Collective phase transition dynamics in microarray composite Li xFePO4 electrodes tracked by in situ electrochemical quartz crystal admittance

Journal of Physical Chemistry C

Volumn 117, Issue 30, 2013, Pages 15505-15514

  Levi, Mikhael D ^a   Sigalov, Sergey ^a   Salitra, Gregory ^a   Nayak, Prasant ^a   Aurbach, Doron ^a   Daikhin, Leonid ^b   Perre, Emilie ^c   Presser, Volker ^c,d  

^a BAR ILAN UNIVERSITY   (Israel)

^b TEL AVIV UNIVERSITY   (Israel)

^c INM LEIBNIZ INSTITUTE FOR NEW MATERIALS   (Germany)

^d SAARLAND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

COLLECTIVE BEHAVIOR; CURRENT TRANSIENTS; EFFECTIVE THICKNESS; GEOMETRIC CHANGES; INDUCED PHASE TRANSITION; NON-UNIFORM DEFORMATION; SIMULTANEOUS ANALYSIS; TRANSITION DYNAMICS;

DEFORMATION; GEOMETRY; LITHIUM; QUARTZ;

ELECTROCHEMICAL ELECTRODES;

EID: 84881258670     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp403653d     Document Type: Article

References (36)

1. 4 porous electrodes Electrochim. Acta 2013, 89, 644-651
2. Inzelt, G. Conducting Polymers-A New Era in Electrochemistry, 2 nd ed.; Springer-Verlag: Berlin, 2012; p 294.
3. McKinnon, W. R.; Haering, R. R. Modern Aspects in Electrochemistry; Bockris, J. O. M., Ed.; Plenum Press: New York, 1987; Vol. 15, p 235-304.
4. Advances in Lithium-Ion Batteries; van Schalkwijk, W. A.; Scrosati, B., Eds.; Kluwer Academic Publishers: New York, 2002.
5. Vorotyntsev, M. A.; Badiali, J. P. Short-Range Electron-Ion Interaction Effects in Charging the Electroactive Polymer Films Electrochim. Acta 1994, 39, 289-306
6. Vakarin, E. V.; Badiali, J. P. Role of structural fluctuations in the insertion into complex host matrices Electrochim. Acta 2005, 50, 1719-1724
7. Levi, M. D.; Aurbach, D.; Maier, J. Electrochemically Driven First-Order Phase Transitions Caused by Elastic Responses of Ion-Insertion Electrodes under External Kinetic Control J. Electroanal. Chem. 2008, 624, 251-261
8. 4 Spinel J. Electrochem. Soc. 2000, 147, 25-33
9. Levi, M. D.; Wang, C.; Aurbach, D. Two parallel diffusion paths model for interpretation of PITT and EIS responses from non-uniform intercalation electrodes J. Electroanal. Chem. 2004, 1-11
10. Meyers, J. P.; Doyle, M.; Darling, R. M.; Newman, J. J. Electrochem. Soc. 2000, 147, 2930
11. Levi, M. D.; Aurbach, D. Impedance of a Single Intercalation Particle and of Non-Homogeneous, Multilayered Porous Composite Electrodes for Li-ion Batteries J. Phys. Chem. B 2004, 108, 11693-11703
12. Levi, M. D.; Aurbach, D. Distinction between Energetic Inhomogeneity and Geometric Non-Uniformity of Ion J. Phys. Chem. B 2005, 109, 2763-2773
13. Dreyer, W.; Jamnik, J.; Guhlke, C.; Huth, R.; Moskon, J.; Gaberscek, M. The thermodynamic origin of hysteresis in insertion batteries Nat. Mater. 2010, 9, 448-453
14. Dreyer, D.; Guhlke, C.; Huth, R. The behavior of a many-particle electrode in a lithium-ion battery Phys. D 2011, 240, 1008-1019
15. 4 Electrode Revealed by Nanoscale State-of-Charge Mapping Nano Lett. 2013, 13, 866-872
16. 4 Precession Electron Diffraction Chem. Mater. 2011, 23, 4515-4524
17. 4 Nanoparticles ACS Nano 2012, 6, 2215-2225
18. Bazant, M. Z. Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics Acc. Chem. Res. 2013, 46, 1144-1160
19. Kolmogorov, A.N. On the statistical theory of metal crystallization (1937), in Selected works of A.N. Kolmogorov; Kluwer Academic: Dordrecht, 1991; Vol. II, p 188.
20. Avrami, M. Kinetics of phase change. I. General theory J. Chem. Phys. 1939, 7, 1103-1112
21. Avrami, M. Kinetics of phase change. II. Transformation-time relations for random distribution of nuclei J. Chem. Phys. 1940, 8, 212-224
22. 4 Phase Transition J. Chem. Mater. 2007, 19, 2108-2111
23. 4 phase transition J. Solid State Electrochem. 2008, 12, 1031-1033
24. 4 J. Phys. Chem. C 2012, 116, 7306-7311
25. Levi, M. D.; Sigalov, S.; Salitra, G.; Elazari, R.; Aurbach, D.; Daikhin, L.; Presser, V. In Situ Tracking of Ion Insertion in Iron Phosphate Olivine Electrodes via Electrochemical Quartz Crystal Admittance J. Phys. Chem. C 2013, 117, 1247-1256
26. Hillman, A. R. The EQCM: Electrogravimetry with a Light Touch J. Solid State Electrochem. 2011, 15, 1647-1660
27. Daikhin, L.; Urbakh, M. Effect of surface film structure on the quartz crystal microbalance response in liquids Langmuir 1996, 12, 6354-6360
28. Daikhin, L.; Levi, M. D.; Sigalov, S.; Salitra, G.; Aurbach, D. Quartz Crystal Impedance Response of Nonhomogenous Composite Electrodes in Contact with Liquids Anal. Chem. 2011, 83, 9614-9621
29. Sahimi, M. Flow and Transport in Porous Media and Fractured Rock; VCH: Weinheim, 1995.
30. 4 single crystals on delithiation J. Am. Chem. Soc. 2012, 134, 2988-2992
31. Chung, K. Y.; Kim, K.-B. Investigation of Structural Fatigue in Spinel Electrodes Using In Situ Laser Probe Beam Deflection Technique J. Electrochem. Soc. 2002, 149, A79-A85
32. Mukhopadhyay, A.; Tokranov, A.; Sena, K.; Xiao, X. C.; Sheldon, B. W. Thin film graphite electrodes with low stress generation during Li-intercalation Carbon 2011, 49, 2742-2749
33. 4 Thin Films Electrochem. Solid-State Lett. 2004, 7, A15-A18
34. Daikhin, L.; Gileadi, E.; Katz, G.; Tsionsky, V.; Urbakh, M.; Zagidulin, D. Influence of Roughness on the Admittance of the Quartz Crystal Microbalance Immersed in Liquids Anal. Chem. 2002, 74, 554-561
35. 4 Nanoparticles during Battery Discharge Nano Lett. 2011, 11, 4890-4896
36. 4 two-phase system by high-resolution electron energy loss spectroscopy Chem. Mater. 2006, 18, 5520-5529