Degradative hydrogen peroxide oxidation of chelates catalysed by metallophthalocyanines

Science of the Total Environment

Volumn 307, Issue 1-3, 2003, Pages 11-18

  Pirkanniemi, Kari ^a   Sillanpää, Mika ^b   Sorokin, Alexander ^c  

^a AALTO UNIVERSITY   (Finland)

^b UNIVERSITY OF OULU   (Finland)

^c CNRS   (France)

Author keywords

Catalysis; Chelating agent; Degradation; Hydrogen peroxide; Phthalocyanine

Indexed keywords

CATALYST ACTIVITY; COMPLEXATION; DEGRADATION; HYDROGEN PEROXIDE; ORGANIC ACIDS; SOLUTIONS;

CHELATING AGENTS;

CHELATION;

BETA ALANINEDIACETIC ACID; CALCIUM DERIVATIVE; CHELATING AGENT; COPPER DERIVATIVE; DIETHYLENETRIAMINE PENTAKIS(METHYLPHOSPHONIC ACID); EDETIC ACID; HYDROGEN PEROXIDE; IRON DERIVATIVE; MANGANESE DERIVATIVE; NITRILOTRIACETIC ACID; OXIDIZING AGENT; PENTETIC ACID; PHTHALOCYANINE DERIVATIVE; SODIUM DERIVATIVE; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

HYDROGEN PEROXIDE;

AQUEOUS SOLUTION; ARTICLE; BIODEGRADABILITY; BLEACHING; CATALYSIS; CATALYST; OXIDATION; PRIORITY JOURNAL; PULP MILL; TEMPERATURE; WASTE WATER;

EID: 0037457680     PISSN: 00489697     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0048-9697(02)00499-0     Document Type: Article

References (26)

1. Keys to Chelation. 1990;Dow Chemical Company, Michigan, USA. 87 pp.
2. Azab H.A., Hassan A. Polarographic study of the composition and stability constants of copper(II) N-(2-acetamido)iminodiacetate complexes. Bull Soc Chim Fr. Sept.-Oct. 1989;599-602.
3. Bhattacharyya S.N., Kundu K.P. Spectrophotometric Determination of EDTA. Talanta. 18:1971;446-449.
4. Bucheli-Witschel M., Egli T. Environmental fate and microbial degradation of aminopolycarboxylic acids. FEMS Microbiol Rev. 25:2001;69-106.
5. Hadasch A., Sorokin A., Rabion A., Fraisse L., Meunier B. Oxidation of 2,4,6-trichlorophenol (TCP) catalyzed by iron tetrasulfophthalocyanine (FePcS) supported on a cationic ion-exchange resin. Bull Soc Chim Fr. 134:1997;1025-1032.
6. 2, pH and solvent effects as key factors in the oxidation of 2,4,6-trichlorophenol catalyzed by iron tetrasulfophthalocyanine. New J Chem. 22:1998;45-51.
7. Hadasch A, Meunier B. Oxidation of dichloroanilines and related anilides catalyzed by iron (III) tetrasulfophthalocyanine. Eur J Inorg Chem 1999;2319-2325.
8. Héquet V., Le Cloirec P., Gonzalez C., Meunier B. Photocatalytic degradation of atrazine by porphyrin and phthalocyanine complexes. Chemosphere. 41:2000;379-386.
9. Kari F.G., Giger W. Speciation and fate of ethylenediaminetetraacetate (EDTA) in municipal wastewater treatment. Water Res. 30:1996;122-134.
10. Larisch B.C., Duff S.J.B. Effect of DTPA and EDTA on activated sludge reactors treating bleached kraft mill effluent. Tappi J. 3:2000;54.
11. Martell AE, Smith RM (editors). Amino acids. Critical stability constants Vol. 1. New York, NY, USA: Plenum 1974: 469 pp.
12. Martell A.E., Smith R.M., Motekaitis R. NIST Critically Selected Stability Constants of Metal Complexes Database. 1997;National Institute of Science and Technology, Gaithersburg, MD.
13. Metsärinne S., Tuhkanen T., Aksela R. Photodegradation of ethylenediaminetetraacetic acid (EDTA) and ethylenediamine disuccinic acid (EDDS) within natural UV radiation range. Chemosphere. 45:2001;949-955.
14. Meunier B., Sorokin A. Oxidation of pollutants catalyzed by metallophthalocyanines. Acc Chem Res. 30:1997;470-476.
15. Nowack B., Stone A.T. Degradation of nitrilotris(methylenephosphonic acid) and related (amino)phosphonate chelating agents in the presence of manganese and molecular oxygen. Environ Sci Technol. 34:2000;4759-4765.
16. Pitter P., Sýkora V. Biodegradability of ethylenediamine-based complexing agents and related compounds. Chemosphere. 44:2001;823-826.
17. Rämö J., Sillanpää M., Orama M., Vickackaite V., Niinisto L. Chelating ability and solubility of DTPA, EDTA and β-ADA in alkaline hydrogen peroxide environment. J Pulp Pap Sci. 26:2000;125-131.
18. Sillanpää M., Orama M., Rämö J., Oikari A. The importance of ligand speciation in environmental research: a case study. Sci Tot Env. 267:2001;23-31.
19. Sillanpää M., Pirkanniemi K. Recent developments in chelate degradation. Environ Technol. 22:2001;791-801.
20. Sillanpää M., Rämö J. Adsorption of metal-ethylenediaminetetraacetic acid chelates onto lake sediment. Chemosphere. 45:2001;881-885.
21. 2-process. Acta Hydrochim Hydrobiol. 26:1998;109-115.
22. 2 and its surrogates. J Mol Cat A. 117:1997;103-114.
23. Sorokin A., Meunier B. Oxidation of polycyclic aromatic hydrocarbons catalyzed by iron tetrasulfophthalocyanine FePcS: inverse isotope effects and oxygen labeling studies. Eur J Inorg Chem. 9:1998;1269-1281.
24. Sorokin A., Séris J.-L., Meunier B. Efficient oxidative dechlorination and aromatic ring cleavage of chlorinated phenols catalyzed by iron sulfophthalocyanine. Science. 268:1995;1163-1166.
25. Vandevivere P.C., Saveyn H., Verstraete W., Feijtel T.C.J., Schowanek D.R. Biodegradation of metal-[S,S]-EDDS complexes. Environ Sci Technol. 35:2001;1765-1770.
26. Weber J.H., Busch D.H. Complexes derived from strong field ligands. XIX. Magnetic properties of transition metal derivatives of 4,4′,4′′,4′′′-tetrasulfophthalocyanine. Inorg Chem. 4:1965;469-471.