Speciation of and D/H partitioning between fluids and melts in silicate-D-O-H-C-N systems determined in-situ at upper mantle temperatures, pressures, and redox conditions

American Mineralogist

Volumn 99, Issue 4, 2014, Pages 578-588

  Mysen, Bjorn O ^a   Tomita, Tokio ^b   Ohtani, Eiji ^b   Suzuki, And Akio ^b  

^a Geophysical Laboratory   (United States)

^b TOHOKU UNIVERSITY   (Japan)

Author keywords

Isotope; Melt structure; Redox; Speciation; Volatiles

Indexed keywords

AMMONIA; DEUTERIUM; DIAMONDS; DYSPROSIUM COMPOUNDS; HYDROGEN BONDS; INERT GASES; ISOTOPES; OXIDATION; PRESSURE EFFECTS; SILICATES; TEMPERATURE; TRACE ELEMENTS;

ALUMINO-SILICATE MELTS; HYDROTHERMAL DIAMOND ANVIL CELL; MELT STRUCTURES; PARTITION COEFFICIENT; REDOX; SPECIATION; THERMODYNAMIC AND TRANSPORT PROPERTIES; VOLATILES;

TRANSPORT PROPERTIES;

ALUMINOSILICATE; BRINE; CHEMICAL BONDING; DIAMOND ANVIL CELL; EXPERIMENTAL MINERALOGY; ISOTOPIC COMPOSITION; MELT; PARTITIONING; PRESSURE EFFECT; RAMAN SPECTROSCOPY; REDOX CONDITIONS; SATURATION; SOLUBILITY; SPECIATION (CHEMISTRY); TEMPERATURE EFFECT; TRACE ELEMENT; UPPER MANTLE; VOLATILE ELEMENT;

EID: 84902438019     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2014.4575     Document Type: Article

References (62)

1. Bassett, W. A., Shen, A. H., Bucknum, M., and Chou, I. M. (1994) A new diamond anvil cell for hydrothermal studies to 2.5 GPa and from -190 to 1200°C. Reviews of Scientific Instruments, 64, 2340-2345.
2. Bassett, W. A., Wu, T.-C, Chou, I.-M., Haselton, H. T. Jr., Frantz, J., Mysen, B. O., Huang, W.-L., Sharma, S. K., and Schiferl D. (1996) The hydrothermal diamond anvil cell (HDAC) and its applications. In M. D. Dyar, C. A. McCammon, and M. W. Schaefer, Eds., Mineral Spectroscopy: A Tribute to Roger G. Burns, 261-272. The Geochemical Society, Houston.
3. Cartigny, P., and Ader, M. (2003) The nitrogen record of crust-mantle interaction and mantle convection from Archean to present; discussion. Earth and Planetary Science Letters, 216, 425-432.
4. Chou, I.-M., and Anderson, A. J. (2009) Diamond dissolution and the production of methane and other carbon-bearing species in hydrothermal diamond anvil cell. Geochimica et Cosmochimica Acta, 73, 6360-6366.
5. Del Gaudio, P., Behrens, H., and Deubener, J. (2007) Viscosity and glass transition temperature of hydrous float glass. Journal of Non-Crystalline Solids, 353, 223-236.
6. Dillon, A. C., Gupta, P., Robinson, M. B., Bracker, A. S., and George, S. M. (1991) Ammonia decomposition on silicon surfaces studied using transmission Fourier transform infrared spectroscopy. Journal of Vacuum Science & Technology: Vacuum, Surfaces and Films, 9, 2222-2230.
7. Dingwell, D. B., and Webb, S. L. (1990) Relaxation in silicate melts. European Journal of Mineralogy, 2, 427-449.
8. Foustoukos, D. I., and Mysen, B. O. (2013) H/D methane isotopologues dissolved in magmatic fluids: Stable hydrogen isotope fractionations in the Earth's interior. American Mineralogist, 98, 946-954.
9. Frantz, J. D., Dubessy, J., and Mysen, B. (1993) An optical cell for Raman spectroscopic studies of supercritical fluids and its application to the study of water to 500 °C and 2000 bar. Chemical Geology, 106, 9-26.
10. Furukawa, T, Fox, K. E., and White, W. B. (1981) Raman spectroscopic investigation of the structure of silicate glasses. III. Raman intensities and structural units in sodium silicate glasses. Journal of Chemical Physics, 75, 3226-3237.
11. 6 glasses. EOS, 68, 1456.
12. Holland, H. D. (1984) The Chemical Evolution of the Atmosphere and Oceans, 598 p. Princeton University Press, New Jersey.
13. Holloway, J. R., and Blank, J. G. (1994) Application of experimental results to C-O-H species in natural melts. In M. R. Carroll and J. R. Holloway, Eds., Volatiles in Magmas, 30, p. 187-230. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
14. 2-water equilibration method: A special implication to brines. Chemical Geology, 72, 89-94.
15. Ishida, H., Chiang, C.-h., and Koenig, J. L. (1982) The structure of aminofunctional silane coupling agents: 1. γ-aminopropyltriethoxysilane and its analogues. Polymer, 23, 251-257.
16. 3 melts in equilibrium with metallic iron at 1.5 GPa and 1400°C. Geochemistry International, 49, 429-438.
17. 3 melt equilibrated with molten Fe alloy at high pressure and temperature. Physics of the Earth and Planetary Interiors, 214, 14-24.
18. Kasting, J. F., Eggler, D. H., and Raeburn, S. P. (1993) Mantle redox evolution and the oxidation state of the Archean atmosphere. Journal of Geology, 101, 245-257.
19. Kessel, R., Ulmer, P., Pettke, T., Schmidt, M. W., and Thompson, A. B. (2004) A novel approach to determine high-pressure high-temperature fluid and melt compositions using diamond-trap experiments. American Mineralogist, 89, 1078-1086.
20. - in Mg/Al-hydrotalcite. American Mineralogist, 87, 623-629.
21. 2. Chemical Geology, 116, 1-16.
22. 18O, and deuterium substituted analogs. Spectrochimica Acta Part A, 58, 1055-1067.
23. Long, D. A. (1977) Raman Spectroscopy, 276 p. McGraw-Hill, New York.
24. 3-n (0≤n≤3) molecules trapped in solid nitrogen. Journal of Molecular Structure, 198, 51-64.0
25. 2. American Mineralogist, 72, 481-486.
26. Luth, R. W., Virgo, D., Boyd, F. R., and Wood, B. J. (1990) Ferric iron in mantlederived garnets. Implications for thermobarometry and for the oxidation state of the mantle. Contributions to Mineralogy and Petrology, 104, 56-72.
27. Matson, D. W., Sharma, S. K., and Philpotts, J. A. (1986) Raman spectra of some tectosilicates and glasses along the orthoclase-anorthite and nepheline-anorthite joins. American Mineralogist, 71, 694-704.
28. McMillan, P. F., and Holloway, J. R. (1987) Water solubility in aluminosilicate melts. Contributions to Mineralogy and Petrology, 97, 320-332.
29. McMillan, P. F., Wolf, G. H., and Poe, B. T. (1992) Vibrational spectroscopy of silicate liquids and glasses. Chemical Geology, 96, 351-366.
30. Mibe, K., Chou, I.-M., and Bassett, W. A. (2008) In situ Raman spectroscopic investigation of the structure of subduction-zone fluids. Journal of Geophysical Research, 113, B04208, DOI: 10.1029/2007JB005179.
31. Moynihan, C. T., Macedo, P. B., Montrose, C. J., Gupta, P. K., De Bolt, M. A., Dill, J. F., Dom, B. E., Drake, P. W., Easteal, A. J., Elterman, P. B., and others. (1976) Structural relaxation in vitreous materials. Annals of the New York Academy of Sciences, 279, 15-35.
32. 2O in peralkaline aluminosilicate melts at high pressure with implications for properties of hydrous melts. Geochimica et Cosmochimica Acta, 71, 1820-1834.
33. 2O in coexisting silicate melts determined in-situ at high pressure and high temperature. Geochimica et Cosmochimica Acta, 73, 5748-5763.
34. 2O-saturated peralkaline aluminosilicate melt and coexisting aluminosilicate-saturated aqueous fluid determined in-situ to 800°C and ∼800 MPa. Geochimica et Cosmochimica Acta, 74, 4123-4139.
35. - (2012) High-pressure and high-temperature titanium solution mechanisms in silicate-saturated aqueous fluids and hydrous silicate melts. American Mineralogist, 97, 1241-1251.
36. - (2013a) Effects of fluid and melt density and structure on high pressure and temperature experimental studies of hydrogen isotope partitioning between coexisting melt and aqueous fluid. American Mineralogist, in press.
37. - (2013b) Hydrogen isotope fractionation between coexisting hydrous melt and silicate-saturated aqueous fluid: An experimental study in situ at high pressure and temperature. American Mineralogist, 98, 376-386.
38. Mysen, B. O., and Armstrong, L. (2002) Solubility behavior of alkali aluminosilicate components in aqueous fluids and silicate melts at high pressure and temperature. Geochimica et Cosmochimica Acta, 66, 2287-2297.
39. Mysen, B. O., and Fogel, M. L. (2010) Nitrogen and hydrogen isotope compositions and solubility in silicate melts in equilibrium with reduced (N+H)-bearing fluids at high pressure and temperature: Effects of melt structure. American Mineralogist, 95, 987-999.
40. Mysen, B. O., and Yamashita, S. (2010) Speciation of reduced C-O-H volatiles in coexisting fluids and silicate melts determined in-situ to ∼1.4 GPa and 800°C. Geochimica et Cosmochimica Acta, 74, 4577-4588.
41. Mysen, B. O., Virgo, D., and Seifert, F. A. (1982) The structure of silicate melts; implications for chemical and physical properties of natural magma. Reviews of Geophysics and Space Physics, 20, 353-383.
42. Mysen, B. O., Yamashita, S., and Chertkova, N. (2008) Solubility and solution mechanisms of NOH volatiles in silicate melts at high pressure and temperature-Amine groups and hydrogen fugacity. American Mineralogist, 93, 1760-1770.
43. Mysen, B. O., Fogel, M. L., Morrill, P. L., and Cody, G. D. (2009) Solution behavior of reduced C-O-H volatiles in silicate melts at high pressure and temperature. Geochimica et Cosmochimica Acta, 73, 1696-1710.
44. Mysen, B. O., Kumamoto, K., Cody, G. D., and Fogel, M. L. (2011) Solubility and solution mechanisms of C-O-H volatiles in silicate melt with variable redox conditions and melt composition at upper mantle temperatures and pressures. Geochimica et Cosmochimica Acta, 75, 6183-6199.
45. 2buffering mineral assemblages. Contributions to Mineralogy and Petrology, 146, 135-143.
46. Pascal, M. L., and Anderson, G. M. (1989) Speciation of Al, Si, and K in supercritical solutions: Experimental study and interpretation. Geochimica et Cosmochimica Acta, 53, 1843-1855.
47. 8, Geochimica et Cosmochimica Acta, 48, 453-471.
48. Roskosz, M., Mysen, B. O., and Cody, G. D. (2006) Dual speciation of nitrogen in silicate melts at high pressure and temperature: an experimental study. Geochimica et Cosmochimica Acta, 70, 2902-2918.
49. Saxena, S. K., and Fei, Y. (1987) High pressure and high temperature fluid fugacities. Geochimica et Cosmochimica Acta, 51, 783-791.
50. 2D in liquid NH3. Physical Chemistry Chemical Physics, 14, 11651-11656.
51. 12C isotope Raman pressure sensor system for high-temperature/pressure diamond-anvil cells with reactive samples. Journal of Applied Physics, 82, 3256-3265.
52. Socrates, G. (2001) Infrared and Raman Characteristic Group Frequencies-Tables and Charts, 3rd Ed., 347 p. Wiley, New York.
53. Stolen, R. H., and Walrafen, G. E. (1976) Water and its relation to broken bond defects in fused silica, Journal of Chemical Physics, 64, 2623-2631.
54. Tolstikhin, I. N., and Marty, B. (1998) The evolution of terrestrial volatiles: a view from helium, neon, argon and nitrogen isotope modeling. Chemical Geology, 147, 27-52.
55. O2 space: An experimental determination to 30 kbar and 1600°C. Contributions to Mineralogy and Petrology, 106, 265-272.
56. 2. Journal of Molecular Spectroscopy, 121, 401-419.
57. Walrafen, G. E., Fisher, M. R., Hokmabadi, M. S., and Yang, W. H. (1986) Temperature dependence of the low- and high-frequency Raman scattering from liquid water. Journal of Chemical Physics, 85, 6970-6982.
58. 2O between 22 and 152 °C. Journal of Physical Chemistry, 100, 1381-1391.
59. Wood, B. J., Bryndzia, L. T., and Johnson, K. E. (1990) Mantle oxidation state and its relationship to tectonic environment and fluid speciation. Science, 248, 337-345.
60. Yeo, G. A., and Ford, T. A. (1994) Ab initio molecular orbital calculations of the energetic, structural, vibrational and electronic properties of some hydrogen bonded complexes of water, ammonia and hydroxylamine. Spectrochimica Acta, 50 A, 5-18.
61. Zhang, Y.-G., and Frantz, J. D. (2000) Enstatite-forsterite-water equilibria at elevated temperatures and pressures. American Mineralogist, 85, 918-925.
62. Zotov, N., and Keppler, H. (2000) In-situ Raman spectra of dissolved silica species in aqueous fluid to 900 °C and 14 kbar. American Mineralogist, 85, 600-603.