Charge transfer kinetics at the solid-solid interface in porous electrodes

Nature Communications

Volumn 5, Issue , 2014, Pages

  Bai, Peng ^a   Bazant, Martin Z ^a,b  

^a Massachusetts Institute of Technology Cambridge   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; IRON;

CARBON; ELECTRIC FIELD; ELECTRODE; INTERFACE; ION EXCHANGE; IRON; KINETICS; LIQUID; LITHIUM; OXYGEN; PHOSPHORUS; POROUS MEDIUM; REDOX CONDITIONS; SOLID; TEMPERATURE;

ARTICLE; DESORPTION; DIELECTRIC CONSTANT; DIFFUSION; ELECTRIC POTENTIAL; ELECTRICITY; ELECTROCHEMISTRY; ELECTRODE; ELECTRON TRANSPORT; ION TRANSPORT; KINETICS; OXIDATION REDUCTION REACTION; PARTICLE SIZE; PHASE SEPARATION; POLARIZATION; SOLVATION; STATIC ELECTRICITY; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 84903717351     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms4585     Document Type: Article

References (49)

1. Bockris, J. O. M., Reddy, A. K. N. & Gamboa-Aldeco, M. E. Modern Electrochemistry 2A: Fundamentals of Electrodics 2nd edn (Kluwer Academic/Plenum Publishers, 2000).
2. Bazant, M. Z. Theory of chemical kinetics and charge transfer based on nonequilibrium thermodynamics. Acc. Chem. Res. 46, 1144-1160 (2013).
3. Marcus, R. A. Electron-transfer reactions in chemistry. Theory and experiment. Rev. Mod. Phys. 65, 599-610 (1993).
4. Chidsey, C. E. D. Free-energy and temperature-dependence of electron-transfer at the metal-electrolyte interface. Science 251, 919-922 (1991).
5. Padhi, A. K., Nanjundaswamy, K. S. & Goodenough, J. B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J. Electrochem. Soc. 144, 1188-1194 (1997).
6. Ravet, N. et al. Electroactivity of natural and synthetic triphylite. J. Power Sources 97-98, 503-507 (2001).
7. 4 cathode materials for high power lithium ion batteries. J. Mater. Chem. 21, 3353-3358 (2011).
8. 4. Chem. Mater. 24, 3212-3218 (2012).
9. 4 and their association with lithium ions and vacancies. Phys. Rev. B 73, 104301 (2006).
10. Li, H. Q. & Zhou, H. S. Enhancing the performances of Li-ion batteries by carbon-coating: present and future. Chem. Commun. 48, 1201-1217 (2012).
11. 4 cathode materials for lithium-ion batteries. Energy Environ. Sci. 5, 5163-5185 (2012).
12. Flandrois, S. & Simon, B. Carbon materials for lithium-ion rechargeable batteries. Carbon 37, 165-180 (1999).
13. Srinivasan, V. & Newman, J. Discharge model for the lithium iron-phosphate electrode. J. Electrochem. Soc. 151, A1517-A1529 (2004).
14. 4 nanoparticles during battery discharge. Nano Lett. 11, 4890-4896 (2011).
15. Bard, A. J. & Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications 2nd edn (John Wiley, 2001).
16. 4 electrodes using a multiscale mathematical model. J. Electrochem. Soc. 157, A830-A840 (2010).
17. Safari, M. & Delacourt, C. Mathematical modeling of lithium iron phosphate electrode: galvanostatic charge/discharge and path dependence. J. Electrochem. Soc. 158, A63-A73 (2011).
18. 4 accounting for the solid solution range. J. Electrochem. Soc. 155, A866-A874 (2008).
19. Wang, C. S., Kasavajjula, U. S. & Arce, P. E. A discharge model for phase transformation electrodes: formulation, experimental validation, and analysis. J. Phys. Chem. C 111, 16656-16663 (2007).
20. Marcus, R. A. On Theory of electron-transfer reactions. VI. Unified treatment for homogeneous and electrode reactions. J. Chem. Phys. 43, 679-701 (1965).
21. Marcus, R. A. On the theory of oxidation-reduction reactions involving electron transfer.1. J. Chem. Phys. 24, 966-978 (1956).
22. 4 by using single particle technique. J. Power Sources 217, 444-448 (2012).
23. Kang, B. & Ceder, G. Battery materials for ultrafast charging and discharging. Nature 458, 190-193 (2009).
24. 2 kinetic overpotentials: Tafel plots from experiment and first-principles theory. J. Phys. Chem. Lett. 4, 556-560 (2013).
25. Ferguson, T. R. & Bazant, M. Z. Nonequilibrium thermodynamics of porous electrodes. J. Electrochem. Soc. 159, A1967-A1985 (2012).
26. Dreyer, W. et al. The thermodynamic origin of hysteresis in insertion batteries. Nat. Mater. 9, 448-453 (2010).
27. Henstridge, M. C., Laborda, E., Rees, N. V. & Compton, R. G. Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: a review. Electrochim. Acta 84, 12-20 (2012).
28. 4 porous electrodes. Electrochim. Acta 89, 644-651 (2013).
29. 4 nanoparticles. ACS Nano 6, 2215-2225 (2012).
30. 4 electrodes tracked by in situ electrochemical quartz crystal admittance. J. Phys. Chem. C 117, 15505-15514 (2013).
31. Laborda, E., Henstridge, M. C., Batchelor-McAuley, C. & Compton, R. G. Asymmetric Marcus-Hush theory for voltammetry. Chem. Soc. Rev. 42, 4894-4905 (2013).
32. Oldham, K. B. & Myland, J. C. On the evaluation and analysis of the Marcus-Hush-Chidsey integral. J. Electroanal. Chem. 655, 65-72 (2011).
33. Royea, W. J., Hamann, T. W., Brunschwig, B. S. & Lewis, N. S. A comparison between interfacial electron-transfer rate constants at metallic and graphite electrodes. J. Phys. Chem. B 110, 19433-19442 (2006).
34. 4 nanoparticles via a domino-cascade model. Nat. Mater. 7, 665-671 (2008).
35. 4 olivine-type battery material. Chem. Mater. 17, 5085-5092 (2005).
36. 4: surface energy, structure, Wulff shape, and surface redox potential. Phys. Rev. B 76, 165435 (2007).
37. Kuznetsov, A. M. & Ulstrup, J. Electron Transfer in Chemistry and Biology: An Introduction to the Theory (Wiley, 1999).
38. Valoen, L. O. & Reimers, J. N. Transport properties of LiPF6-based Li-ion battery electrolytes. J. Electrochem. Soc. 152, A882-A891 (2005).
39. 4. Phys. Rev. B 69, 104303 (2004).
40. 4 (M=Mn, Fe, Co, Ni) olivine materials. Electrochem. Solid-State Lett. 7, A30-A32 (2004).
41. Malik, R., Burch, D., Bazant, M. & Ceder, G. Particle size dependence of the ionic diffusivity. Nano Lett. 10, 4123-4127 (2010).
42. Dathar, G. K. P., Sheppard, D., Stevenson, K. J. & Henkelman, G. Calculations of Li-ion diffusion in olivine phosphates. Chem. Mater. 23, 4032-4037 (2011).
43. Zhu, Y. J. & Wang, C. S. Galvanostatic intermittent titration technique for phase-transformation electrodes. J. Phys. Chem. C 114, 2830-2841 (2010).
44. 4 thin films by CV, GITT, and EIS. Electrochim. Acta 56, 4869-4875 (2011).
45. 4. Solid State Ionics 148, 45-51 (2002).
46. Cogswell, D. A. & Bazant, M. Z. Theory of coherent nucleation in phaseseparating nanoparticles. Nano Lett. 13, 3036-3041 (2013).
47. Newman, J. S. & Thomas-Alyea, K. E. Electrochemical Systems 3rd edn (J Wiley, 2004).
48. Chen, S. L. & Liu, Y. W. Electrochemistry at nanometer-sized electrodes. Phys. Chem. Chem. Phys. 16, 635-652 (2014).
49. 4 cathodes. Electrochim. Acta 111, 474-490 (2013).