Study of the performance of nitrilotriacetic acid and ethylenediiminopropanedioic acid as alternative biodegradable chelating agents for pulp bleaching

International Journal of Environmental Research

Volumn 8, Issue 3, 2014, Pages 613-620

  Neto, I F F ^a   Pinto, I S S ^a   Barros, M T ^b   Maycock, C D ^c,d   Soares, H M V M ^a  

^a UNIVERSITY OF PORTO   (Portugal)

^b UNIVERSIDADE NOVA DE LISBOA   (Portugal)

^c UNIVERSIDADE NOVA DE LISBOA   (Portugal)

^d UNIVERSITY OF LISBON   (Portugal)

Author keywords

Biodegradable; Chelating agent; Ethylenediiminopropanedioic acid (EDDM); Nitrilotriacetic acid (NTA); TCF bleaching

Indexed keywords

ACETIC ACID; BIODEGRADATION; BLEACHING; CHELATING AGENT; CHLORINE; COMPUTER SIMULATION; SPECIATION (CHEMISTRY);

EID: 84903126924     PISSN: 17356865     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (33)

1. Aoki, M. and Hara, Y. (2002). Aminopolycarboxylates, process for producing the same and use thereof. Patent number US6465676.
2. Chauveheid, R., Devenyns, J. and Van, B. T. (1999). Method for bleaching paper pulp. Patent number WO9946440.
3. Colodette, J. L., Gomide, J. L., Junior, D. L. and Pedrazzi, C. (2007). Effect of Pulp delignification degree on fiber line performance and bleaching effluent load. Bioresources, 2, 223-234.
4. Colodette, J. L., Rothenberg, S. and Dence, C. W. (1988). Factors affecting hydrogen peroxide stability in the brightening of mechanical and chemimechanical pulps. 1. Hydrogen peroxide stability in the absence of stabilizing systems. Journal of Pulp and Paper Science, 14, 126-132.
5. De Almeida, J., Bachus, H., Djodikromo, Z., Doerfler, C., Hage, R. and Lienke, J. (2008). Bleaching of substrates. Patent number WO2008086937.
6. Dick, R. H. and Andrews, D. H. (1965). The bleaching of groundwood pulp with peroxide, the influence of certain metals on bleach response. Pulp and Paper Magazine Canadá, 62, 201-208.
7. Dixon, N. J. and Giles, M. R. (2009). Process for bleaching pulp. Patent number WO2009056893A2.
8. Egli, T. (2001). Biodegradation of metal-complexing aminopolycarboxylic acids. Journal of Bioscience and Bioengineering, 92, 89-97.
9. Fuerhacker, M., Lorbeer, G. and Haberl, R. (2003). Emission factors and sources of ethylene-diaminetetraacetic acid in waste water-a case study. Chemosphere, 52, 253-257.
10. Hyvonen, H. and Aksela, R. (2007). The complexation of novel amino acid derivatives with La(III) ion in aqueous solution. Journal of Coordination Chemistry, 60, 901-910.
11. Hyvonen, H., Orama, M., Arvelac, R., Henriksson, K., Saarinen, H., Aksela, R., Parene, A., Jakara, J. and Renvall, I. (2006). Studies on three new environmentally friendly chelating ligands. Appita Journal, 59, 142-149.
12. Jakara, J., Paren, A., Aksela, R. and Renvall, I. (1997). Proocess for the bleaching oh high yield pulp or recycled paper pulp. Patent number WO9745585A1.
13. Jones, P. W. and Williams, D. R. (2001). Speciation efficiency indices (SEI) and readily-biodegradable indices (RBI) for optimising ligand control of environmental and associated industrial processes. International Journal of Environmental Analytical Chemistry, 81, 73-88.
14. Jones, P. W. and Williams, D. R. (2002). Chemical speciation simulation used to assess the efficiency of environmentfriendly EDTA alternatives for use in the pulp and paper industry. Inorganica Chimica Acta, 339, 41-50.
15. Kujala, M., Sillanpaa, M. and Ramo, J. (2004). A method to leach manganese and some other metal cations from pulp matrix to aqueous phase for the subsequent ICP-AES analysis: a potential tool for controlling the metal profile in a pulp bleaching process. Journal of Cleaner Production, 12, 707-712.
16. Lapierre, L., Bouchard, J., Berry, R. M. and Vanlierop, B. (1995). Chelation prior to hydrogen peroxide bleaching of kraft pulps-An overview. Journal of Pulp and Paper Science, 21, 268-273.
17. Liden, J. and Ohman, L. O. (1997). Redox stabilization of iron and manganese in the +II oxidation state by magnesium precipitates and some anionic polymers. Implications for the use of oxygen-based bleaching chemicals. Journal of Pulp and Paper Science, 23, J193-J199.
18. Loureiro, P. E. G., Evtuguin, D. V. and Carvalho, M. G. V. S. (2011). The final bleaching of eucalypt kraft pulps with hydrogen peroxide: relationship with industrial ECF bleaching history and cellulose degradation. Journal of Chemical Technology and Biotechnology, 86, 381-390.
19. Martell, A. E. and Smith, R. M. (2004). NIST Standard Reference Database 46 Version 8.0. NIST Critically Selected Stability Constants of Metal Complexes Database, US Department of Commerce, National Institute of Standards and Technology.
20. Mashihar, M., Ando, T. and Murase, I. (1973). Synthesis and metal chelate stability of N, N'-ethylenebis(aminomalonic) acid. Bulletin of the Chemical Society of Japan, 46, 844-847.
21. Metsarinne, S., Ronkainen, E., Tuhkanen, T., Aksela, R. and Sillanpaa, M. (2007). Biodegradation of novel amino acid derivatives suitable for complexing agents in pulp bleaching applications. Science of the Total Environment, 377, 45-51.
22. Ni, Y. and Liu, Z. (2000). Pulp bleaching. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc.
23. Pirkanniemi, K., Sillanpaa, M. and Sorokin, A. (2003). Degradative hydrogen peroxide oxidation of chelates catalysed by metallophthalocyanines. Science of the Total Environment, 307, 11-18.
24. Pitter, P. and Sykora, V. (2001). Biodegradability of ethylenediamine-based complexing agents and related compounds. Chemosphere, 44, 823-826.
25. Potucek, F. and Milichovsky, M. (2000). Kraft pulp bleaching with hydrogen peroxide and peracetic acid. Chemical Papers, 54, 406-411.
26. Povoas, T. M., Angelico, D. A. G., Egas, A. P. V., Loureiro, P. E. G., Gando-Ferreira, L. M. and Carvalho, M. G. V. S. (2012). Prebleaching of eucalypt kraft pulp with OP stages: Effect of an acid pretreatment or chelation step. Tappi Journal, 11, 31-38.
27. Renvall, I., Askela, R. and Paren, A. (1997). Process for bleaching of a high yield pulp. Patent number WO9730209.
28. Schecher, W. D. and McAvoy, D. C. (2003). MINEQL+ A Chemical Equilibrium Modeling System, Version 4.5 for Windows, User's Manual. Hallowell, Maine.
29. Schmidt, C. K. and Brauch, H. J. (2004). Impact of aminopolycarboxylates on aquatic organisms and eutrophication: Overview of available data. Environmental Toxicology, 19, 620-637.
30. Seccombe, R. and Dournel, P. (2007). Process for the bleaching of mechanical paper pulp.
31. Sykora, V., Pitter, P., Bittnerova, I. and Lederer, T. (2001). Biodegradability of ethylenediamine-based complexing agents. Water Research, 35, 2010-2016.
32. Takahashi, R., Fujimoto, N., Suzuki, M. and Endo, T. (1997). Biodegradabilities of ethylenediamine-N, N'-disuccinic acid (EDDS) and other chelating agents. Bioscience Biotechnology and Biochemistry 61, 1957-1959.
33. Wuorimaa, A., Jokela, R. and Aksela, R. (2006). Recent developments in the stabilization of hydrogen peroxide bleaching of pulps: An overview. Nordic Pulp & Paper Research Journal, 21, 435-443.