Anion charge storage through oxygen intercalation in LaMnO 3 perovskite pseudocapacitor electrodes

Nature Materials

Volumn 13, Issue 7, 2014, Pages 726-732

  Mefford, J Tyler ^a   Hardin, William G ^b   Dai, Sheng ^c   Johnston, Keith P ^b,d   Stevenson, Keith J ^a,b  

^a The University of Texas at Austin   (United States)

^b UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^c OAK RIDGE NATIONAL LABORATORY   (United States)

^d The University of Texas at Austin   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC PROPERTIES; ELECTRODES; ELECTRONIC PROPERTIES; ENERGY STORAGE; OXYGEN; PEROVSKITE; POSITIVE IONS; STABILITY;

CATION INTERCALATION; ELECTRICAL POLARIZATION; ELECTROCHEMICAL ENERGY STORAGE; METAL-AIR BATTERY; OXYGEN INTERCALATION; PEROVSKITE OXIDES; PSEUDOCAPACITANCE; STRUCTURAL STABILITIES;

OXYGEN VACANCIES;

EID: 84903213283     PISSN: 14761122     EISSN: 14764660     Source Type: Journal    
DOI: 10.1038/nmat4000     Document Type: Article

References (37)

1. Conway, B. E. Electrochemical sup er capacitors (Kluwer-Academic, 1999).
2. Arico, A. S., Bruce, P., Scrosati, B., Tarascon, J. & Van Schalkwijk, W Nanostructured materials for advanced energy conversion and storage devices. NatureMater. 4, 366-377 (2005). (Pubitemid 40557887)
3. Zheng, J. P. & Jow, T. R. A new charge storage mechanism for electrochemical capacitors. J. Electrochem. Soc. 142, 6-8 (1995).
4. 2 nanoparticles in graphitic disordered mesoporous carbon at high scan rates. J. Mater. Chem. 22, 3160-3169(2012).
5. 2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. J. Am. Chem. Soc. 132, 7472-7477 (2010).
6. Herrero, E., Buller, L. J. & Abruña, H. D. Underpotential deposition at single crystal surfaces of Au, Pt, Ag and other materials. Chem. Rev. 101, 1897-1930(2001). (Pubitemid 35381670)
7. Guidelli, R. & Schmickler, W. in Modern Aspects of Electrochemistry Vol. 38, 303-371 (Springer, 2005).
8. + intercalation pseudocapacitance. Nature Mater. 12, 518-522 (2013).
9. Brezesinski, T., Wang, J., Tolbert, S. H. & Dunn, B. Ordered mesoporous CC-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors. Nature Mater. 9, 146-151 (2010).
10. Hahn, B. P., Long, J. W & Rolison, D. R. Something from nothing: Enhancing electrochemical charge storage with cation vacancies. Acc. Chem. Res. 46, 1181-1191(2013).
11. Ishihara, T. Perovskite Oxide for Solid Oxide Fuel Cells (Springer, 2009).
12. Wilde, P. M., Guther, T. J., Oesten, R. & Garche, J. Strontium ruthenate perovskite as the active material for supercapacitors. J. Electroanal. Chem. 461, 154-160(1999).
13. Suntivich, J., May, K. J., Gasteiger, H. A., Goodenough, J. B. & Shao-Horn, Y. A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles. Science 334, 1383-1385(2011).
14. Suntivich, J. et al. Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries. Nature Chem. 3, 546-550(2011).
15. Wohlfahrt-Mehrens, M. et al. New materials for supercapacitors. J. Power Sources 105, 182-188(2002). (Pubitemid 34232141)
16. 3. Sci. Rep. 2, 601-605(2012).
17. 2 (anatase) nanoparticles. J. Phys. Chem. C 111, 14925-14931 (2007). (Pubitemid 350013591)
18. Kalinin, S. V, Borisevich, A. & Fong, D. Beyond condensed matter physics on the nanoscale: The role of ionic and electrochemical phenomena in the physical functionalities of oxide materials. ACSNano 6, 10423-10437(2012).
19. Hardin, W. G. et al. Highly active, nonprecious metal perovskite electrocatalysts for bifunctional metal-air battery electrodes. J. Phys. Chem. Lett. 4, 1254-1259(2013).
20. 3-3. J. Phys. Chem. Solids 67, 579-582 (2006).
21. 3+a with 0.065<5 <0.154. J. Phys. Chem. Solids 64, 2313-2319 (2003).
22. Ruiz-González, L., Cortés-Gil, R., Alonso, J. M., González-Calbet, J. M. & Vallet-Regí, M. Revisiting the role of vacancies in manganese related perovskites. Open Inorg. Chem. J. 1, 37-46 (2007).
23. Boehm, H. P. Acidic and basic properties of hydroxylated metal oxide surfaces. Discuss. Faraday Soc. 52, 264-275 (1971).
24. Schmidt, T. J. et al. Characterization of high-surface-area electrocatalysts using a rotating disk electrode configuration. J. Electrochem. Soc. 145, 2354-2358 (1998). (Pubitemid 128602467)
25. Wiberg, G. K. H., Mayrhofer, K. J. J. & Arenz, M. Investigation of the oxygen reduction activity on silver-a rotating disc electrode study. Fuel Cells 10, 575-581 (2010).
26. Garsany, Y., Singer, I. L. & Swider-Lyons, K. E. Impact of film drying procedures on RDE characterization of Pt/VC electrocatalysis. J. Electroanal. Chem. 662, 396-406 (2011).
27. 3 in an aqueous alkaline solution. J. Electrochem. Soc. 122, 159-163 (1975).
28. Grenier, J. C., Pouchard, M. & Wattiaux, A. Electrochemical synthesis: Oxygen intercalation. Curr. Opin. Solid State Mater. Sci. 1, 233-240 (1996). (Pubitemid 126407971)
29. 25 system. J. Phys. Chem. C 115, 1311-1322 (2011).
30. 3-δ. Chem. Mater. 22, 70-76 (2010).
31. 3 cubic perovskite by electrochemical means. Solid State Commun. 77, 489-493 (1991).
32. 3. J. Solid State Chem. 114, 294-296 (1995).
33. Nemudry, A., Goldberg, E. L., Aguirre, M. & Alario-Franco, M. Á. Electrochemical topotactic oxidation of nonstoichiometric perovskites at ambient temperature. Solid State Sci. 4, 677-690 (2002).
34. 3 studied by soft X-ray absorption spectroscopy. Phys. Rev. B 46, 4511-4519 (1992).
35. Manthiram, A., Kuo, J. F. & Goodenough, J. B. Characterization of oxygen deficient perovskites as oxide ion electrolytes. Solid State Ion. 52, 225-234 (1993).
36. 2). Solid State Ion. 17, 13-19 (1985). (Pubitemid 15588761)
37. Wang, X. Q. et al. Ammonia treated ordered mesoporous carbons as catalytic materials for oxygen reduction reaction. Chem. Mater. 22, 2178-2180 (2010).