Self-healing nanocoatings for corrosion control

Corrosion Protection and Control Using Nanomaterials

Volumn , Issue , 2012, Pages 213-263

  Ferreira, M G S ^a   Zheludkevich, M L ^a   Tedim, J ^a   Yasakau, K A ^a  

^a UNIVERSITY OF AVEIRO   (Portugal)

Author keywords

Conversion coatings; Nanoreservoirs; Nanostructured coatings; Self healing; Silane coatings

Indexed keywords

EID: 84902616534     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-1-84569-949-9.50009-5     Document Type: Chapter

References (201)

1. 3 binary solutions as environment-friendly corrosion inhibitors of AA5083 Al-Mg alloy in NaCl solutions. J. Alloys Compd. 2001, 323:855-858.
2. Abdullayev E., Lvov Y. Clay nanotubes for corrosion inhibitor encapsulation: release control with end stoppers. J. Mater. Chem. 2010, 20:6681-6687.
3. Ahmad N., McDiarmid A.G. Inhibition of corrosion of steels with the exploitation of conducting polymers. Synth. Met. 1996, 78:103-110.
4. Aldykiewicz A.J., Davenport A.J., Isaacs H.S. Studies of the formation of cerium-rich protective films using x-ray absorption near-edge spectroscopy and rotating disk electrode methods. J. Electrochem. Soc. 1996, 143:147-154.
5. Allsop N.A., Bowditch M.R., Glass N.F.C., Harris A.E., O'Gara P.M. Thermal analysis in the development of self validating adhesives. Thermochim. Acta. 1998, 315:67-75.
6. Alpha Metal Finishing, Chromate Conversion. Available from: [Accessed 27 May 2011]. http://www.alphametal.com/services/chromate-conversion.
7. 2 pretreatment for AA2024 aluminum alloy. Surf. Interface Anal. 2010, 42:293-298.
8. Aramaki K. Self-healing mechanism of an organosiloxane polymer film containing sodium silicate and cerium(III) nitrate for corrosion of scratched zinc surface in 0.5M NaCl. Corros. Sci. 2002, 44:1621-1632.
9. Aramaki K. Self-healing mechanism of a protective film prepared on a Ce(NO3)3-pretreated zinc electrode by modification with Zn(NO3)2 and Na3PO4. Corros. Sci. 2003, 45:1085-1101.
10. Arenas M.A., Bethencourt M., Botana F.J., de Damborenea J.J., Marcos M. Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts. Corros. Sci. 2001, 43:157-170.
11. Atanacio A.J., Latella B.A., Barbé C.J., Swain M.V. Mechanical properties and adhesion characteristics of hybrid sol-gel thin films. Surf. Coat. Technol. 2005, 192:354-364.
12. Atik M., Lima Neto P., Avaca L.A., Aegerter M.A., Zarzycki J. Protection of 316L stainless steel against corrosion by SiO2 coatings. J. Mater. Sci. Lett. 1994, 13:1081-11015.
13. Atik M., Luna F.P., Messaddeq S.H., Aegerter M.A. Ormocer (ZrO2;-PMMA) Films for Stainless Steel Corrosion Protection. J. Sol-Gel Sci. Technol. 1997, 8:517-522.
14. Azim S.S., Sathiyanarayanan S., Venkatachari G. Anticorrosive properties of PANI-ATMP polymer containing organic coating. Prog. Org. Coatings 2006, 56:154-158.
15. Bai H., Li C., Shi G. Electrochemical Fabrication of Superhydrophobic Surfaces on Metal and Semiconductor Substrates. J. Adhes. Sci. Technol. 2008, 22:1819-1839.
16. Barranco V., Carmona N., Galván J.C., Grobelny M., Kwiatkowski L., Villegas M.A. Electrochemical study of tailored sol-gel thin films as pre-treatment prior to organic coating for AZ91 magnesium alloy. Prog. Org. Coat. 2010, 68:347-355.
17. Bescher E., Mackenzie J.D. Sol-Gel Coatings for the Protection of Brass and Bronze. J. Sol-Gel Sci. Technol. 2003, 26:1223-1226.
18. Bethencourt M., Botana F.J., Calvino J.J., Marcos M., Rodriguez-Chacon M.A. Lanthanide compounds as environmentally friendly corrosion inhibitors for aluminum alloys: a review. Corros. Sci. 1998, 40:1803-1819.
19. Bilal B.A., Muller E. Thermodynamic study of cerium(4+)/cerium(3+) redox reaction in aqueous solutions at elevated temperatures 1. Reduction potential and hydrolysis equilibria of cerium(4+) in perchloric acid solutions. Z. Naturforsch., A: Phys. Sci. 1992, 47:974-984.
20. Bohm S., McMurray H.N., Powell S.M., Worsley D.A. Novel environment friendly corrosion inhibitor pigments based on naturally occurring clay minerals. Mater. Corros. 2001, 52:896-903.
21. Borisova D., Möhwald H., Shchukin D.G. Mesoporous Silica Nanoparticles for Active Corrosion Protection. ACS Nano 2011, 5:1939-1946.
22. Boysen W., Frattini A., Pellegri N., de Sanctis O. Protective coatings on copper prepared by sol-gel for industrial applications. Surf. Coat. Technol. 1999, 122:14-17.
23. Brédas J.L., Scott J.C., Yakushi K., Street G.B. Polarons and bipolarons in polypyrrole: Evolution of the band structure and optical spectrum upon doing. Phys. Rev. B 1984, 30:1023-1025.
24. Brown E.N., White S.R., Sottos N.R. Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite-Part II: In situ self-healing. Compos. Sci. Technol. 2005, 65:2474-2480.
25. 2 particles. Surf. Coat. Tech. 2010, 205:603-613.
26. Buchheit R.G., Mamidipally S.B., Schmutz P., Guan H. Active Corrosion Protection in Ce-Modified Hydrotalcite Conversion Coatings. Corrosion 2002, 58:3-14.
27. Buchheit R.G., Guan H., Mahajanam S., Wong F. Active corrosion protection and corrosion sensing in chromate-free organic coatings. Prog. Org. Coat. 2003, 47:174-182.
28. Cabral A.M., Trabelsi W., Serra R., Montemor M.F., Zheludkevich M.L., et al. The corrosion resistance of hot dip galvanised steel and AA2024-T3 pre-treated with bis-[triethoxysilylpropyl] tetrasulfide solutions doped with Ce(NO3)3. Corros. Sci 2006, 48:3740-3758.
29. Campestrini P., Terryn H., Hovestad A., de Wit J.H.W. Formation of a cerium-based conversion coating on AA2024: relationship with the microstructure. Surf. Coat. Technol. 2004, 176:365-381.
30. Chang K.-C., Lai M.-C., Peng C.-W., Chen Y.-T., Yeh J.-M., et al. Comparative studies on the corrosion protection effect of DBSA-doped polyaniline prepared from in situ emulsion polymerization in the presence of hydrophilic Na+-MMT and organophilic organo-MMT clay platelets. Electrochim. Acta 2006, 51:5645-5653.
31. Chen Y., Jin L., Xie Y. Sol-Gel Processing of Organic-Inorganic Nanocomposite Protective Coatings. J. Sol-Gel Sci. Technol. 1998, 13:735-738.
32. Chiang J.-C., MacDiarmid A.G. Polyaniline: Protonic acid doping of the emeraldine form to the metallic regime. Synth. Met. 1986, 13:193-205.
33. Cho B.S.H., Andersson H.M., White S.R., Sottos N.R., Braun P.V. Polydimethylsiloxane-Based Self-Healing Materials. Adv. Mater. 2006, 18:997-1000.
34. Chou T.P., Chandrasekaran C., Limmer S.J., Seraji S., Wu Y., et al. Organic-inorganic hybrid coatings for corrosion protection. J. Non-Cryst. Solids 2001, 290:153-162.
35. Chou T.P., Chandrasekaran C., Cao G.Z. Sol-Gel-Derived Hybrid Coatings for Corrosion Protection. J. Sol-Gel Sci. Technol. 2003, 26:321-327.
36. Conde A., Durán A., de Damborenea J.J. Polymeric sol-gel coatings as protective layers of aluminium alloys. Prog. Org. Coat. 2003, 46:288-296.
37. Cook A., Gabriel A., Laycock N. On the Mechanism of Corrosion Protection of Mild Steel with Polyaniline. J. Electrochem. Soc. 2004, 151:B529-B535.
38. Cook R.L. Releasable corrosion inhibitor compositions 2005, TDA Research, Inc., Wheat Ridge, CO, US patent application 6933046, 2005-Aug-23.
39. Daum P., Murray R.W. Charge-transfer diffusion rates and activity relationships during oxidation and reduction of plasma-polymerized vinylferrocene films. J. Phys. Chem. 1981, 85:389-396.
40. Davo B., de Damborenea J.J. Use of rare earth salts as electrochemical corrosion inhibitors for an Al-Li-Cu (8090) alloy in 3.56% NaCl. Electrochim. Acta 2004, 49:4957-4965.
41. DeBerry D.W. Modification ofthe electrochemical and corrosion behavior of stainless steels with an electroactive coating. J. Electrochem. Soc. 1985, 132:1022-1026.
42. Di Maggio R., Rossi S., Fedrizzi L., Scardi P. ZrO2-CeO2 films as protective coatings against dry and wet corrosion of metallic alloys. Surf. Coat. Technol. 1997, 89:292-298.
43. Doblhofer K., Durr W., Jauch M. Electrochemical redox response of iron (II)/(III) ions implanted in permeable, polymeric electrode coatings. Electrochim. Acta 1982, 27:677-682.
44. Dominis A.J., Spinks G.M., Wallace G.G. Comparison of polyaniline primers prepared with different dopants for corrosion protection of steel. Prog. Org. Coat. 2003, 48:43-49.
45. Doscher T.M., Myers G.C., Atkins D.C. The behavior of nonionic surface active agents in salt solutions. J. Colloid Sci. 1951, 6:223-235.
46. Eckler E.P., Ferrara L.M. Anti-corrosive protective coatings 1988, International Minerals & Chemical Corp., US patent application 4738720, 1988-April-19.
47. Fedrizzi L., Rodriguez F.J., Rossi S., Deflorian F., Di Maggio R. The use of electrochemical techniques to study the corrosion behaviour of organic coatings on steel pretreated with sol-gel zirconia films. Electrochim. Acta 2001, 46:3715-3724.
48. Feil F., Fürbeth W., Schütze M. Purely inorganic coatingsbasedonnanoparticles for magnesium alloys. Electrochim. Acta 2009, 54:2478-2486.
49. Filipovic N., Kojic M., Tsuda A. Modelling thrombosis using dissipative particle dynamics method. Phil. Trans. Royal 2008, 366:3265-3279.
50. Fix D., Andreeva D.V., Lvov Y.M., Shchukin D.G., Möhwald H. Application of Inhibitor-Loaded Halloysite Nanotubes in Active Anti-Corrosive Coatings. Adv. Funct. Mater. 2009, 19:1720-1727.
51. Galio A.F., Lamaka S.V., Zheludkevich M.L., Dick L.F.P., Müller I.L., et al. Inhibitor-doped sol-gel coatings for corrosion protection of magnesium alloy AZ31. Surf. Coat. Technol. 2010, 204:1479-1486.
52. Gallardo J., Duran A., Garcia I., Celis J.P., Arenas M.A., et al. Effect of Sintering Temperature on the Corrosion and Wear Behavior of Protective SiO2-Based Sol-Gel Coatings. J. Sol-Gel Sci. Technol. 2003, 27:175-183.
53. Garcia-Heras M., Jimenez-Morales A., Casal B., Galvan J.C., Radzki S., et al. Preparation and electrochemical study of cerium-silica sol-gel thin films. J. Alloys Compd. 2004, 380:219-224.
54. Ghosh S.K. Self-healing materials 2008, Wiley-VCH, Weinheim.
55. Grigoriev D.O., Köhler K., Skorb E., Shchukin D.G., Möhwald H. Polyelectrolyte complexes as a "smart" depot for self-healing anticorrosion coatings. Soft Matter 2009, 5:1426-1432.
56. Guglielmi M. Sol-gel coatings on metals. J. Sol-Gel Sci. Technol. 1997, 8:443-449.
57. Haas K.H. Hybrid Inorganic-Organic Polymers Based on Organically Modified Si-Alkoxides. Adv. Eng. Mater. 2000, 2:571-582.
58. Hermelin E., Petitjean J., Lacroix J.-C., Chane-Ching K.I., Tanguy J., et al. Ultrafast electrosynthesis of high hydrophobic polypyrrole coatings on a Zinc electrode: Applications to the protection against Corrosion. Chem. Mater. 2008, 20:4447-4456.
59. Hien N.T.L., Garcia B., Pailleret A., Deslouis C. Role of doping ions in the corrosion protection of iron by polypyrrole films. Electrochim. Acta 2005, 50:1747-1755.
60. Hoebbel D., Nacken M., Schmidt H. A NMR Study on the Hydrolysis, Condensation and Epoxide Ring-Opening Reaction in Sols and Gels of the System Glycidoxypropyltrimethoxysilane-Water-Titaniumtetraethoxide. J. Sol-Gel Sci. Technol. 1998, 12:169-179.
61. Hofacker S., Mechtel M., Mager M., Kraus H. Sol-gel: a new tool for coatings chemistry. Prog. Org. Coat. 2002, 45:159-164.
62. Hu J.-M., Liu L., Zhang J.-Q., Cao C.-N. Electrodeposition of silane films on aluminum alloys for corrosion protection. Prog. Org. Coat. 2007, 58:265-271.
63. Iroh J.O., Zhua Y., Shah K., Levine K., Rajagopalan R., et al. Electrochemical synthesis: a novel technique for processing multi-functional coatings. Prog. Org. Coatings 2003, 47:365-375.
64. Izumi K., Murakami M., Deguchi T., Morita A., Tohge N., Minami T. Zirconia Coating on Stainless Steel Sheets from Organozirconium Compounds. J. Am. Ceram. Soc. 1989, 72:1465-1468.
65. Joshua Du Y., Damron M., Tang G., Zheng H., Chu C.J., et al. Inorganic/organic hybrid coatings for aircraft aluminum alloy substrates. Prog. Org. Coat. 2001, 41:226-232.
66. Judeinstein P., Sanchez C. Hybrid Organic-Inorganic Materials: A Land of Multidisciplinarity. J.Mater. Chem. 1996, 6:511-525.
67. Kartsonakis I.A., Kordas G. Synthesis and Characterization of Cerium Molybdate Nanocontainers and their Inhibitor Complexes. J. Am. Ceram. Soc. 2010, 93:65-73.
68. Kasten L.S., Grant J.T., Grebasch N., Voevodin N.N., Arnold F.E., et al. AnXPS Study of Cerium Dopants in Sol-gel Coatings for Aluminum 2024-T3. Surf. Coat. Technol. 2001, 140:11-15.
69. Kendig M.W., Davenport A.J., Isaacs H.S. The mechanism of corrosion inhibition by chromate conversion coatings from x-ray absorption near edge spectroscopy (Xanes). Corros. Sci. 1993, 34:41-49.
70. Kendig M., Hon M., Warren L. "Smart" corrosion inhibiting coatings. Prog. Org. Coat. 2003, 47:183-189.
71. Khobaib M., Reynolds L.B., Donley M.S. A comparative evaluation of corrosion protection of sol-gel based coatings systems. Surf. Coat. Technol. 2001, 140:16-23.
72. Khramov A.N., Balbyshev V.N., Voevodin N.N., Donley M.S. Nanostructured sol-gel derived conversion coatings based on epoxy- and amino-silanes. Prog. Org. Coat. 2003, 47:207-213.
73. Khramov A.N., Voevodin N.N., Balbyshev V.N., Donley M.S. Hybrid organo-ceramic corrosion protection coatings with encapsulated organic corrosion inhibitors. Thin Solid Films 2004, 447-8:549-557.
74. Khramov A.N., Voevodin N.N., Balbyshev V.N., Mantz R.A. Sol-gel-derived corrosion-protective coatings with controllable release of incorporated organic corrosion inhibitors. Thin Solid Films 2005, 483:191-196.
75. Kinlen P.J., Ding Y., Silverman D.C. Corrosion protection of mild steel using sulfonic and phosphonic acid-doped polyanilines. Corrosion 2002, 58:490.
76. Koch K., Ensikat H.J. The hydrophobic coatings of plant surfaces: epicuticular wax crystals and their morphologies, crystallinity and molecular self-assembly. Micron 2008, 39:759-772.
77. Koch K., Bhushan B., Ensikat H.J., Barthlott W. Self-healing of voids in the wax coating on plant surfaces. Philos. Transact. A Math. Phys. Eng. Sci. 2009, 367:1673-1688.
78. Kowalski D., Ueda M., Ohtsuka T. Self-healing ion-permselective conducting polymer coating. J. Mater. Chem. 2010, 20:7630-7633.
79. Lacaze P.C., Ghilane J., Randriamahazaka H., Lacroix J.-C. Electroactive Conducting Polymers for the Protection of Metals against Corrosion: from Micro- to Nano structured Films. Nanostructured conductive polymers 2010, John Wiley & Sons. A. Eftekhari (Ed.).
80. Lacroix J.-C., Camalet J.L., Aeiyach S., Chane-Ching K.I., Petitjean J., et al. Aniline electropolymerization on mild steel and zinc in a two-step process. J. Electroanal. Chem. 2000, 481:76-81.
81. Lamaka S.V., Zheludkevich M.L., Yasakau K.A., Montemor M.F., Cecilio P., et al. TiOx self-assembled networks prepared by templating approach as nanostructured reservoirs for self-healing anticorrosion pre-treatments. Electrochem. Commun. 2006, 8:421-428.
82. Lamaka S.V., Zheludkevich M.L., Yasakau K.A., Serra R., Poznyak S.K., et al. Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability. Prog. Org. Coat. 2007, 58:127-135.
83. Lamaka S.V., Shchukin D.G., Andreeva D.V., Zheludkevich M.L., Möhwald H., et al. Sol-Gel/Polyelectrolyte Active Corrosion Protection System. Adv. Funct. Mater. 2008, 18:3137-3147.
84. Leggat R.B., Zhang W., Buchheit R.G., Taylor S.R. Performance of Hydrotalcite Conversion Treatments on AA2024-T3 When Used in a Coating System. Corrosion 2002, 58:322-328.
85. Li Y.-S., Lu W., Wang Y., Tran T. Studiesof(3-mercaptopropyl)trimethoxylsilane and bis(trimethoxysilyl)ethane sol-gel coating on copper and aluminum. Spectrochim. Acta, Part A 2009, 73:922-928.
86. Liu J., Lin Y., Liang L., Voigt J.A., Huber D.L., et al. Templateless assembly of molecularly aligned conductive polymer nanowires: a new approach for oriented nanostructures. Chem. Eur. J. 2003, 9:604-611.
87. Liu Y., Sun D., You H., Chung J.S. Corrosion resistance properties of organic-inorganic hybrid coatings on 2024 aluminum alloy. Appl. Surf. Sci. 2005, 246:82-89.
88. Lu W.-K., Elsenbaumer R.L., Wessling B. Corrosion Protection Of Mild Steel By Coatings Containing Polyaniline. Synt. Met. 1995, 71:2163-2166.
89. Luca V., Thomson S. Intercalation and polymerisation of aniline within a tubular aluminosilicate. J. Mater. Chem. 2000, 10:2121-2126.
90. MacDiarmid A.G., Chiang J.-C., Richter A.F., Epstein A.J. Polyaniline: a new concept in conducting polymers. Synth. Met. 1987, 18:285-290.
91. MacDiarmid A.G. Synthetic Metals: ANovel Role for Organic Polymers (Nobel Lecture). Angew. Chem. Int. Ed. 2001, 40:2581-2590.
92. Mackenzie J.D., Bescher E.P. Structures, Properties and Potential Applications of Ormosils. J. Sol-Gel Sci. Technol. 1998, 13:371-377.
93. Mackenzie J.D., Bescher E. Some Factors Governing the Coating of Organic Polymers by Sol-Gel Derived Hybrid Materials. J. Sol-Gel Sci. Technol. 2003, 27:7-14.
94. Malzbender J., de With G. Modification ofthe Mechanical Properties of a Sol-Gel Coating Using Silica Filler Nanoparticles. Adv. Eng. Mater. 2002, 4:296-300.
95. Mascia L., Prezzi L., Wilcox G.D., Lavorgna M. Molybdate doping of networks in epoxy-silica hybrids: Domain structuring and corrosion inhibition. Prog. Org. Coat. 2006, 56:13-22.
96. Mayer C.R., Cabuil V., Lalot T., Thouvenot R. Magnetic Nanoparticles Trapped in pH 7Hydrogels as a Tool to Characterize the Properties of the Polymeric Network. Adv. Mater. 2000, 12:417-420.
97. Mayrand M., Quinson J.F., Roche A., Roisne V., Guyon H. Heteropolysiloxane Coatings on Electrogalvanized Steel: Elaboration and Characterization. J. Sol-Gel Sci. Technol. 1998, 12:49-57.
98. McAndrew T.P., Miller S.A., Gilicinski A.G., Robeson L.M. Polym. Mater. Sci. Eng. 1996, 74:204-206.
99. McMurray H.N., Williams D., Williams G., Worsley D. Inhibitorpretreatment synergies demonstrated using a scanning Kelvin probe technique. Corros. Eng. Sci. Techn. 2003, 38:112-118.
100. McMurray H.N., Williams G. Inhibition of Filiform Corrosion on Organic-Coated Aluminum Alloy by Hydrotalcite-Like Anion-Exchange Pigments. Corrosion 2004, 60:219-228.
101. Mengoli G., Munari M., Bianco P., Musiani M. Anodic synthesis of polyaniline coatings onto fe sheets. J. Appl. Polym. Sci. 1981, 26:4247-4257.
102. Menning M., Schelle C., Duran A., Damborenea J.J., Guglielmi M., et al. Investigation of Glass-Like Sol-Gel Coatings for Corrosion Protection of Stainless Steel Against Liquid and Gaseous Attack. J. Sol-Gel Sci. Technol. 1998, 13:717-722.
103. Metroke T.L., Parkhill R.L., Knobbe E.T. Passivation of metal alloys using sol-gel-derived materials - a review. Prog. Org. Coat. 2001, 41:233-238.
104. Metroke T.L., Kachurina O., Knobbe E.T. Spectroscopic and corrosion resistance characterization of GLYMO-TEOS Ormosil coatings for aluminum alloy corrosion inhibition. Prog. Org. Coat. 2002, 44:295-305.
105. Metroke T.L., Kachurina O., Knobbe E.T. Spectroscopic and corrosion resistance characterization of amine and super acid-cured hybrid organic-inorganic thin films on 2024-T3 aluminum alloy. Prog. Org. Coat. 2002, 44:185-199.
106. Michalik A., Rohwerder M. Conducting polymers for corrosion protection: a critical view. Z. Phys. Chemie 2005, 219:1547-1560.
107. Montemor M.F., Cabral A.M., Zheludkevich M.L., Ferreira M.G.S. The corrosion resistance of hot dip galvanized steel pretreated with bis-functional silanes modified with microsilica. Surf. Coat. Technol. 2006, 200:2875-2885.
108. Montemor M.F., Trabelsi W., Zheludkevich M., Ferreira M.G.S. Modification of bis-silane solutions with rare-earth cations for improved corrosion protection of galvanized steel substrates. Prog. Org. Coat. 2006, 57:67-77.
109. Montemor M.F., Ferreira M.G.S. Electrochemical study of modified bis-[triethoxysilylpropyl] tetrasulfide silane films applied on the AZ31Mg alloy. Electrochim. Acta 2007, 52:7486-7495.
110. Montemor M.F., Ferreira M.G.S. Analytical and microscopic characterisation of modified bis-[triethoxysilylpropyl] tetrasulfide silane films on magnesium AZ31 substrates. Prog. Org. Coat. 2007, 60:228-237.
111. Montemor M.F., Ferreira M.G.S. Cerium Salt Activated Nanoparticles as Fillers For Silane Films: Evaluation of The Corrosion Inhibition Performance On Galvanised Steel Substrates. Electrochim. Acta. 2007, 52:6976-6987.
112. Mortimer R.J., Anson F.C. Apparent diffusion coefficients and electron propagation mechanisms in viologen polyelectrolyte coatings containing multiply charged anions. J. Electroanal. Chem. 1982, 138:325-341.
113. Moutarlier V., Neveu B., Gigandet M.P. Evolution of corrosion protection for sol-gel coatings doped with inorganic inhibitors. Surf. Coat. Technol. 2008, 202:2052-2058.
114. Ni H., Simonsick W.J., Skaja A.D., Williams J.P., Soucek M.D. Polyurea/polysiloxane ceramer coatings. Prog. Org. Coat. 2000, 38:97-110.
115. Ono S., Tsuge H., Nishi Y., Hirano S.-I. Improvement of Corrosion Resistance of Metals by an Environmentally Friendly Silica Coating Method. J. Sol-Gel Sci. Technol. 2004, 29:147-153.
116. Osborne J.H., Blohowiak K.Y., Taylor S.R., Hunter C., Bierwagen G., et al. Testing and evaluation of nonchromated coating systems for aerospace applications. Prog. Org. Coat. 2001, 41:217-225.
117. Palanivel V., Zhu D., van Ooij W.J. Nanoparticle-filled silane films as chromate replacements for aluminum alloys. Prog. Org. Coat. 2003, 47:384-392.
118. Palanivel V., Huang Y., Ooij W.J. Effects of Addition of Corrosion Inhibitors to Silane Films on the Performance of AA2024-T3 in a 0.5M NaCl Solution. Prog. Org. Coat. 2005, 53:153-168.
119. Paliwoda-Porebska G., Stratmann M., Rohwerder M., Potje-Kamloth K., Lu Y., et al. On the development of polypyrrole coatings with self-healing properties for iron corrosion protection. Cor. Sci. 2005, 47:3216-3233.
120. Paliwoda-Porebska G., Rohwerder M., Stratmann M., Rammelt U., Duc L.M., et al. Release mechanism of electrodeposited polypyrrole doped with corrosion inhibitor anions. J. Solid State Electrochem. 2006, 10:730-736.
121. Parkhill R.L., Knobbe E.T., Donley M.S. Application and evaluation of environmentally compliant spray-coated ormosil films as corrosion resistant treatments for aluminum 2024-T3. Prog. Org. Coat. 2001, 41:261-265.
122. Pepe A., Aparicio M., Durán A., Ceré S. Cerium hybrid silica coatings on stainless steel AISI 304 substrate. J. Sol-Gel Sci. Technol. 2006, 39:131-138.
123. Pilz M., Römich H. Sol-gel derived coating for outdoor bronze conservation. J. Sol-Gel Sci. Technol. 1997, 8:1071-1075.
124. Pippard D.A. Corrosion inhibitors, method of producing them and protective coatings containing them 1983, The British Petroleum Company Limited, US patent application 4405493. 1983-Sept-20.
125. Pirhady Tavandashti N., Sanjabi S. Corrosion study of hybrid sol-gel coatings containing boehmite nanoparticles loaded with cerium nitrate corrosion inhibitor. Prog. Org. Coat. 2010, 69:384-391.
126. Poznyak S.K., Tedim J., Rodrigues L.M., Salak A.N., Zheludkevich M.L., et al. Novel Inorganic Host Layered Double Hydroxides Intercalated with Guest Organic Inhibitors for Anticorrosion Applications. ACSAppl. Mater. Inter. 2009, 1:2353-2362.
127. Quinet M., Neveu B., Moutarlier V., Audebert P., Ricq L. Corrosionprotection of sol-gel coatings doped with an organic corrosion inhibitor: Chloranil. Prog. Org. Coat. 2007, 58:46-53.
128. Rajagopalan R., Iroh J.O. Development of polyaniline-polypyrrole composite coatings on steel by aqueous electrochemical process. Electrochim. Acta 2001, 46:2443-2455.
129. Rammelt U., Nguyen P.T., Plieth W. Corrosion protection by ultrathin films of conducting polymers. Electrochim. Acta 2003, 48:1257-1262.
130. Rao A.V., Latthe S.S., Mahadik S.A., Kappenstein C. Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate. Appl. Surf. Sci. 2011, 257:5772-5776.
131. Raps D., Hack T., Wehr J., Zheludkevich M.L., Bastos A.C., et al. Electrochemical study of inhibitor-containing organic-inorganic hybrid coatings on AA2024. Corros. Sci 2009, 51:1012-1021.
132. Rekharsky M.V., Inoue Y. Complexation Thermodynamics of Cyclodextrins. Chem. Rev. 1998, 98:1875-1917.
133. Rohwerder M., Michalik A. Conducting polymers for corrosion protection: What makes the difference between failure and success?. Electrochim. Acta 2007, 53:1300-1313.
134. Rosero-Navarro N.C., Pellice S.A., Durán A., Aparicio M. Effects of Ce-containing sol-gel coatings reinforced with SiO2 nanoparticles on the protection of AA2024. Corros. Sci. 2008, 50:1283-1291.
135. Rosero-Navarro N.C., Paussa L., Andreatta F., Castro Y., Durán A., et al. Optimization of hybrid sol-gel coatings by combination of layers with complementary properties for corrosion protection of AA2024. Prog. Org. Coat. 2010, 69:167-174.
136. Rout T.K., Jha G., Singh A.K., Bandyopadhyay N., Mohanty O.N. Development of conducting polyaniline coating: a novel approach to superior corrosion resistance. Surf. Coat. Technol. 2003, 167:16-24.
137. Rubio F., Rubio J., Oteo J.L. Effect of TiO2 on the Pore Structure of SiO2-PDMS Ormosils. J. Sol-Gel Sci. Technol. 2000, 18:105-113.
138. Sankara Narayanan T.S.N. Surface Pretreatment by Phosphate Conversion Coatings. A Review. Rev. Adv. Mater. Sci. 2005, 9:130-177.
139. Sathiyanarayanan S., Dhawan S.K., Trivedi D.C., Balakrishnan K. Soluble conducting poly ethoxy aniline as an inhibitor for iron in HCl. Corros. Sci. 1992, 33:1831-1841.
140. Sathiyanarayanan S., Muthukrishnan S., Venkatachari G., Trivedi D.C. Corrosion protection of steel by polyaniline (PANI) pigmented paint coating. Prog. Org. Coat. 2005, 53:297-301.
141. Schem M., Schmidt T., Gerwann J., Wittmar M., Veith M., et al. CeO2-filled sol-gel coatings for corrosion protection of AA2024-T3 aluminium alloy. Corros. Sci. 2009, 51:2304-2315.
142. Schmidt C. Anti-corrosive coating including a filler with a hollow cellular structure 2002, (DaimlerChrysler AG), US patent application 6383271, 2002-May-7.
143. Schmidt H., Langenfeld S., Naß R. A new corrosion protection coating system for pressure-cast aluminium automotive parts. Mater. Des. 1997, 18:309-313.
144. Schubert U., Huesing N., Lorenz A. Hybrid Inorganic-Organic Materials by Sol-Gel Processing of Organofunctional Metal Alkoxides. Chem. Mater. 1995, 7:2010-2027.
145. Shchukin D.G., Zheludkevich M., Möhwald H. Feedback active coatings based on incorporated nanocontainers. J. Mater. Chem. 2006, 16:4561-4566.
146. Shchukin D.G., Zheludkevich M., Yasakau K., Lamaka S., Ferreira M.G.S., et al. LbL Nanocontainers for Self-Healing Corrosion Protection. Adv. Mater. 2006, 18:1672-1678.
147. Shchukin D.G., Möhwald H., Ferreira M.G.S., Zheludkevich M.L. Corrosion Inhibiting Pigment Comprising Nanoreservoirs of Corrosion Inhibitor 2007, (MPG Max Planck Ges Zur Foerder), DE patent application EP1832629, Publication date: 2007-Sep-12.
148. Shchukin D.G., Lamaka S.V., Yasakau K.A., Zheludkevich M.L., Möhwald H., et al. Active Anticorrosion Coatings with Halloysite Nanocontainers. J. Phys. Chem. C 2008, 112:958-964.
149. Sheffer M., Groysman A., Mandler D. Electrodeposition of sol-gel films on Al for corrosion protection. Corros. Sci. 2003, 45:2893-2904.
150. Sheffer M., Groysman A., Starosvetsky D., Savchenko N., Mandler D. Anion embedded sol-gel films on Al for corrosion protection. Corros. Sci. 2004, 46:2975-2985.
151. Shi H., Liu F., Han E.-h. Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine. Progress in Organic Coatings 2009, 66:183-191.
152. Silva J.E.P., Torresi S.I.C., Torresi R.M. Polyaniline acrylic coatings for corrosion inhibition: the role played by counter-ions. Corros. Sci. 2005, 47:811-822.
153. Smarsly B., Garnweitner G., Assink R., Brinker C.J. Preparation and characterization of mesostructured polymer-functionalized sol-gel-derived thin films. Prog. Org. Coat. 2003, 47:393-400.
154. Spinks G.M., Dominis A.J., Wallace G.G., Tallman D.E. Electroactive conducting polymers for corrosion control-Part 2 Ferrous metals. J. Solid State Electrochem. 2002, 6:85-100.
155. Supplit R., Koch T., Schubert U. Evaluation of the anti-corrosive effect of acid pickling and sol-gel coating on magnesium AZ31 alloy. Corros. Sci. 2007, 49:3015-3023.
156. Tallman D.E., Spinks G., Dominis A., Wallace G.G. Electroactive conducting polymers for corrosion control -Part 1 General introduction and a review of non-ferrous metals. J. Solid State Electrochem. 2002, 6:73-84.
157. Talo A., Passiniemi P., Forsen O., Ylasaari S. Polyaniline/epoxy coatings with good anti-corrosion properties. Synth. Met. 1997, 85:1333-1334.
158. Tan A.L.K., Soutar A.M. Hybrid sol-gel coatings for corrosion protection of copper. Thin Solid Films 2008, 516:5706-5709.
159. Tan C.K., Blackwood D.J. Corrosion protection by multi-layered conducting polymer coatings. Corros. Sci. 2003, 45:545-557.
160. Tedim J., Poznyak S.K., Kuznetsova A., Raps D., Hack T., et al. Enhancement of Active Corrosion Protection via Combination of Inhibitor-Loaded Nanocontainers. ACSAppl. Mater. Inter. 2010, 2:1528-1535.
161. Thim G.P., Oliveira M.A.S., Oliveira E.D.A., Melo F.C.L. Sol-gel silica film preparation from aqueous solutions for corrosion protection. J. Non-Cryst. Solids 2000, 273:124-128.
162. Toohey K.S., Sottos N.R., Lewis J.A., Moore J.S., White S.R. Self-healing materials with microvascular networks. Nat. Mater. 2007, 6:581-585.
163. Trabelsi W., Cecilio P., Ferreira M.G.S., Montemor M.F. Electrochemical assessment of the self-healing properties of Ce-doped silane solutions for the pretreatment of galvanised steel substrates. Prog. Org. Coat. 2005, 54:276-284.
164. Trabelsi W., Triki E., Dhouibi L., Ferreira M.G.S., Zheludkevich M.L., et al. The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates. Surf. Coat. Technol. 2006, 200:4240-4250.
165. Trabelsi W., Cecilio P., Ferreira M.G.S., Yasakau K., Zheludkevich M.L., et al. Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates. Prog. Org. Coat 2007, 59:214-223.
166. Twite R.L., Bierwagen G.P. Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys. Progress in Organic Coatings 1998, 33:91-100.
167. Uekama K., Hirayama F., Irie T. Cyclodextrin Drug Carrier Systems. Chem. Rev. 1998, 98:2045-2076.
168. van der Zwaag S., Schmets A.J.M., van der Zaken G. Self-healing materials: an alternative approach to 20 centuries of materials 2007, Springer, Dordrecht.
169. Van Schaftinghen T., Deslouis C., Hubin A., Terryn H. Influence of the surface pre-treatment prior to the film synthesis on the corrosion protection of iron with polypyrrole films. Electrochim. Acta 2006, 51:1695-1703.
170. Vasconcelos D.C.L., Carvalho J.A.N., Mantel M., Vasconcelos W.L. Corrosion resistance of stainless steel coated with sol-gel silica. J. Non-Cryst. Solids 2000, 273:135-139.
171. Voevodin N.N., Grebasch N.T., Soto W.S., Arnold F.E., Donley M.S. Potentiodynamic evaluation of sol-gel coatings with inorganic inhibitors. Surf. Coat. Technol. 2001, 140:24-48.
172. Voevodin N.N., Grebasch N.T., Soto W.S., Kasten L.S., Grant J.T., et al. An organically modified zirconate film as a corrosion-resistant treatment for aluminum 2024-T3. Prog. Org. Coat 2001, 41:287-293.
173. Voevodin N., Jeffcoate C., Simon L., Khobaib M., Donley M. Characterization of pitting corrosion in bare and sol-gel coated aluminum 2024-T3 alloy. Surf. Coat. Technol. 2001, 140:29-34.
174. Voevodin N.N., Balbyshev V.N., Khobaib M., Donley M.S. Nanostructured coatings approach for corrosion protection. Prog. Org. Coat. 2003, 47:416-423.
175. Voevodin N.N., Balbyshev V.N., Donley M.S. Investigation of corrosion protection performance of sol-gel coatings on AA2024-T3. Prog. Org. Coat. 2005, 52:28-33.
176. Vreugdenhil A.J., Woods M.E. Triggered release of molecular additives from epoxy-amine sol-gel coatings. Prog. Org. Coat. 2005, 53:119-125.
177. Wang H., Presuel F., Kelly R.G. Computational Modeling of Inhibitor Release and Transport from Multifunctional Organic Coatings. Electrochim. Acta 2004, 49:239-255.
178. Wernick S., Pinner R., Sheasby P.G. The Surface Treatment and Finishing of Aluminum and its Alloys 1987, Finishing Publications Ltd., Teddington, Middlesex, England.
179. Wessling B. Passivation of metals by coating with polyaniline: Corrosion potential shift and morphological changes. Adv. Mater. 1994, 6:226-228.
180. Wessling B. Scientific and Commercial Breakthrough for Organic Metals. Synth. Met 1997, 85:1313-1318.
181. Wessling B. Dispersion as the link between basic research and commercial applications of conductive polymers (polyaniline). Synth. Met. 1998, 93:143-154.
182. Wey Y., Wang J., Jia X., Yeh J.-M., Spellane P. Polym. Mater. Sci. Eng. 1995, 72:563-564.
183. White S.R., Sottos N.R., Geubelle P.H., Moore J.S., Kessler M.R., et al. Autonomic Healing of Polymer Composites. Nature 2001, 409:794-797.
184. Williams G., McMurray H.N. Inhibition of Filiform Corrosion on Polymer Coated AA2024-T3 by Hydrotalcite-Like Pigments Incorporating Organic Anions. Electrochem. Solid. St. 2004, 7:B13-B15.
185. Xu L., Chen W., Mulchandani A., Yan Y. Reversible Conversion of Conducting Polymer Films from Superhydrophobic to Superhydrophilic. Angew. Chem. Int. Ed. 2005, 44:6009-6012.
186. Yang H., Van Ooij W.J. Plasma-treated triazole as a novel organic slow-release paint pigment for corrosion control of AA2024-T3. Prog. Org. Coat. 2004, 50:149-161.
187. Yasakau K.A., Zheludkevich M.L., Lamaka S.V., Ferreira M.G.S. Mechanism of Corrosion Inhibition of AA2024 by Rare-Earth Compounds. J. Phys. Chem. B 2006, 110:5515-5528.
188. Yasakau K.A., Zheludkevich M.L., Karavai O.V., Ferreira M.G.S. Influence of inhibitor addition on the corrosion protection performance of sol-gel coatings on AA2024. Prog. Org. Coat. 2008, 63:352-361.
189. Yeh J.-M., Liou S.-J., Lai C.-Y., Wu P.-C., Tsai T.-Y. Enhancement of Corrosion Protection Effect in Polyaniline via the Formation of Polyaniline-Clay Nanocomposite Materials. Chem. Mater. 2001, 13:1131-1136.
190. Yeh J.-M., Chin C.-P., Chang S. Enhanced Corrosion Protection Coatings Prepared from Soluble Electronically Conductive Polypyrrole-Clay Nanocomposite Materials. J. Appl. Polym. Sci. 2003, 88:3264-3272.
191. +-MMT clay nanocomposite via emulsion polymerization: Electrochemical studies of corrosion protection. Eur. Poly. J. 2007, 43:1624-1634.
192. Yin T., Rong M.Z., Zhang M.Q., Yang G.C. Self-healing epoxy composites - Preparation and effect of the healant consisting of microencapsulated epoxy and latent curing agent. Compos. Sci. Technol. 2007, 67:201-212.
193. Yu X., Cao C. Electrochemical study of the corrosion behavior of Ce sealing of anodized 2024 aluminum alloy. Thin Solid Films 2003, 423:252-256.
194. Zaarei D., Sarabi A.A., Sharif F., Kassiriha S.M. Structure, properties and corrosion resistivity of polymeric nanocomposite coatings based on layered silicates. J. Coat. Technol. Res. 2008, 5:241-249.
195. Zheludkevich M.L., Serra R., Montemor M.F., Yasakau K.A., Salvado I.M.M., et al. Nanostructured sol-gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 - Corrosion protection performance. Electrochim. Acta 2005, 51:208-217.
196. Zheludkevich M.L., Serra R., Montemor M.F., Ferreira M.G.S. Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors. Electrochem. Commun. 2005, 7:836-840.
197. Zheludkevich M., Serra R., Montemor F., Salvado I., Ferreira M. Corrosion protective properties of nanostructured sol-gel hybrid coatings to AA2024-T3. Surf. Coat. Tech. 2006, 200:3084-3094.
198. Zheludkevich M.L., Shchukin D.G., Yasakau K.A., Möhwald H., Ferreira M.G.S. Anticorrosion coatings with self-healing effect based on nanocontainers loaded with corrosion inhibitor. Chem. Mater. 2007, 19:402-411.
199. Zheludkevich M.L. Self-healing anticorrosion coatings. Self-healing materials 2008, 101-140. Wiley-VCH. S.K. Ghosh (Ed.).
200. Zheludkevich M.L., Poznyak S.K., Rodrigues L.M., Raps D., Hack T., et al. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corros. Sci. 2010, 52:602-611.
201. Zheludkevich M.L., Tedim J., Freire C.S.R., Fernandes S.C.M., Kallip S., et al. Self-healing protective coatings with "green" chitosan based pre-layer reservoir of corrosion inhibitor. J. Mater. Chem. 2011, 21:4805-4812.