Photocatalytic degradation of 17α-ethinylestradiol (EE2) in the presence of TiO2-doped zeolite

Journal of Hazardous Materials

Volumn 279, Issue , 2014, Pages 17-25

  Pan, Zhong ^a   Stemmler, Elizabeth A ^b   Cho, Hong Je ^c   Fan, Wei ^c   LeBlanc, Lawrence A ^d   Patterson, Howard H ^e   Amirbahman, Aria ^a  

^a The University of Maine   (United States)

^b BOWDOIN COLLEGE   (United States)

^c University of Massachusetts   (United States)

^d UNIVERSITY OF MAINE   (United States)

^e Department of Chemistry University of Maine ^*  (United States)

Author keywords

17 Ethinylestradiol; Hydroxyl radical; Photodegradation; UV

Indexed keywords

CATALYSTS; DEGRADATION; LINEAR REGRESSION; PHOTODEGRADATION; SEWAGE PUMPING PLANTS; SURFACE ANALYSIS; WASTEWATER TREATMENT; WATER TREATMENT PLANTS;

ETHINYLESTRADIOL; HYDROXYL RADICALS; MULTIPLE LINEAR REGRESSION ANALYSIS; PHARMACEUTICAL AND PERSONAL CARE PRODUCTS; PHOTO CATALYTIC DEGRADATION; PSEUDO-FIRST ORDER KINETICS; TIO; UV;

TITANIUM DIOXIDE;

ETHINYLESTRADIOL; TITANIUM DIOXIDE; ZEOLITE; HYDROXYL RADICAL; TITANIUM;

DRUG; HYDROXYL RADICAL; PHOTOCHEMISTRY; PHOTODEGRADATION; ULTRAVIOLET A RADIATION; WASTE TREATMENT; WASTEWATER; ZEOLITE;

AQUEOUS SOLUTION; ARTICLE; CATALYST; DEGRADATION KINETICS; IONIZATION; ISOMER; LIGHT ABSORPTION; MOLECULAR SIZE; OXIDATION; PHOTOCATALYSIS; PHOTODEGRADATION; PHOTOLYSIS; QUANTUM YIELD; WASTE WATER MANAGEMENT; X RAY DIFFRACTION; ALGORITHM; CATALYSIS; CHEMISTRY; PHOTOCHEMISTRY; SCANNING ELECTRON MICROSCOPY; SEWAGE; SPECTROFLUOROMETRY; ULTRAVIOLET RADIATION; WASTE DISPOSAL FACILITY;

ALGORITHMS; CATALYSIS; ETHINYL ESTRADIOL; HYDROXYL RADICAL; MICROSCOPY, ELECTRON, SCANNING; PHOTOCHEMISTRY; SPECTROMETRY, FLUORESCENCE; TITANIUM; ULTRAVIOLET RAYS; WASTE DISPOSAL FACILITIES; WASTE DISPOSAL, FLUID; X-RAY DIFFRACTION; ZEOLITES;

EID: 84904312776     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2014.06.040     Document Type: Article

References (52)

1. Lima D.L., Calisto V., Esteves V.I. Adsorption behavior of 17α-ethynylestradiol onto soils followed by fluorescence spectral deconvolution. Chemosphere 2011, 84:1072-1078.
2. Nasuhoglu D., Berk D., Yargeau V. Photocatalytic removal of 17α-ethinylestradiol (EE2) and levonorgestrel (LNG) from contraceptive pill manufacturing plant wastewater under UVC radiation. Chem. Eng. J. 2012, 185:52-60.
3. Matamoros V., Duhec A., Albaigés J., Bayona J.M. Photodegradation of carbamazepine, ibuprofen, ketoprofen and 17α-ethinylestradiol in fresh and seawater. Water Air Soil Pollut. 2009, 196:161-168.
4. Kumar A., Xagoraraki I. Pharmaceuticals, personal care products and endocrine-disrupting chemicals in US surface and finished drinking waters: a proposed ranking system. Sci. Total Environ. 2010, 408:5972-5989.
5. Hwang S., Lee D.I., Lee C.H., Ahn I.S. Oxidation of 17α-ethinylestradiol with Mn(III) and product identification. J. Hazard. Mater. 2008, 155:334-341.
6. 2 technology. J. Hazard. Mater. 2010, 181:1127-1133.
7. Desbrow C.E.J.R., Routledge E.J., Brighty G.C., Sumpter J.P., Waldock M. Identification of estrogenic chemicals in STW effluent. 1. Chemical fractionation and in vitro biological screening. Environ. Sci. Technol. 1998, 32:1549-1558.
8. 2) degradation of 17α-ethynylestradiol in environmental matrices: experimental studies and artificial neural network modeling. J. Photochem. Photobiol. A 2012, 240:33-41.
9. 2 treatments. Chemosphere 2009, 77:518-525.
10. 2 under UVC illumination. Cent. Eur. J. Chem. 2012, 10:1137-1148.
11. 2 and UV illumination in a horizontal circulating bed photocatalytic reactor (HCBPR). J. Hazard. Mater. 2009, 169:926-932.
12. 2 catalysts supported by Y zeolite: an investigation of the effects of operational parameters. Dyes Pigments 2008, 76:817-824.
13. 2 membranes supported on glass. J. Catal. 1991, 127:166-167.
14. 2 immobilized on fused-silica glass fibers: photomineralization of 4-chlorophenol. Environ. Sci. Technol. 1994, 28:670-674.
15. Soga I., Dhinojwala A., Granick S. Optorheological studies of sheared confined fluids with mesoscopic thickness. Langmuir 1998, 14:1156-1161.
16. Yoneyama H., Haga S., Yamanaka S. Photocatalytic activities of microcrystalline titania incorporated in sheet silicates of clay. J. Phys. Chem. 1989, 93:4833-4837.
17. Liu X., Lu K.K., Thomas J.K. Preparation, characterization and photoreactivity of titanium(IV) oxide encapsulated in zeolites. J. Chem. Soc. Faraday Trans. 1993, 89:1861-1865.
18. 2 photocatalyst for environmental applications. J. Photochem. Photobiol. C 2013, 15:1-20.
19. 2-supported Y-zeolites. J. Photochem. Photobiol. C 2003, 4:5-18.
20. 2/HZSM-11 zeolite for photodegradation of dichlorvos in aqueous solution. J. Hazard. Mater. 2013, 258-259:19-26.
21. 2. Chemosphere 2006, 63:1014-1021.
22. 2 photocatalysts. Appl. Surf. Sci. 2011, 257:6873-6877.
23. Xu Y., Langford C.H. Photoactivity of titanium dioxide supported on MCM41, zeolite X, and zeolite Y. J. Phys. Chem. B 1997, 101:3115-3121.
24. 2-zeolite as photocatalyst for photodegradation of some organic pollutants. Iran. J. Catal. 2011, 1:45-50.
25. 3~2.0). Zeolites 1987, 7:451-457.
26. Hatchard P.G., Parker C.A. A new sensitive chemical actinometer. II. Potassium ferrioxalate as a standard chemical actimeter. Proc. R. Soc. Lond. A 1956, 35:518-536.
27. Stookey L.L. Ferrozine-a new spectrophotometric reagent for iron. Anal. Chem. 1970, 42:779-781.
28. 2-photocatalyzed As(III) oxidation in aqueous suspensions: reaction kinetics and effects of adsorption. Environ. Sci. Technol. 2005, 39:1880-1886.
29. 2. Appl. Surf. Sci. 2011, 257:7083-7089.
30. Becke A.D. Density-functional thermochemistry. III. The role of exact exchange. J. Chem. Phys. 1993, 98:5648-5653.
31. Lee C., Yang W.R., Parr R.G. Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. Phys. Rev. 1988, B37:785-789.
32. Mulliken R.S. Electronic population analysis on LCAO-MO molecular wave functions. I. J. Chem. Phys. 1955, 23:1833-1841.
33. Mulliken R.S. Criteria for the construction of good self-consistent-field molecular orbital wave functions, and the significance of LCAO-MO population analysis,. J. Chem. Phys. 1962, 3(6):3428-3440.
34. Takahashi A., Yang F.H., Yang R.T. New sorbents for desulfurization by π-complexation: thiophene/benzene adsorption. Ind. Eng. Chem. Res. 2002, 41:2487-2496.
35. 2 under UV and sunlight irradiation: prediction of the reaction paths via conceptual DFT. Chem. Eng. J. 2012, 184:113-124.
36. 2]. J. Chem. Sci. 2011, 1(23):727-731.
37. 2CO. J. Mol. Struct. Theochem. 1988, 163:305-313.
38. Treacy M.M., Higgins J.B. Collection of Simulated XRD Powder Patterns for Zeolites 2001, Accessed Online via Elsevier.
39. Ogura M., Kawazu Y., Takahashi H., Okubo T. Aluminosilicate species in the hydrogel phase formed during the aging process for the crystallization of FAU zeolite. Chem. Mater. 2003, 15:2661-2667.
40. 2 for ultrasound-assisted degradation of amaranth dye in water. J. Hazard. Mater. 2012, 233-234:184-193.
41. Chowdhury R.R., Charpentier P.A., Ray M.B. Photodegradation of 17β-estradiol in aquatic solution under solar irradiation: kinetics and influencing water parameters. J. Photochem. Photobiol. A 2011, 219:67-75.
42. Leifer A. The Kinetics of Environmental Aquatic Photochemistry: Theory and Practice 1988, ACS Professional Reference Book, USA.
43. 2: influence of operational parameters and kinetic modeling. Dyes Pigments 2006, 70:54-59.
44. 2 treatment of Rhodamine B in aqueous solution: influence of operational parameters and kinetic modeling. Desalination 2008, 230:16-26.
45. 2 processes. J. Hazard. Mater. 2006, 136:816-821.
46. Vos A.M., Nulens K.H., De Proft F., Schoonheydt R.A., Geerlings P. Reactivity descriptors and rate constants for electrophilic aromatic substitution: acid zeolite catalyzed methylation of benzene and toluene. J. Phys. Chem. B 2002, 106:2026-2034.
47. Pozo O.J., Van Eenoo P., Deventer K., Grimalt S., Sancho J.V., Hernández F., Delbeke F.T. Collision-induced dissociation of 3-keto anabolic steroids and related compounds after electrospray ionization. Considerations for structural elucidation. Rapid Commun. Mass Spectrom. 2008, 22:4009-4024.
48. Thevis M., Bommerich U., Opfermann G., Schänzer W. Characterization of chemically modified steroids for doping control purposes by electrospray ionization tandem mass spectrometry. J. Mass Spectrom. 2005, 40:494-502.
49. Stumm W., Morgan J.J. Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters 2012, John Wiley & Sons, New York.
50. 2-zeolite sheets. Appl. Catal. B: Environ. 2003, 46:453-462.
51. 2 supported on zeolites. Catal. Today 2007, 120:158-162.
52. Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W. Environmental applications of semiconductor photocatalysis. Chem. Rev. 1995, 95:69-96.