Amphiphilic invertible polymers (AIPs): Micellization and self-assembly in aqueous solutions

ACS Symposium Series

Volumn 1070, Issue , 2011, Pages 205-224

  Kohut, A ^a   Sieburg, L ^a,b   Vasylyev, S ^c   Kudina, O ^d   Hevus, I ^a   Stafslien, S ^e   Daniels, J ^e   Kislenko, V ^d   Voronov, A ^a  

^a NORTH DAKOTA STATE UNIVERSITY   (United States)

^b UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^c UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^d LVIV POLYTECHNIC NATIONAL UNIVERSITY   (Ukraine)

^e Center for Nanoscale Science and Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

POLYETHYLENE GLYCOLS;

ALIPHATIC DICARBOXYLIC ACIDS; AMPHIPHILICS; AQUEOUS MEDIUM; COMPLEX NANOSTRUCTURES; CONFORMATIONAL CHANGE; INSOLUBLE SUBSTANCES; PHARMACEUTICAL INDUSTRY; SELF-ASSEMBLE;

POLYMERS;

EID: 84905509518     PISSN: 00976156     EISSN: 19475918     Source Type: Book Series    
DOI: 10.1021/bk-2011-1070.ch013     Document Type: Conference Paper

References (56)

1. Cohen Stuart, M. A.; Huck, W. T. S.; Genzer, J.; Müller, M.; Ober, C.; Stamm, M.; Sukhorukov, G. B.; Szleifer, I.; Tsukruk, V. V.; Urban, M.; Winnik, F.; Zauscher, S.; Luzinov, I.; Minko, S. Emerging applications of stimuli-responsive polymer materials. Nat. Mater. 2010, 9, 101-113.
2. Hamley, I. W. Introduction to Soft Matter: Polymers, Colloids, Amphiphilies and Liquid Crystals; Wiley: Chichester, U.K., 2000.
3. McPherson, A. Crystallization of macromolecules: general principles. Methods Enzymol. 1985, 114, 112-120.
4. Cudney, R.; Patel, S.; Weisgraber, K.; Newhouse, Y.; McPherson, A. Screening and optimization strategies for macromolecular crystal growth. Acta Crystallogr. 1994, 50, 414-423.
5. Harris, J. M. In Poly(Ethylene Glycol) Chemistry: Biotechnical and Biomedical Applications; Harris, J. M., Ed.; Plenum Press: New York, 1992.
6. Andrade, J. D.; Hlady, V.; Jeon, S.-I. In Hydrophilic Polymers: Performance with Environmental Acceptance; Glass, J. E., Ed.; Advances in Chemistry Series 248; American Chemical Society: Washington, DC, 1996; pp 51-59.
7. Sakai, T.; Alexandridis, P. Size-and shape-controlled synthesis of colloidal gold through autoreduction of the auric cation by poly(ethylene oxide)-poly(propylene oxide) block copolymers in aqueous solutions at ambient conditions. Nanotechnology 2005, 16, S344-S353.
8. Alexandridis, P. Poly(ethylene oxide)/poly(propylene oxide) block copolymer surfactants. Curr. Opin. Colloid Interface Sci. 1997, 2, 478-489.
9. Adams, M. L.; Lavasanifar, A.; Kwon, G. S. Amphiphilic block copolymers for drug delivery. J. Pharm. Sci. 2003, 92, 1343-1355.
10. Mortensen, K. In Amphiphilic Block Copolymers; Alexandridis P., Lindman, B., Eds.; Elsevier: New York, 2000.
11. Rosch, H. In Nonionic surfactants; Schick, M. J., Ed.; Dekker: New York, 1967.
12. Alexandridis, P.; Holzwarth, J. F.; Hatton, T. A. Micellization of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymers in aqueous solutions: Thermodynamics of copolymer association. Macromolecules 1994, 27, 2414-2425.
13. Pedersen, J. S.; Gerstenberg, M. C. The structure of P85 Pluronic block copolymer micelles determined by small-angle neutron scattering. Colloids Surf., A 2003, 213, 175-187.
14. Wanka, G.; Hoffmann, H.; Ulbricht, W. Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions. Macromolecules 1994, 27, 4145-4159.
15. Tanford, C. The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd ed.; John Wiley & Sons: New York, 1980.
16. Liu, S. Y.; Armes, S. P. Polymeric surfactants for the new millennium: A pHresponsive, zwitterionic, schizophrenic diblock copolymer. Angew. Chem., Int. Ed. 2002, 41, 1413-1416.
17. Cogan, K. A.; Gast, A. P. Effect of water on diblock copolymers in oil: large aggregates, micelles, and microemulsions. Macromolecules 1990, 23, 745-753.
18. Halperin, A.; Tirrell, M.; Lodge, T. P. Tethered chains in polymer microstructures. Adv. Polym. Sci. 1991, 100, 31-71.
19. Winsor, P. A. In Liquid Crystals and Plastic Crystals; Gray, G. W., Winsor, P. A., Eds.; Ellis Harwood Ltd.: Chichester, U.K., 1974; Vol. 1, Chapter 5.
20. Voronov, A.; Kohut, A.; Peukert, W.; Voronov, S.; Gevus, O.; Tokarev, V. Invertible Architectures from Amphiphilic Polyesters. Langmuir 2006, 22 (5), 1946-1948.
21. Basu, S.; Vutukuri, D. R.; Shyamroy, S.; Sandanaraj, B. S.; Thayumanavan, S. Invertible Amphiphilic Homopolymers. J. Am. Chem. Soc. 2004, 126, 9890-9891.
22. Kohut, A.; Ranjan, S.; Voronov, A.; Peukert, W.; Tokarev, V.; Bednarska, O.; Gevus, O.; Voronov, S. Design of a New Invertible Polymer Coating on a Solid Surface and Its Effect on Dispersion Colloidal Stability. Langmuir 2006, 22 (15), 6498-6506.
23. Kohut, A.; Voronov, A.; Peukert, W. An Effective Way to Stabilize Colloidal Particles Dispersed in Polar and Nonpolar Media. Langmuir 2007, 23 (2), 504-508.
24. Voronov, A.; Kohut, A.; Peukert, W. Synthesis of Amphiphilic Silver Nanoparticles in Nanoreactors from Invertible Polyester. Langmuir 2007, 23 (2), 360-363.
25. Kohut, A.; Voronov, A.; Samaryk, V.; Peukert, W. Amphiphilic Invertible Polyesters as Reducing and Stabilizing Agents in the Formation of Metal Nanoparticles. Macromol. Rapid Commun. 2007, 28, 1410-1414.
26. Martinez Tomalino, L.; Voronov, A.; Kohut, A.; Peukert, W. Study of Amphiphilic Polyester Micelles by Hyper-Rayleigh Scattering: Invertibility and Phase Transfer. J. Phys. Chem. B 2008, 112 (20), 6338-6343.
27. Voronov, A.; Vasylyev, S.; Kohut, A.; Peukert, W. Surface activity of new invertible amphiphilic polyesters based on poly(ethylene glycol) and aliphatic dicarboxylic acids. J. Colloid Interface Sci. 2008, 323 (2), 379-385.
28. Voronov, A.; Kohut, A.; Vasylyev, S.; Peukert, W. Mechanism of silver ion reduction in concentrated solutions amphiphilic invertible polyesters in nonpolar solvent at room temperature. Langmuir 2008, 24 (21), 12587-12594.
29. Kohut, A.; Voronov, A. Hierarchical Micellar Structures from Amphiphilic Invertible Polyesters: 1H NMR Spectroscopic Study. Langmuir 2009, 25 (8), 4356-4360.
30. Shafranska, O.; Voronov, A.; Kohut, A.; Wu, X.-F.; Akhatov, I. S. Polymer-metal complexes as a catalyst for the growth of carbon nanostructures. Carbon 2009, 47 (13), 3137-3139.
31. Arumugam, S.; Vutukuri, D. R.; Thayumanavan, S.; Ramamurthy, V. Amphiphilic Homopolymer as a Reaction Medium in Water: Product Selectivity within Polymeric Nanopockets. J. Am. Chem. Soc. 2005, 127, 13200-13206.
32. Davies, J. T.; Rideal, E. K. Interfacial Phenomena; Academic Press: New York, 1961; p 371.
33. Sadron, Ch. Angew. Chem., Int. Ed. 1962, 2, 5.
34. Tuzar, Z.; Kratochvil, P. Adv. Colloid Interface Sci. 1976, 6, 201.
35. Saito, Y. J. Jpn. Oil Chem. Soc. (Oleo Science) 2000, 49, 1071.
36. Suzuki, K.; Saito, Y.; Horiuchi, T.; Tokuoka, Y.; Abe, M.; Sato, T. J. Soc. Cosmet. Chem. Jpn. 1996, 30, 330.
37. Schmitz, C.; Mourran, A.; Keul, H.; Möller, M. Macromol. Chem. Phys. 2008, 209, 1859-1871.
38. Wilhelm, M.; Zhao, C. L.; Wang, Y.; Xu, R.; Winnik, M. A.; Mura, J. L.; Riess, G.; Croucher, M. D. Macromolecules 1991, 24, 1033.
39. Wanka, G.; Hoffmann, H.; Ulbricht, W. Macromolecules 1994, 27, 4145-4159.
40. Kim, B. J.; Im, S. S.; Oh, S. G. Langmuir 2001, 17, 565-566.
41. Wu, J.; Harwell, J. H.; O'Rear, E. A. Langmuir 1987, 3, 531-537.
42. Zhu, B. Y.; Xhao, X.; Gu, T. J. Chem. Soc., Faraday Trans. 1 1988, 84, 3951-3960.
43. Esumi, K.; Yamada, T. Langmuir 1993, 9, 622-624.
44. Sakai, K.; Nakajima, E.; Takamatsu, Y.; Sharma, S. C.; Torigoe, K.; Yoshimura, T.; Esumi, K.; Sakai, H.; Abe, M. J. Oleo Sci. 2008, 57, 423-429.
45. Sakhalkar, S. S.; Hirt, D. E. Langmuir 1995, 11, 3369-3373.
46. Rosen, M. J.; Li, F. J. Colloid Interface Sci. 2001, 234, 418-424.
47. Zhao, W. R.; Gu, J. L.; Zhang, L. X.; Chen, H. R.; Shi, J. L. J. Am. Chem. Soc. 2005, 127, 8916-8917.
48. Zhu, Y. F.; Shi, J. L.; Shen, W. H.; Dong, X. P.; Feng, J. W.; Ruan, M. L.; Li, Y. S. Stimuli-responsive controlled drug release from a hollow mesoporous silica sphere/polyelectrolyte multilayer core-shell structure. Angew. Chem., Int. Ed. 2005, 44, 5083-5087.
49. Nuysink, J.; Koopal, L. K. The effect of polyethylene oxide molecular weight on determination of its concentration in aqueous solutions. Talanta 1982, 29, 495-501.
50. Tsurumi, D.; Yoshimura, T.; Esumi, K. Adsolubilization of 2-naphthol into adsorbed layer of PEO-PPO-PEO triblock copolymers on hydrophilic silica. J. Colloid Interface Sci. 2006, 297, 465-469.
51. Tsurumi, D.; Sakai, K.; Yoshimura, T.; Esumi, K. Adsolubilization of 2-naphthol into adsorbed layers of triblock PEO-PPO-PEO copolymers on hydrophobic silica particles. J. Colloid Interface Sci. 2006, 302, 82-86.
52. Ghoneim, N. Photophysics of Nile Red in solution-Steady state Spectroscopy. Spectrochim. Acta, Part A 2000, 56, 1003.
53. Torchilin, V. P. Targeted polymeric micelles for delivery of poorly soluble drugs. Cell. Mol. Life Sci. 2004, 61 (19-20), 2549-2559.
54. Sinha, R.; Kim, G. J.; Nie, S.; Shin, D. M. Nanotechnology in cancer therapeutics: bioconjugated nanoparticles for drug delivery. Mol. Cancer Ther. 2006, 5 (8), 1909-1917.
55. Das, M.; Mohanty, C.; Sahoo, S. K. Ligand-based targeted therapy for cancer tissue. Expert Opin. Drug Delivery 2009, 6 (3), 285-304.
56. Sutton, D.; Nasongkla, N.; Blanco, E.; Gao, J. Functionalized Micellar Systems for Cancer Targeted Drug Delivery. Pharm. Res. 2007, 24 (6), 1029-1046.