Photoinduced giant dielectric constant in lead halide perovskite solar cells

Journal of Physical Chemistry Letters

Volumn 5, Issue 13, 2014, Pages 2390-2394

  Juarez Perez, Emilio J ^a   Sanchez, Rafael S ^a   Badia, Laura ^a   Garcia Belmonte, Germá ^a   Kang, Yong Soo ^b   Mora Sero, Ivan ^a   Bisquert, Juan ^a,c  

^a UNIVERSITAT JAUME I   (Spain)

^b Hanyang University   (South Korea)

^c KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

Author keywords

giant dielectric constant; permittivity; perovskite; solar cell

Indexed keywords

PERMITTIVITY; PEROVSKITE; SOLAR CELLS;

DIELECTRIC RESPONSE; GIANT DIELECTRIC CONSTANTS; HALIDE PEROVSKITES; ILLUMINATION INTENSITY; INTRINSIC PROPERTY; PHOTOVOLTAIC MATERIALS; PHOTOVOLTAIC OPERATION; STRUCTURAL FLUCTUATIONS;

DIELECTRIC MATERIALS;

EID: 84903842225     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz5011169     Document Type: Article

References (38)

1. Park, N.-G. Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell J. Phys. Chem. Lett. 2013, 4, 2423-2429
2. Snaith, H. J. Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells J. Phys. Chem. Lett. 2013, 4, 3623-3630
3. Bokov, A. A. Recent Progress in Relaxor Ferroelectrics with Perovskite Structure J. Mater. Sci. 2006, 41, 31-52 (Pubitemid 43260928)
4. Zhong, W.; Vanderbilt, D. Competing Structural Instabilities in Cubic Perovskites Phys. Rev. Lett. 1995, 74, 2587-2590
5. Ghita, M.; Fornari, M.; Singh, D. J.; Halilov, S. V. Interplay Between A-site and B-site Driven Instabilities in Perovskites Phys. Rev. B: Condens. Matter Mater. Phys. 2005, 72, 054114
6. Ohtomo, A.; Muller, D. A.; Grazul, J. L.; Hwang, H. Y. Artificial Charge-Modulationin Atomic-Scale Perovskite Titanate Superlattices Nature 2002, 419, 378-380
7. Mitzi, D. B. Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials. In Progress in Inorganic Chemistry; John Wiley & Sons, Inc.: Hoboken, NJ, 2007; pp 1-121.
8. Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells J. Am. Chem. Soc. 2009, 131, 6050-6051
9. Im, J.-H.; Lee, C.-R.; Lee, J.-W.; Park, S.-W.; Park, N.-G. 6.5% Efficient Perovskite Quantum-Dot-Sensitized Solar Cell Nanoscale 2011, 3, 4088-4093
10. Burschka, J.; Pellet, N.; Moon, S.-J.; Humphry-Baker, R.; Gao, P.; Nazeeruddin, M. K.; Gratzel, M. Sequential Deposition as a Route to High-Performance Perovskite-Sensitized Solar Cells Nature 2013, 499, 316-319
11. Liu, M.; Johnston, M. B.; Snaith, H. J. Efficient Planar Heterojunction Perovskite Solar Cells by Vapour Deposition Nature 2013, 501, 395-398
12. 2 nanocomposites in thin film perovskite solar cells Nano Lett. 2014, 14, 724-730
13. Kim, H.-S.; Mora-Sero, I.; Gonzalez-Pedro, V.; Fabregat-Santiago, F.; Juarez-Perez, E. J.; Park, N.-G.; Bisquert, J. Mechanism of Carrier Accumulation in Perovskite Thin-Absorber Solar Cells Nat. Commun. 2013, 4, 2242
14. 3 Perovskite Solar Cells Nano Lett. 2014, 14, 888-893
15. Sánchez, R. S.; Gonzalez-Pedro, V.; Lee, J.-W.; Park, N.-G.; Kang, Y. S.; Mora-Sero, I.; Bisquert, J. Slow Dynamic Processes in Lead Halide Perovskite Solar Cells. Characteristic Times and Hysteresis J. Phys. Chem. Lett. 2014, 5, 2357-2363
16. Woodward, P. Octahedral Tilting in Perovskites. II. Structure Stabilizing Forces Acta Crystallogr., Sect. B: Struct. Sci. 1997, 53, 44-66 (Pubitemid 127439778)
17. Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Inorg. Chem. 2013, 52, 9019-9038
18. Kim, H.-S.; Im, S. H.; Park, N.-G. Organolead Halide Perovskite: New Horizons in Solar Cell Research J. Phys. Chem. C 2014, 118, 5615-5625
19. Frost, J. M.; Butler, K. T.; Brivio, F.; Hendon, C. H.; van Schilfgaarde, M.; Walsh, A. Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells Nano Lett. 2014, 14, 2584-2590
20. 6+ x (x = 0) Phys. Rev. B: Condens. Matter Mater. Phys. 1990, 41, 8974-8980
21. Ramirez, A. P.; Subramanian, M. A.; Gardel, M.; Blumberg, G.; Li, D.; Vogt, T.; Shapiro, S. M. Giant Dielectric Constant Response in a Copper-Titanate Solid State Commun. 2000, 115, 217-220
22. Homes, C. C.; Vogt, T.; Shapiro, S. M.; Wakimoto, S.; Ramirez, A. P. Optical Response of High-Dielectric-Constant Perovskite-Related Oxide Science 2001, 293, 673-676 (Pubitemid 32728665)
23. Horiuchi, S.; Kumai, R.; Tokura, Y. Room-Temperature Ferroelectricity and Gigantic Dielectric Susceptibility on a Supramolecular Architecture of Phenazine and Deuterated Chloranilic Acid J. Am. Chem. Soc. 2005, 127, 5010-5011 (Pubitemid 40523447)
24. Ligatchev, V. Polaronic Phase Transitions and Complex Permittivity of Solid Polar Insulators with Gigantic Dielectric Response Phys. Status Solidi B 2013, 251, 569-592
25. Lunkenheimer, P.; Bobnar, V.; Pronin, A. V.; Ritus, A. I.; Volkov, A. A.; Loidl, A. Origin of Apparent Colossal Dielectric Constants Phys.Rev. B 2002, 66, 052105
26. 12 Phys. Rev. B: Condens. Matter Mater. Phys. 2004, 70, 174306
27. Hasegawa, T.; Mouri, S.-I.; Yamada, Y.; Tanaka, K. Giant Photo-Induced Dielectricity in SrTiO3 J. Phys. Soc. Jpn. 2003, 72, 41-44
28. Kim, H.-S.; Lee, C.-R.; Im, J.-H.; Lee, K.-B.; Moehl, T.; Marchioro, A.; Moon, S.-J.; Humphry-Baker, R.; Yum, J.-H.; Moser Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Sci. Rep. 2012, 2, 591
29. Lee, M. M.; Teuscher, J.; Miyasaka, T.; Murakami, T. N.; Snaith, H. J. Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science 2012, 338, 643-647
30. Liu, D.; Kelly, T. L. Perovskite Solar Cells with a Planar Heterojunction Structure Prepared Using Room-Temperature Solution Processing Techniques Nat. Photonics 2014, 8, 133-138
31. Bisquert, J. Chemical Capacitance of Nanostructured Semiconductors: Its Origin and Significance for Heterogeneous Solar Cells Phys. Chem. Chem. Phys. 2003, 5, 5360-5364
32. Juarez-Perez, E. J.; Wuβler, M.; Fabregat-Santiago, F.; Lakus-Wollny, K.; Mankel, E.; Mayer, T.; Jaegermann, W.; Mora-Sero, I. The Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells J. Phys. Chem. Lett. 2014, 5, 680-685
33. 3 Perovskites for Solar Cell Applications Sci. Rep. 2014, 4, 4467
34. 3 (X = Cl and Br) Single Crystals J. Phys. Soc. Jpn. 1997, 66, 1508-1511
35. Wasylishen, R. E.; Knop, O.; Macdonald, J. B. Cation Rotation in Methylammonium Lead Halides Solid State Commun. 1985, 56, 581-582 (Pubitemid 15599224)
36. 3 J. Korean Phys. Soc. 2007, 51, 850-853
37. Even, J.; Pedesseau, L.; Jancu, J.-M.; Katan, C. Importance of Spin-Orbit Coupling in Hybrid Organic/Inorganic Perovskites for Photovoltaic Applications J. Phys. Chem. Lett. 2013, 4, 2999-3005
38. Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites Adv. Mater. 2014, 26, 1584-1589