopy and LIBS in space and rover-based planetary exploration. 2013 IEEE International Solid-State Circuits Conference, San Francisco, CA, February 22-26.
20. Díaz Pace, D.M., Gabriele, N.A., Garcimuño, M., D'Angelo, C.A., Bertuccelli, G., and Bertuccelli, D. (2011) Analysis of minerals and rocks by laser-induced breakdown spectroscopy. Spectros. Lett., 44 (6): 399-411.
21. Lin, Q., Niu, G., Wang, Q., Yu, Q., and Duan, Y. (2013) Combined laser-induced breakdown with Raman spectroscopy: Historical technology development and recent applications. Appl. Spectros. Rev., 48 (6): 487-508.
22. Cuñat, J., Palanco, S., Carrasco, F., Simon, M., and Laserna, J. (2005) Portable instrument and analytical method using laser-induced breakdown spectrometry for in situ characterization of speleothems in karstic caves. JAAS: Journal of Analytical Atomic Spectrometry, 20 (4): 295-300.
23. Cuñat, J., Fortes, F., Cabalín, L., Carrasco, F., Simón, M., and Laserna, J. (2008) Man-portable laser-induced breakdown spectroscopy system for in situ characterization of karstic formations. Appl. Spectros., 62 (11): 1250-1255.
24. Gaft, M., Nagli, L., Fasaki, I., Kompitsas, M., and Wilsch, G. (2009) Laser-induced breakdown spectroscopy for on-line sulfur analyses of minerals in ambient conditions. Spectrochim. Acta B Atom. Spectros., 64 (10): 1098-1104.
25. Gaft, M., Sapir-Sofer, I., Modiano, H., and Stana, R. (2007) Laser induced breakdown spectroscopy for bulk minerals online analyses. Spectrochim. Acta B Atom. Spectros., 62 (12): 1496-1503.
26. Cremers, D., Barefield, J., and Koskelo, A. (1995) Remote elemental analysis by laser-induced breakdown spectroscopy using a fiber-optic cable. Appl. Spectros., 49 (6): 857-860.
27. Panne, U., Neuhauser, R., Haisch, C., Fink, H., and Niessner, R. (2002) Remote analysis of a mineral melt by laser-induced plasma spectroscopy. Appl. Spectros., 56 (3): 375-380.
28. Palanco, S., López-Moreno, C., and Laserna, J.J. (2006) Design, construction and assessment of a field-deployable laser-induced breakdown spectrometer for remote elemental sensing. Spectrochim. Acta B Atom. Spectros., 61 (1): 88-95.
29. Lopez-Moreno, C., Palanco, S., Laserna, J.J., DeLucia, F., Jr., Miziolek, A.W., Rose, J., Walters, R.A., and Whitehouse, A.I. (2006) Test of a stand-off laser-induced breakdown spectroscopy sensor for the detection of explosive residues on solid surfaces. JAAS: Journal of Analytical Atomic Spectrometry, 21 (1): 55-60.
30. Gottfried, J.L. (2007) Double-pulse standoff laser-induced breakdown spectroscopy for versatile hazardous materials detection. Spectrochim. Acta B Atom. Spectros., 62 (12): 1405-1411.
31. Gottfried, J.L., Harmon, R.S., De Lucia, F.C., and Miziolek, A.W. (2009) Multivariate analysis of laser-induced breakdown spectroscopy chemical signatures for geomaterial classification. Spectrochim. Acta B Atom. Spectros., 64 (10): 1009-1019.
32. Sallé, B., Lacour, J.-L., Vors, E., Fichet, P., Maurice, S., Cremers, D.A., and Wiens, R.C. (2004) Laser-induced breakdown spectroscopy for Mars surface analysis: Capabilities at stand-off distances and detection of chlorine and sulfur elements. Spectrochim. Acta B Atom. Spectros., 59 (9): 1413-1422.
33. Sallé, B., Cremers, D.A., Maurice, S., Wiens, R.C., and Fichet, P. (2005) Evaluation of a compact spectrograph for in-situ and stand-off laser-induced breakdown spectroscopy analyses of geological samples on Mars missions. Spectrochim. Acta B Atom. Spectros., 60 (6): 805-815.
34. Cremers, D.A., Wiens, R.C., Ferris, M.J., Brennetot, R., and Maurice, S. (2002) Capabilities of LIBS for analysis of geological samples at stand-off distances in a Mars atmosphere. Laser-Induced Plasma Spectroscopy and Applications, 81: 5-7.
35. Wiens, R.C., Arvidson, R.E., Cremers, D.A., Ferris, M.J., Blacic, J.D., Seelos, F.P., and Deal, K.S. (2002) Combined remote mineralogical and elemental identification from rovers: Field and laboratory tests using reflectance and laser-induced breakdown spectroscopy. J. Geophys. Res., 107 (E11): FIDO3-1-FIDO3-14.
36. Sharma, S.K., Lucey, P.G., Ghosh, M., Hubble, H.W., and Horton, K.A. (2003) Stand-off Raman spectroscopic detection of minerals on planetary surfaces. Spectrochim. Acta Mol. Biomol. Spectros., 59 (10): 2391-2407.
37. Wiens, R.C., Sharma, S.K., Thompson, J., Misra, A., and Lucey, P.G. (2005) Joint analyses by laser-induced breakdown spectroscopy (LIBS) and Raman spectroscopy at stand-off distances. Spectrochim. Acta Mol. Biomol. Spectros., 61 (10): 2324-2334.
38. Sharma, S.K., Misra, A.K., Lucey, P.G., Wiens, R.C., and Clegg, S.M. (2007) Combined remote LIBS and Raman spectroscopy at 8.6m of sulfur-containing minerals, and minerals coated with hematite or covered with basaltic dust. Spectrochim. Acta Mol. Biomol. Spectros., 68 (4): 1036-1045.
39. Jehlička, J., Edwards, H.G.M., and Vítek, P. (2009) Assessment of Raman spectroscopy as a tool for the non-destructive identification of organic minerals and biomolecules for Mars studies. Planet. Space Sci., 57 (5-6): 606-613.
40. Dreyer, C.B., Mungas, G.S., Thanh, P., and Radziszewski, J.G. (2007) Study of sub-mJ-excited laser-induced plasma combined with Raman spectroscopy under Mars atmosphere-simulated conditions. Spectrochim. Acta B Atom. Spectros., 62 (12): 1448-1459.
41. Kramida, A., Ralchenko, Y., and Reader, J. (2013) NIST Atomic Spectra Database (version 5). Available at: http://www.nist.gov/pml/data/asd.cfm (accessed March 2014).
42. Vadillo, J., and Laserna, J. (1996) Laser-induced breakdown spectroscopy of silicate, vanadate and sulfide rocks. Talanta, 43 (7): 1149-1154.
43. Haider, A.F.M.Y., Wahadoszamen, M., Sadat, M.E., Abedin, K.M., and Talukder, A.I. (2010) Elemental profiling and determination of Ti content of the beach sand samples of Bangladesh using LIBS technique. Optic. Laser Tech., 42 (6): 969-974.
44. Abedin, K.M., Haider, A.F.M.Y., Rony, M.A., and Khan, Z.H. (2011) Identification of multiple rare earths and associated elements in raw monazite sands by laser-induced breakdown spectroscopy. Optic. Laser Tech., 43 (1): 45-49.
45. Lui, S.-L., and Koujelev, A. (2011) Accurate identification of geological samples using artificial neural network processing of laser-induced breakdown spectroscopy data. JAAS: Journal of Analytical Atomic Spectrometry, 26 (12): 2419-2427.
46. Kaski, S., Häkkänen, H., and Korppi-Tommola, J. (2003) Sulfide mineral identification using laser-induced plasma spectroscopy. Miner. Eng., 16 (11): 1239-1243.
47. McMillan, N.J., Harmon, R.S., De Lucia, F.C., and Miziolek, A.M. (2007) Laser-induced breakdown spectroscopy analysis of minerals: Carbonates and silicates. Spectrochim. Acta B Atom. Spectros., 62 (12): 1528-1536.
48. McManus, C.E., McMillan, N.J., Harmon, R.S., and Whitmore, R.C. (2008) Use of laser induced breakdown spectroscopy in the determination of gem provenance: Beryls. Appl. Optic., 47 (31): G72-G79.
49. McMillan, N.J., McManus, C.E., Harmon, R.S., De Lucia, F.C., Jr., and Miziolek, A.W. (2006) Laser-induced breakdown spectroscopy analysis of complex silicate minerals-Beryl. Anal. Bioanal. Chem., 385 (2): 263-271.
50. Alvey, D.C., Morton, K., Harmon, R.S., Gottfried, J.L., Remus, J.J., Collins, L.M., and Wise, M.A. (2010) Laser-induced breakdown spectroscopy-based geochemical fingerprinting for the rapid analysis and discrimination of minerals: The example of garnet. Appl. Optic., 49 (13): C168-C180.
51. Clegg, S.M., Sklute, E., Dyar, M.D., Barefield, J.E., and Wiens, R.C. (2009) Multivariate analysis of remote laser-induced breakdown spectroscopy spectra using partial least squares, principal component analysis, and related techniques. Spectrochim. Acta B Atom. Spectros., 64 (1): 79-88.
52. McMillan, N.J., Montoya, C., and Chesner, W.H. (2012) Correlation of limestone beds using laser-induced breakdown spectroscopy and chemometric analysis. Appl. Optic., 51 (7): B213-B222.
53. Koujelev, A., Sabsabi, M., Motto-Ros, V., Laville, S., and Lui, S.L. (2010) Laser-induced breakdown spectroscopy with artificial neural network processing for material identification. Planet. Space Sci., 58 (4): 682-690.
54. Zhu, X., Xu, T., Lin, Q., Liang, L., Niu, G., Lai, H., Xu, M., Wang, X., Li, H., and Duan, Y. (2014) Advanced statistical analysis of laser-induced breakdown spectroscopy data to discriminate sedimentary rocks based on Czerny-Turner and Echelle spectrometers. Spectrochim. Acta B Atom. Spectros., 93: 8-13.
55. Vieitez, M.O., Hedberg, J., Launila, O., and Berg, L.-E. (2005) Elemental analysis of steel scrap metals and minerals by laser-induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 60 (7): 920-925.
56. Horňáčková, M., Grolmusová, Z., Horňáček, M., Rakovský, J., Hudec, P., and Veis, P. (2012) Calibration analysis of zeolites by laser induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 74: 119-123.
57. Lasheras, R., Bello-Gálvez, C., and Anzano, J. (2013) Quantitative analysis of oxide materials by laser-induced breakdown spectroscopy with argon as an internal standard. Spectrochim. Acta B Atom. Spectros., 82: 65-70.
58. Grant, K.J., Paul, G.L., and O'Neill, J.A. (1991) Quantitative elemental analysis of iron ore by laser-induced breakdown spectroscopy. Appl. Spectros., 45 (4): 701-705.
59. Bolger, J. (2000) Semi-quantitative laser-induced breakdown spectroscopy for analysis of mineral drill core. Appl. Spectros., 54 (2): 181-189.
60. Tucker, J., Dyar, M., Schaefer, M., Clegg, S., and Wiens, R. (2010) Optimization of laserinduced breakdown spectroscopy for rapid geochemical analysis. Chem. Geol., 277 (1): 137-148.
61. Motto-Ros, V., Koujelev, A.S., Osinski, G.R., and Dudelzak, A.E. (2008) Quantitative multielemental laser-induced breakdown spectroscopy using artificial neural networks. J. Eur. Opt. Soc., 3 (08011): 1-5.
62. Anderson, R.B., Morris, R.V., Clegg, S.M., Bell, J.F., III, Wiens, R.C., Humphries, S.D., Mertzman, S.A., Graff, T.G., and McInroy, R. (2011) The influence of multivariate analysis methods and target grain size on the accuracy of remote quantitative chemical analysis of rocks using laser induced breakdown spectroscopy. Icarus, 215 (2): 608-627.
63. Dyar, M., Carmosino, M., Breves, E., Ozanne, M., Clegg, S., and Wiens, R. (2012) Comparison of partial least squares and lasso regression techniques as applied to laser-induced breakdown spectroscopy of geological samples. Spectrochim. Acta B Atom. Spectros., 70: 51-67.
64. Colao, F., Fantoni, R., Lazic, V., Paolini, A., Fabbri, F., Ori, G.G., Marinangeli, L., and Baliva, A. (2004) Investigation of LIBS feasibility for in situ planetary exploration: An analysis on Martian rock analogues. Planet. Space Sci., 52 (1-3): 117-123.
65. Sallé, B., Lacour, J.L., Mauchien, P., Fichet, P., Maurice, S., and Manhès, G. (2006) Comparative study of different methodologies for quantitative rock analysis by Laser-induced breakdown spectroscopy in a simulated Martian atmosphere. Spectrochim. Acta B Atom. Spectros., 61 (3): 301-313.
66. Anzano, J.M., Villoria, M.A., Ruiz-Medina, A., and Lasheras, R.J. (2006) Laser-induced breakdown spectroscopy for quantitative spectrochemical analysis of geological materials: Effects of the matrix and simultaneous determination. Anal. Chim. Acta, 575 (2): 230-235.
67. Death, D.L., Cunningham, A.P., and Pollard, L.J. (2008) Multi-element analysis of iron ore pellets by laser-induced breakdown spectroscopy and principal components regression. Spectrochim. Acta B Atom. Spectros., 63 (7): 763-769.
68. Yaroshchyk, P., Death, D.L., and Spencer, S.J. (2010) Quantitative measurements of loss on ignition in iron ore using laser-induced breakdown spectroscopy and partial least squares regression analysis. Appl. Spectros., 64 (12): 1335-1341.
69. Gondal, M.A., Hussain, T., Yamani, Z.H., and Ahmed, Z. (2007) Determination of toxic metals in petroleum, cultivated land and ore samples using laser-induced breakdown spectroscopy. Bull. Environ. Contam. Toxicol., 78 (3-4): 270-274.
70. Kwak, J.-H., Lenth, C., Salb, C., Ko, E.-J., Kim, K.-W., and Park, K. (2009) Quantitative analysis of arsenic in mine tailing soils using double pulse-laser induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 64 (10): 1105-1110.
71. Grant, K.J., Paul, G.L., and O'Neill, J.A. (1990) Time-resolved laser-induced breakdown spectroscopy of iron ore. Appl. Spectros., 44 (10): 1711-1714.
72. Barrette, L., and Turmel, S. (2001) On-line iron-ore slurry monitoring for real-time process control of pellet making processes using laser-induced breakdown spectroscopy: Graphitic vs. total carbon detection. Spectrochim. Acta B Atom. Spectros., 56 (6): 715-723.
73. Sun, Q., Tran, M., Smith, B., and Winefordner, J. (2000) Determination of Mn and Si in iron ore by laser-induced plasma spectroscopy. Anal. Chim. Acta, 413 (1): 187-195.
74. Death, D.L., Cunningham, A.P., and Pollard, L.J. (2009) Multi-element and mineralogical analysis of mineral ores using laser induced breakdown spectroscopy and chemometric analysis. Spectrochim. Acta B Atom. Spectros., 64 (10): 1048-1058.
75. Michaud, D., Leclerc, R., and Proulx, É. (2007) Influence of particle size and mineral phase in the analysis of iron ore slurries by laser-induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 62 (12): 1575-1581.
76. Rosenwasser, S., Asimellis, G., Bromley, B., Hazlett, R., Martin, J., Pearce, T., and Zigler, A. (2001) Development of a method for automated quantitative analysis of ores using LIBS. Spectrochim. Acta B Atom. Spectros., 56 (6): 707-714.
77. Asimellis, G., Giannoudakos, A., and Kompitsas, M. (2006) Phosphate ore beneficiation via determination of phosphorus-to-silica ratios by laser induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 61 (12): 1253-1259.
78. Harmon, R.S., Shughrue, K.M., Remus, J.J., Wise, M.A., East, L.J., and Hark, R.R. (2011) Can the provenance of the conflict minerals columbite and tantalite be ascertained by laser-induced breakdown spectroscopy? Anal. Bioanal. Chem., 400 (10): 3377-3382.
79. Hark, R.R., Remus, J.J., East, L.J., Harmon, R.S., Wise, M.A., Tansi, B.M., Shughrue, K.M., Dunsin, K.S., and Liu, C. (2012) Geographical analysis of "conflict minerals" utilizing laser-induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 74-75: 131-136.
80. Dyar, M.D., Carmosino, M.L., Tucker, J.M., Brown, E.A., Clegg, S.M., Wiens, R.C., Barefield, J.E., Delaney, J.S., Ashley, G.M., and Driese, S.G. (2012) Remote laser-induced breakdown spectroscopy analysis of East African Rift sedimentary samples under Mars conditions. Chem. Geol., 294-295: 135-151.
81. 2 atmosphere. Appl. Phys. A, 79 (1): 143-152.
82. Radziemski, L., Cremers, D.A., Benelli, K., Khoo, C., and Harris, R.D. (2005) Use of the vacuum ultraviolet spectral region for laser-induced breakdown spectroscopy-based Martian geology and exploration. Spectrochim. Acta B Atom. Spectros., 60 (2): 237-248.
83. Rauschenbach, I., Lazic, V., Pavlov, S.G., Hübers, H.W., and Jessberger, E.K. (2008) Laser induced breakdown spectroscopy on soils and rocks: Influence of the sample temperature, moisture and roughness. Spectrochim. Acta B Atom. Spectros., 63 (10): 1205-1215.
84. Thompson, J., Wiens, R., Cremers, D., Barefield, J., and Wetteland, C. (2004). The suitability of laser induced breakdown spectroscopy for determining the compositions of extraterrestrial material. 35th Lunar and Planetary Science Conference, League City, TX, March 15-19.
85. Pavlov, S.G., Jessberger, E.K., Hübers, H.W., Schröder, S., Rauschenbach, I., Florek, S., Neumann, J., Henkel, H., and Klinkner, S. (2011) Miniaturized laser-induced plasma spectrometry for planetary in situ analysis-The case for Jupiter's moon Europa. Adv. Space Res., 48 (4): 764-778.
86. Thompson, J.R., Wiens, R.C., Barefield, J.E., Vaniman, D.T., Newsom, H.E., and Clegg, S.M. (2006) Remote laser-induced breakdown spectroscopy analyses of Dar al Gani 476 and Zagami Martian meteorites. J. Geophys. Res., 111 (E05006): 1-9.
87. De Giacomo, A., Dell'Aglio, M., De Pascale, O., Longo, S., and Capitelli, M. (2007) Laser induced breakdown spectroscopy on meteorites. Spectrochim. Acta B Atom. Spectros., 62 (12): 1606-1611.
88. Dell'Aglio, M., De Giacomo, A., Gaudiuso, R., Pascale, O.D., Senesi, G.S., and Longo, S. (2010) Laser induced breakdown spectroscopy applications to meteorites: Chemical analysis and composition profiles. Geochim. Cosmochim. Acta, 74 (24): 7329-7339.
89. Wiens, R.C., Maurice, S., Barraclough, B., Saccoccio, M., Barkley, W.C., Bell, J.F., Bender, S., Bernardin, J., Blaney, D., Blank, J., Bouyé, M., Bridges, N., Bultman, N., Caïs, P., Clanton, R.C., Clark, B., Clegg, S., Cousin, A., Cremers, D., Cros, A., DeFlores, L., Delapp, D., Dingler, R., D'Uston, C., Darby Dyar, M., Elliott, T., Enemark, D., Fabre, C., Flores, M., Forni, O., Gasnault, O., Hale, T., Hays, C., Herkenhoff, K., Kan, E., Kirkland, L., Kouach, D., Landis, D., Langevin, Y., Lanza, N., LaRocca, F., Lasue, J., Latino, J., Limonadi, D., Lindensmith, C., Little, C., Mangold, N., Manhes, G., Mauchien, P., McKay, C., Miller, E., Mooney, J., Morris, R. V., Morrison, L., Nelson, T., Newsom, H., Ollila, A., Ott, M., Pares, L., Perez, R., Poitrasson, F., Provost, C., Reiter, J. W., Roberts, T., Romero, F., Sautter, V., Salazar, S., Simmonds, J. J., Stiglich, R., Storms, S., Striebig, N., Thocaven, J.-J., Trujillo, T., Ulibarri, M., Vaniman, D., Warner, N., Waterbury, R., Whitaker, R., Witt, J., and Wong-Swanson, B. (2012) The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body unit and combined system tests. Space Sci. Rev., 170 (1-4): 167-227.
90. Williams, R., Grotzinger, J.P., Dietrich, W., Gupta, S., Sumner, D., Wiens, R., Mangold, N., Malin, M., Edgett, K., and Maurice, S. (2013) Martian fluvial conglomerates at Gale crater. Science, 340 (6136): 1068-1072.
91. 2 atmosphere. Appl. Phys. Mater. Sci. Process., 79 (1): 143-152.
92. McSween, H.Y. (2002) The rocks of Mars, from far and near. Meteoritics & Planetary Science, 37 (1): 7-25.
93. Fabre, C., Maurice, S., Cousin, A., Wiens, R.C., Forni, O., Sautter, V., and Guillaume, D. (2011) Onboard calibration igneous targets for the Mars Science Laboratory Curiosity rover and the Chemistry Camera laser induced breakdown spectroscopy instrument. Spectrochim. Acta B Atom. Spectros., 66 (3-4): 280-289.
94. Dyar, M.D., Tucker, J.M., Humphries, S., Clegg, S.M., Wiens, R.C., and Lane, M.D. (2011) Strategies for Mars remote laser-induced breakdown spectroscopy analysis of sulfur in geological samples. Spectrochim. Acta B Atom. Spectros., 66 (1): 39-56.
95. Sobron, P., Wang, A., and Sobron, F. (2012) Extraction of compositional and hydration information of sulfates from laser-induced plasma spectra recorded under Mars atmospheric conditions-Implications for ChemCam investigations on Curiosity rover. Spectrochim. Acta B Atom. Spectros., 68: 1-16.
96. Lanza, N.L., Wiens, R.C., Clegg, S.M., Ollila, A.M., Humphries, S.D., Newsom, H.E., and Barefield, J.E. (2010) Calibrating the ChemCam laser-induced breakdown spectroscopy instrument for carbonate minerals on Mars. Appl. Optic., 49 (13): C211-C217.
97. Stipe, C.B., Guevara, E., Brown, J., and Rossman, G.R. (2012) Quantitative laser-induced breakdown spectroscopy of potassium for in-situ geochronology on Mars. Spectrochim. Acta B Atom. Spectros., 70: 45-50.
98. Wiens, R.C., Maurice, S., Lasue, J., Forni, O., Anderson, R.B., Clegg, S., Bender, S., Blaney, D., Barraclough, B.L., Cousin, A., Deflores, L., Delapp, D., Dyar, M.D., Fabre, C., Gasnault, O., Lanza, N., Mazoyer, J., Melikechi, N., Meslin, P. Y., Newsom, H., Ollila, A., Perez, R., Tokar, R.L., and Vaniman, D. (2013) Pre-flight calibration and initial data processing for the ChemCam laser-induced breakdown spectroscopy instrument on the Mars Science Laboratory rover. Spectrochim. Acta B Atom. Spectros., 82: 1-27.
99. Lasue, J., Wiens, R.C., Stepinski, T.F., Forni, O., Clegg, S.M., Maurice, S., and Chem-Cam, T. (2011) Nonlinear mapping technique for data visualization and clustering assessment of LIBS data: Application to ChemCam data. Anal. Bioanal. Chem., 400 (10): 3247-3260.
100. Sirven, J.-B., Sallé, B., Mauchien, P., Lacour, J.-L., Maurice, S., and Manhès, G. (2007) Feasibility study of rock identification at the surface of Mars by remote laser-induced breakdown spectroscopy and three chemometric methods. JAAS: Journal of Analytical Atomic Spectrometry, 22 (12): 1471-1480.
101. Ollila, A.M., Lasue, J., Newsom, H.E., Multari, R.A., Wiens, R.C., and Clegg, S.M. (2012) Comparison of two partial least squares-discriminant analysis algorithms for identifying geological samples with the ChemCam laser-induced breakdown spectroscopy instrument. Appl. Optic., 51 (7): B130-B142.
102. Lasue, J., Forni, O., Anderson, R., Berger, G., Clegg, S., Cousin, A., Dyar, M., Fabre, C., Gasnault, O., and Lewin, E. (2013). Partial least squares sensitivity analysis and improvements for ChemCam LIBS data analysis on Mars. 44th Lunar and Planetary Science Conference, Houston, TX, March 18-22.
103. Cousin, A., Forni, O., Maurice, S., Gasnault, O., Fabre, C., Sautter, V., Wiens, R.C., and Mazoyer, J. (2011) Laser induced breakdown spectroscopy library for the Martian environment. Spectrochim. Acta B Atom. Spectros., 66 (11-12): 805-814.
104. McCanta, M.C., Dobosh, P.A., Dyar, M.D., and Newsom, H.E. (2013) Testing the veracity of LIBS analyses on Mars using the LIBSSIM program. Planet. Space Sci., 81: 48-54.
105. Arp, Z.A., Cremers, D.A., Harris, R.D., Oschwald, D.M., Parker, G.R., and Wayne, D.M. (2004) Feasibility of generating a useful laser-induced breakdown spectroscopy plasma on rocks at high pressure: Preliminary study for a Venus mission. Spectrochim. Acta B Atom. Spectros., 59 (7): 987-999.
106. Sharma, S., Misra, A., Clegg, S., Barefield, J., Wiens, R., Quick, C., Dyar, M., McCanta, M., and Elkins-Tanton, L. (2009). Venus geochemical analysis by remote Raman-laser induced breakdown spectroscopy (Raman-LIBS). 40th Lunar and Planetary Science Conference, Houston, TX, March 23-27.
107. Clegg, S., Barefield, J., Wiens, R., Sharma, S., Misra, A., Tucker, J., Dyar, M., Lambert, J., Smrekar, S., and Treiman, A. (2010). Venus geochemical analysis by remote laser-induced breakdown spectroscopy (LIBS). 41st Lunar and Planetary Science Conference, Houston, TX, March 1-5.
108. Lambert, J., Morookian, J., Roberts, T., Polk, J., Smrekar, S., Clegg, S., Weins, R., Dyar, M., and Treiman, A. (2010). Standoff LIBS and Raman spectroscopy under Venus conditions. 41st Lunar and Planetary Science Conference, Houston, TX, March 1-5.
109. Clegg, S., Sharma, S., Misra, A., Dyar, M., Hecht, M., Lambert, J., Feldman, S., Dallmann, N., Wiens, R., and Humphries, S. (2011). Remote Raman-laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions. 42nd Lunar and Planetary Science Conference, Houston, TX, March 7-11.
110. Clegg, S., Sharma, S., Misra, A., Dyar, M., Dallmann, N., Wiens, R., Vaniman, D., Speicher, E., Smrekar, S., and Wang, A. (2012). Raman and laser-induced breakdown spectroscopy (LIBS) remote geochemical analysis under Venus atmospheric pressure. 43rd Lunar and Planetary Science Conference, Houston, TX, March 19-23.
111. McDermott, F. (2004) Palaeo-climate reconstruction from stable isotope variations in speleothems: A review. Quaternary Sci. Rev., 23 (7-8): 901-918.
112. Vadillo, J.M., Vadillo, I., Carrasco, F., and Laserna, J. (1998) Spatial distribution profiles of magnesium and strontium in speleothems using laser-induced breakdown spectrometry. Fresen. J. Anal. Chem., 361 (2): 119-123.
113. Ma, Q.L., Motto-Ros, V., Lei, W.Q., Boueri, M., Zheng, L.J., Zeng, H.P., Bar-Matthews, M., Ayalon, A., Panczer, G., and Yu, J. (2010) Multi-elemental mapping of a speleothem using laser-induced breakdown spectroscopy. Spectrochim. Acta B Atom. Spectros., 65 (8): 707-714.
114. Galbács, G., Kevei-Bárány, I., Szo{double acute}ke, E., Jedlinszki, N., Gornushkin, I.B., and Galbács, M.Z. (2011) A study of stalagmite samples from Baradla Cave (Hungary) by laser induced plasma spectrometry with automatic signal correction. Microchem. J., 99 (2): 406-414.
115. Fortes, F.J., Vadillo, I., Stoll, H., Jiménez-Sánchez, M., Moreno, A., and Laserna, J.J. (2012) Spatial distribution of paleoclimatic proxies in stalagmite slabs using laser-induced breakdown spectroscopy. JAAS: Journal of Analytical Atomic Spectrometry, 27 (5): 868-873.
116. Barbini, R., Colao, F., Fantoni, R., Lazic, V., Palucci, A., Capitelli, F., and Van der Steen, H. (2000). Laser induced breakdown spectroscopy for semi-quantitative elemental analysis in soils and marine sediments. In 4th EARSeL Workshop Lidar Remote Sensing of Land and Sea, Dresden, Germany, June 16-17.
117. Lazic, V., Barbini, R., Colao, F., Fantoni, R., and Palucci, A. (2001) Self-absorption model in quantitative laser induced breakdown spectroscopy measurements on soils and sediments. Spectrochim. Acta B Atom. Spectros., 56 (6): 807-820.
118. Barbini, R., Colao, F., Lazic, V., Fantoni, R., Palucci, A., and Angelone, M. (2002) On board LIBS analysis of marine sediments collected during the XVI Italian campaign in Antarctica. Spectrochim. Acta B Atom. Spectros., 57 (7): 1203-1218.
119. Fabre, C., Boiron, M.-C., Dubessy, J., and Moissette, A. (1999) Determination of ions in individual fluid inclusions by laser ablation optical emission spectroscopy: Development and applications to natural fluid inclusions. JAAS: Journal of Analytical Atomic Spectrometry, 14 (6): 913-922.
120. Fabre, C., Boiron, M.-C., Dubessy, J., Cathelineau, M., and Banks, D.A. (2002) Palaeofluid chemistry of a single fluid event: A bulk and in-situ multi-technique analysis (LIBS, Raman spectroscopy) of an Alpine fluid (Mont-Blanc). Chem. Geol., 182 (2): 249-264.
121. Derome, D., Cuney, M., Cathelineau, M., Fabre, C., Dubessy, J., Bruneton, P., and Hubert, A. (2003) A detailed fluid inclusion study in silicified breccias from the Kombolgie sandstones (Northern Territory, Australia): Inferences for the genesis of middle-Proterozoic unconformitytype uranium deposits. J. Geochem. Explor., 80 (2-3): 259-275.
122. Derome, D., Cathelineau, M., Fabre, C., Boiron, M.-C., Banks, D., Lhomme, T., and Cuney, M. (2007) Paleo-fluid composition determined from individual fluid inclusions by Raman and LIBS: Application tomid-proterozoic evaporitic Na-Ca brines (Alligator Rivers Uranium Field, northern territories Australia). Chem. Geol., 237 (3-4): 240-254.
123. Derome, D., Cathelineau, M., Cuney, M., Fabre, C., Lhomme, T., and Banks, D.A. (2005) Mixing of sodic and calcic brines and uranium deposition at McArthur River, Saskatchewan, Canada: A Raman and laser-induced breakdown spectroscopic study of fluid inclusions. Econ. Geol., 100 (8): 1529-1545.