Study of Co-W crystalline alloys as hydrogen electrodes in alkaline water electrolysis

International Journal of Hydrogen Energy

Volumn 39, Issue 24, 2014, Pages 12448-12456

  Rosalbino, F ^a   Maccio D ^b   Saccone, A ^b   Scavino, G ^a  

^a POLITECNICO DI TORINO   (Italy)

^b UNIVERSITY OF GENOA   (Italy)

Author keywords

Alkaline solution; Co W alloys; Electrocatalytic activity; Electrochemical impedance spectroscopy (EIS); Hydrogen evolution reaction (HER)

Indexed keywords

BINARY ALLOYS; ELECTROCATALYSTS; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; HYDROGEN; NICKEL; POLYCRYSTALLINE MATERIALS;

ALKALINE SOLUTIONS; ALKALINE WATER ELECTROLYSIS; ELECTROCATALYTIC ACTIVITY; ELECTROCATALYTIC EFFICIENCIES; ELECTROCATALYTIC MATERIALS; ELECTRONIC STRUCTURE CALCULATIONS; EXCHANGE CURRENT DENSITIES; HYDROGEN EVOLUTION REACTIONS;

TUNGSTEN;

EID: 84905277676     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2014.06.082     Document Type: Article

References (51)

1. S. Hodoshima, H. Arai, S. Takaiwa, and Y. Saito Catalytic decalin dhydrogenation/naphtalene hydrogenation pair as a hydrogen source for fuel-cell vehicle Int J Hydrogen Energy 28 2003 1255
2. M. Nocef, and A.M. Affoune Comparison between direct small molecular weight alcohols fuel cells and hydrogen fuel cells parameters at low and high temperature Int J Hydrogen Energy 26 2001 4208
3. 4 solution on the electrode characteristics and inner pressure of nickel-metal-hydride secondary batteries Int J Hydrogen Energy 34 2009 9570
4. 5 metal hydride electrode Int J Hydrogen Energy 28 2003 961
5. K. Zeng, and D. Zhang Recent progress in alkaline water electrolysis for hydrogen production and applications Prog Energy Combust Sci 36 2010 307
6. K. Zeng, and D. Zhang Evaluating the effect of surface modifications on Ni based electrodes for alkaline water electrolysis Fuel 116 2014 692
7. K. Zeng, and D. Zhang Evaluating the behaviour of electrolytic gas bubbles and their effect on the cell voltage in alkaline water electrolysis Ind Eng Chem Res 51 2012 13825
8. x alloy: the influence of sorbed hydrogen Int J Hydrogen Energy 26 2001 2101
9. N.V. Krstajic, D. Jovic, L. Gajic-Krstajic, B.M. Jovis, A.L. Antonozzi, and G.N. Martelli Electrodeposition of Ni-Mo alloy coatings and their characterization as cathodes for hydrogen evolution in sodium hydroxide solution Int J Hydrogen Energy 33 2008 3676
10. M. Rojas, C.L. Fan, H.J. Miao, and D.L. Piron Characterization of hydrogen evolution on cobalt electrodeposits in water electrolysis J Appl Electrochem 22 1992 1135
11. C.L. Fan, D.L. Piron, and P. Paradis Polarization of cobalt-molybdenum and nickel-molybdenum hydrogen electrodes for alkaline fuel cells Int J Hydrogen Energy 19 1994 529
12. B. Bozzini, G. Zangari, and P.L. Cavallotti Electrolytic hydrogen evolution on Co-alloy thin films prepared by electrochemical and autocatalytic deposition techniques Electrochim Acta 39 1994 1787
13. 67 metallic glass for hydrogen evolution J Mol Catal A Chem 166 2001 293
14. A. Parsons The rate of electrolytic hydrogen evolution and the heat of adsorption of hydrogen Trans Faraday Soc 54 1958 1053
15. M.H. Miles, and M.A. Thomson Electrocatalysis of hydrogen evolution in the light of the Brewer-Engel theory for bonding in metals and intermetallic phases J Electrochem Soc 123 1976 1459
16. M.M. Jakŝic Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory Int J Hydrogen Energy 12 1987 727
17. C. Fan, D.L. Piron, A. Sleb, and P. Paradis Study of electrodeposited Ni-Mo, Ni-W, Co-Mo, and Co-W as hydrogen electrodes in alkaline water electrolysis J Electrochem Soc 141 1994 382
18. M.P.M. Kaninski, S.M. Miulovic, G.S. Tasic, A.D. Maksic, and V.M. Nikolic A study on the Co-W activated Ni electrodes for the hydrogen production from alkaline water electrolysis - energy saving Int J Hydrogen Energy 36 2011 5227
19. N. Krstajic, M. Popovic, B. Grgur, M. Vojnovic, and D. Sepa On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution. Part I. The mechanism J Electroanal Chem 512 2001 16
20. N. Krstajic, M. Popovic, B. Grgur, M. Vojnovic, and D. Sepa On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution. Part II. Effect of temperature J Electroanal Chem 512 2001 27
21. J.M. Jaksic, M.V. Voinovic, and N.V. Krstajic Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes Electrochim Acta 45 2000 4151
22. L. Chen, and A. Lasia Study of the kinetics of hydrogen evolution reaction on Ni-Zn powder electrodes J Electrochem Soc 139 1992 3214
23. D. Miousse, A. Lasia, and V. Borck Hydrogen evolution reaction on Ni-Al-Mo and Ni-Al electrodes prepared by low pressure plasma spraying J Appl Electrochem 25 1995 592
24. M. Metikoš-Hukovic, and A. Jukic Correlation of electronic structure and catalytic activity of Zr-Ni amorphous alloys for the hydrogen evolution reaction Electrochim Acta 45 2000 4159
25. G.J. Brug, A.L.G. Van den Eden, M. Sluyters-Rehabach, and J.H. Sluyters Analysis of impedance and admittance data for solids and liquids J Electroanal Chem 176 1984 275
26. T. Pajkossy Fractal dimension and fractional power frequency-dependent impedance of blocking electrodes J Electroanal Chem 364 1994 111
27. Z. Kerner, and T. Pajkossy On the origin of capacitance dispersion of rough electrodes Electrochim Acta 46 2000 207
28. J.R. Macdonald, J. Schoonman, and A.P. Lehner A microcomputer based system for frequency dependent impedance/admittance measurements J Electroanal Chem 131 1982 77
29. M. Metikoš-Hukovic, Z. Grubač, N. Radić, P. Dubček, and I. Djerdj The influence of local structure of nanocrystalline Ni films on the catalytic activity Electrochem Commun 9 2007 299
30. L. Chen, and A. Lasia Hydrogen evolution reaction on nickel-molybdenum powder electrodes J Electrochem Soc 139 1992 3458
31. F. Rosalbino, D. Macciò, E. Angelini, A. Saccone, and S. Delfino Characterization of Fe-Zn-R (R = rare earth metal) crystalline alloys as electrocatalysts for hydrogen evolution Int J Hydrogen Energy 33 2008 2660
32. F. Rosalbino, S. Delsante, G. Borzone, and E. Angelini Electrocatalytic behaviour of Co-Ni-R (R = rare earth metal) crystalline alloys as electrode materials for hydrogen evolution reaction in alkaline medium Int J Hydrogen Energy 33 2008 6696
33. W. Hu Electrocatalytic properties of new electrocatalysts for hydrogen evolution reaction in alkaline water electrolysis Int J Hydrogen Energy 25 2000 111
34. H. Alemu, and K. Jüttner Characterization of the electrocatalytic properties of amorphous metals for oxygen and hydrogen evolution by impedance measurements Electrochim Acta 33 1988 1101
35. B. Łosiewicz, A. Budniok, E. Rówiński, E. Łagiewka, and A. Lasia The structure, morphology, and electrochemical impedance study of the hydrogen evolution reaction on the modified nickel electrodes Int J Hydrogen Energy 29 2004 145
36. S. Trasatti, and O.A. Petrii Real surface area measurements in electrochemistry Pure Appl Chem 63 1991 711
37. M.M. Jakšić Hypo-hyper-d-electronic interactive nature of interionic synergism in catalysis and electrocatalysis for hydrogen reactions Int J Hydrogen Energy 26 2001 559
38. M.M. Jakšić, C.M. Lačnievac, B.N. Grugur, and N.V. Krstajić Volcano plots along intermetallic hypo-hyper-d-electronic phase diagrams and electrocatalysis for hydrogen electrode reactions J New Mater Electrochem Syst 3 2000 169
39. N.V. Krstajić, B.N. Grugur, N.S. Mladenović, M.V. Vojnović, and M.M. Jakšić The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance Electrochim Acta 42 1997 323
40. H. Ezaki, M. Morinaga, and S. Watanabe Hydrogen overpotential for transition metals and alloys, and its interpretation using an electronic model Electrochim Acta 38 1993 557
41. H. Ezaki, M. Morinaga, S. Watanabe, and J. Saito Hydrogen overpotential for intermetallic compounds, TiAl, FeAl and NiAl, containing 3d transition metals Electrochim Acta 39 1994 1769
42. H. Shibutani, T. Higashijima, H. Ezaki, M. Morinaga, and K. Kikuchi An electronic approach to the hydrogen overpotential for Zr alloys Electrochim Acta 43 1998 3235
43. O.K. Andersen, O. Jelsen, and M. Sob M. Yussouf, Electronic band structure and its application 1990 Springer Verlag Berlin 1 57
44. T. Nambu, H. Ezaki, M. Takagi, H. Yukawa, and M. Morinaga Correlation between electronic structure and phase stability of metal hydrides J Alloy Compd 330 2002 318
45. M. Hanson, and H.J. Bauer Magnetic properties of nickel hydride and cobalt hydride - a comparison of magnetic susceptibility with band structure calculations J Alloy Compd 179 1992 339
46. B. Szpunar, M. Aus, C. Cheung, U. Erb, G. Palumbo, and J.A. Szpunar Magnetism in nanostructured Ni-P and Co-W alloys J Magn Mater 187 1998 325
47. M.V. Ananth, and N.V. Partasardhy Magnetization studies on electrodeposited Ni-Mo-Fe and Co-Mo-Fe alloys Mater Sci Eng B 5 1990 451
48. A. Stephen, T. Nagarajan, and M.V. Ananth Magnetization behaviour of electrodeposited Ni-Mn and Co-Mn alloys Mater Sci Eng B 55 1998 184
49. A. Burgstaller, W. Socher, J. Voitländer, I. Bakonyi, E. Tóth-Kádár, and A. Lovas et al. Magnetic studies of amorphous Ni-P and Co-P alloys J Magn Mater 109 1992 117
50. S.S.M. Tavares, S. Miraglia, A. Lafuente, and D. Fruchart Thermomagnetic analysis of hydrogenated nickel and cobalt J Magn Mater 242-245 2002 898
51. J.G. Highfield, E. Claude, and K. Oguro Electrocatalytic synergism in Ni/Mo cathodes for hydrogen evolution in acid medium: a new model Electrochim Acta 44 1999 2805