The surface barrier phenomenon at the loading of metal-organic frameworks

Nature Communications

Volumn 5, Issue , 2014, Pages

  Heinke, Lars ^a   Gu, Zhigang ^a   Wöll, Christof ^a  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; CUPRIC ION; CYCLOHEXANE; METAL ORGANIC FRAMEWORK;

BIOFILM; MAGNITUDE; MASS TRANSFER; METAL; MOLECULAR ANALYSIS; POROUS MEDIUM; QUANTITATIVE ANALYSIS; QUARTZ; WATER VAPOR;

ADSORPTION; AIR; ARTICLE; CHEMICAL PHENOMENA; CRYSTAL STRUCTURE; DECELERATION; FILM; FLOW RATE; HUMIDITY; PERMEABILITY; QUANTITATIVE ANALYSIS; QUARTZ CRYSTAL MICROBALANCE; SURFACE PROPERTY; SYNTHESIS; WATER VAPOR; X RAY DIFFRACTION;

EID: 84905493986     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms5562     Document Type: Article

References (38)

1. Zhou, H. C., Long, J. R. & Yaghi, O. M. Introduction to metal-organic frameworks. Chem. Rev. 112, 673-674 (2012
2. Farha, O. K. et al. Metal-organic framework materials with ultrahigh surface areas: is the sky the limit? J. Am. Chem. Soc. 134, 15016-15021 (2012
3. Lu, W.-G., Zhong, D.-C., Jiang, L. & Lu, T.-B. Lanthanide coordination polymers constructed from Imidazole-4,5-dicarboxylate and sulfate: syntheses, structural diversity, and photoluminescent properties. Cryst. Growth Des. 12, 3675-3683 (2012
4. Gu, Z.-G. et al. Construction of metal-imidazole-based dicarboxylate networks with topological diversity: thermal stability, gas adsorption, and fluorescent emission properties. Crystal Growth Design 12, 2178-2186 (2012
5. Vermoortele, F. et al. Tuning the catalytic performance of metal-organic frameworks in fine chemistry by active site engineering. J. Materials Chem. 22, 10313-10321 (2012
6. Tan, Y. X., He, Y. P. & Zhang, J. Tuning MOF stability and porosity via adding rigid Pillars. Inorg. Chem. 51, 9649-9654 (2012
7. Purewal, J. J. et al. Increased volumetric hydrogen uptake of MOF-5 by powder densification. Int. J. Hydrogen Energy 37, 2723-2727 (2012
8. 2 adsorption from ultradilute gases. J. Phys. Chem. Lett. 3, 1136-1141 (2012
9. Li, J.-R., Sculley, J. & Zhou, H.-C. Metal-organic frameworks for separations. Chem. Rev. 112, 869-932 (2011
10. Lee, J. et al. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 38, 1450-1459 (2009
11. Kreno, L. E. et al. Metal-organic framework materials as chemical sensors. Chem. Rev. 112, 1105-1125 (2011
12. Xu, C. et al. Hydrogen permeation and diffusion in densified MOF-5 pellets. Int. J. Hydrogen Energy 38, 3268-3274 (2013
13. Saha, D., Wei, Z. & Deng, S. Hydrogen adsorption equilibrium and kinetics in metal-organic framework (MOF-5) synthesized with DEF approach. Sep. Purif. Technol. 64, 280-287 (2009
14. Zhao, Z., Ma, X., Li, Z. & Lin, Y. S. Synthesis, characterization and gas transport properties of MOF-5 membranes. J. Memb. Sci. 382, 82-90 (2011
15. Zhao, Z. X., Li, Z. & Lin, Y. S. Adsorption and diffusion of carbon dioxide on metal-organic framework (MOF-5). Ind. Eng. Chem. Res. 48, 10015-10020 (2009
16. Kärger, J. et al. Unprecedented insight into diffusion by monitoring the concentration of guest molecules in nanoporous host materials. Angew. Chem. Int. Ed. 45, 7846-7849 (2006 (Pubitemid 44871360)
17. Heinke, L. et al. Assessing guest diffusivities in porous hosts from transient concentration profiles. Phys. Rev. Lett. 102, 065901 (2009
18. Sholl, D. S. Metal-organic frameworks: a porous maze. Nat. Chem. 3, 429-430 (2011
19. Micke, A., Bulow, M. & Kocirik, M. A nonequilibrium surface barrier for sorption kinetics of p-Ethyltoluene on ZSM-5 molecular sieves. J. Phys. Chem. 98, 924-929 (1994
20. Kärger, J., Ruthven, D. M. & Theodorou, D. N. Diffusion in Nanoporous Materials (Wiley-VCH, 2012
21. Barrer, R. M. Zeolites and Clay Minerals as Sorbents and Molecular Sieves (Academic Press, 1978
22. Shekhah, O., Liu, J., Fischer, R. A. & Wöll, C. MOF thin films: existing and future applications. Chem. Soc. Rev. 40, 1081-1106 (2011
23. Munuera, C., Shekhah, O., Wang, H., Wöll, C. & Ocal, C. The controlled growth of oriented metal-organic frameworks on functionalized surfaces as followed by scanning force microscopy. Phys. Chem. Chem. Phys. 10, 7257-7261 (2008
24. Heinke, L. & Wöll, C. Adsorption and diffusion in thin films of nanoporous metal-organic frameworks: ferrocene in SURMOF Cu2(ndc)2(dabco). Phys. Chem. Chem. Phys. 15, 9295-9299 (2013
25. Zybaylo, O. et al. A novel method to measure diffusion coefficients in porous metal-organic frameworks. Phys. Chem. Chem. Phys. 12, 8092-8097 (2010
26. Heinke, L. et al. Photoswitching in two-component surface-mounted metalorganic frameworks: optically triggered release from a molecular container. ACS Nano 8, 1463-1467 (2014
27. Chui, S. S. Y., Lo, S. M. F., Charmant, J. P. H., Orpen, A. G. & Williams, I. D. A chemically functionalizable nanoporous material Cu-3(TMA)(2)(H2O)(3) (n). Science 283, 1148-1150 (1999
28. Schlichte, K., Kratzke, T. & Kaskel, S. Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound CU3(BTC)(2). Micropor. Mesopor. Mater. 73, 81-88 (2004 (Pubitemid 38945996)
29. Alaerts, L. et al. Probing the Lewis acidity and catalytic activity of the metal-organic framework Cu-3(btc)(2) (BTC=benzene-1,3,5-tricarboxylate). Chemistry 12, 7353-7363 (2006 (Pubitemid 44483827)
30. Plaza, M. G. et al. Propane/propylene separation by adsorption using shaped copper trimesate MOF. Micropor. Mesopor. Mater. 157, 101-111 (2012
31. Chmelik, C. et al. Adsorption and diffusion of alkanes in CuBTC crystals investigated using infra-red microscopy and molecular simulations. Micropor. Mesopor. Mater. 117, 22-32 (2009
32. Dosseh, G., Xia, Y. D. & Alba-Simionesco, C. Cyclohexane and benzene confined in MCM-41 and SBA-15: confinement effects on freezing and melting. J. Phys. Chem. B 107, 6445-6453 (2003
33. Shekhah, O., Wang, H., Zacher, D., Fischer, R. A. & Wöll, C. Growth mechanism of metal-organic frameworks: insights into the nucleation by employing a step-by-step route. Angew. Chem. Int. Ed. 48, 5038-5041 (2009
34. Sauerbrey, G. Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung. Zeitschrift Fur Physik 155, 206-222 (1959
35. Heinke, L. & Kärger, J. Correlating surface permeability with intracrystalline diffusivity in nanoporous solids. Phys. Rev. Lett. 106, 074501 (2011
36. Hibbe, F. et al. The nature of surface barriers on nanoporous solids explored by microimaging of transient guest distributions. J. Am. Chem. Soc. 133, 2804-2807 (2011
37. Zhuang, J.-L., Ceglarek, D., Pethuraj, S. & Terfort, A. Rapid room-temperature synthesis of metal-organic framework HKUST-1 crystals in bulk and as oriented and patterned thin films. Adv. Funct. Mater. 21, 1442-1447 (2011
38. Van Assche, T. R. C. et al. High adsorption capacities and two-step adsorption of polar adsorbates on copper-benzene-1,3,5-tricarboxylate metal-organic framework. J. Phys. Chem. C 117, 18100-18111 (2013).