Hydrogen-based technologies for mobile applications

Renewable Resources and Renewable Energy: A Global Challenge, Second Edition

Volumn , Issue , 2006, Pages 225-272

  Hickey, Neal ^a   Fornasiero, Paolo ^a   Graziani, Mauro ^a  

^a UNIVERSITY OF TRIESTE   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84901987777     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1201/b16003     Document Type: Chapter

References (200)

1. International Partnership for the Hydrogen Economy; available on-line at http://www.iphe.net, 2005.
2. Painter, D.E., Air Pollution Technology, Reston Publishing Co., Reston, VA, 1974.
3. De Nevers, N., Air Pollution Control Engineering, 2nd ed., McGraw-Hill, Boston, 2000.
4. Obuchi, A., et al., A practical scale evaluation of catalysts for the selective reduction of NOx with organic substances using a diesel exhaust, Appl. Catal. B, Environ., 15, 37, 1998.
5. Ciambelli, P., et al., Lean NOx reduction CuZSM5 catalysts: evaluation of performance at the spark ignition engine exhaust, Catal. Today, 26, 33, 1995.
6. Degobert, P., Automobiles and Pollution, Society of Automotive Engineers, Warrendale, PA, 1995.
7. Iwamoto, M., et al., Performance and durability of Pt-MFI zeolite catalyst for selective reduction of nitrogen monoxide in actual diesel engine exhaust, Appl. Catal. B, Environ., 5, L1, 1994.
8. The European Environmental Agency, Annual Report 2005. Available on-line at http://themes.eea.europa.eu.
9. Antia, A.N., et al., Basin-wide particulate carbon flux in the Atlantic Ocean: regional export patterns and potential for atmospheric CO2 sequestration, Global Biogeochemical Cycles, 15, 845, 2001.
10. Conte, M., et al., Hydrogen economy for a sustainable development: state-of-the-art and technological perspectives, J. Power Sources, 100, 171, 2001.
11. Kyoto Protocol to the United Nations Framework Convention on Climate Change. Available on-line at http://unfccc.int/resource/docs/convkp/kpeng.html, 2005.
12. Church, M.L., Cooper, B.J., and Willson, P.J., Catalyst Formulations 1960 to Present, SAE 890815, Society of Automotive Engineers, Warrendale, PA, 1989.
13. McCabe, R.W. and Kisenyi, J.M., Advances in automotive catalyst technology, Chem. Ind. (London), 15, 605, 1995.
14. Kaspar, J., Graziani, M., and Fornasiero, P., Ceria-containing three way catalysts, in Handbook on the Physics and Chemistry of Rare Earths: The Role of Rare Earths in Catalysis, Vol. 29, Gschneidner, Jr., K.A. and Eyring, L., Eds., Elsevier Science B.V., Amsterdam, 2000, chap. 184, pp. 159-267.
15. Kaspar, J., Fornasiero, P., and Hickey, N., Automotive catalytic converters: current status and some perspectives, Catal. Today, 77, 419, 2003.
16. Burch, R., Knowledge and know-how in emission control for mobile applications, Catalysis Reviews: Science Engineering, 46, 271, 2004.
17. Takahashi, N., et al., The new concept 3-way catalyst for automotive lean-burn engine: NOx storage and reduction catalyst, Catal. Today, 27, 63, 1996.
18. Shinjoh, H., et al., Effect of periodic operation over Pt catalysts in simulated oxidizing exhaust gas, Appl. Catal. B, Environ., 15, 189, 1998.
19. Farrauto, R.J. and Voss, K.E., Monolithic diesel oxidation catalysts, Appl. Catal. B, Environ., 10, 29, 1996.
20. van Setten, B.A.A.L., Makkee, M., and Moulijn, J.A., Science and technology of catalytic diesel particulate filters, Catal. Rev., Sci. Eng., 43, 489, 2001.
21. Amon, B., et al., The SINOx system for trucks to fulfil the future emission regulations, Top. Catal., 16, 187, 2001.
22. Guibet, J.C., Fuels and Engines, Editions Technip, Paris, 1999.
23. Tromp, T.K., et al., Potential environmental impact of a hydrogen economy on the stratosphere, Science, 300, 1740, 2003.
24. Prather, M.J., An environmental experiment with H2? Science, 302, 581, 2003.
25. Service, R.F., The hydrogen backlash, Science, 305, 958, 2004.
26. Schlapbach, L. and Zuttel, A., Hydrogen-storage materials for mobile applications, Nature, 414, 353, 2001.
27. McNicol, B.D., Rand, D.A.J., and Williams, K.R., Fuel cells for road transportation purposes: yes or no?, J. Power Sources, 100, 47, 2001.
28. Bain, A. and Van Vorst, W.D., The Hindenburg tragedy revisited: the fatal flaw found, Int. J. Hydrogen Energy, 24, 399, 1999.
29. Rostrup-Nielsen, J.R. and Rostrup-Nielsen T., Large-scale hydrogen production, CATTECH, 6, 150, 2002.
30. Pena, M.A., Gomez, J.P., and Fierro, J.L.G., New catalytic routes for syngas and hydrogen production, Appl. Catal. A Gen., 144, 7, 1996.
31. Freni, S., Calogero, G., and Cavallaro, S., Hydrogen production from methane through catalytic partial oxidation reactions, J. Power Sources, 87, 28, 2000.
32. Reyniers, M.F., et al., Catalytic partial oxidation, Part I: catalytic processes to convert methane: partial or total oxidation, CATTECH, 6, 140, 2002.
33. Edwards, N., et al., On-board hydrogen generation for transport applications: the HotSpot™ methanol processor, J. Power Sources, 71, 123, 1998.
34. Ghenciu, A.F., Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems, Curr. Opin. Solid St. M., 6, 389, 2002.
35. Farrauto, R., et al., New material needs for hydrocarbon fuel processing: generating hydrogen for the PEM fuel cell, Ann. Rev. Mater. Res., 33, 1, 2003.
36. Giroux, T., et al., Monolithic structures as alternatives to particulate catalysts for the reforming of hydrocarbons for hydrogen generation, Appl. Catal. B, Environ., 56, 95, 2005.
37. Wei, J.M. and Iglesia, E., Isotopic and kinetic assessment of the mechanism of methane reforming and decomposition reactions on supported iridium catalysts, Phys. Chem. Chem. Phys., 6, 3754, 2004.
38. Wei, J.M. and Iglesia, E., Isotopic and kinetic assessment of the mechanism of reactions of CH4 with CO2 or H2O to form synthesis gas and carbon on nickel catalysts, J. Catal., 224, 370, 2004.
39. Wei, J.M. and Iglesia, E., Mechanism and site requirements for activation and chemical conversion of methane on supported Pt clusters and turnover rate comparisons among noble metals, J. Phys. Chem. B, 108, 4094, 2004.
40. Wei, J.M. and Iglesia, E., Reaction pathways and site requirements for the activation and chemical conversion of methane on Ru-based catalysts, J. Phys. Chem. B, 108, 7253, 2004.
41. Wei, J.M. and Iglesia, E., Structural requirements and reaction pathways in methane activation and chemical conversion catalyzed by rhodium, J. Catal., 225, 116, 2004.
42. Hayakawa, T., et al., CO2 reforming of CH4 over Ni perovskite catalysts prepared by solid phase crystallization method, Appl. Catal. A, Gen., 183, 273, 1999.
43. Ashcroft, A.T., et al., Partial oxidation of methane to synthesis gas using carbon dioxide, Nature, 352, 225, 1991.
44. Song, C.S., Fuel processing for low-temperature and high-temperature fuel cells: challenges and opportunities for sustainable development in the 21st century, Catal. Today, 77, 17, 2002.
45. Liu, Q.S., et al., Progress in water-gas-shift catalysts, Prog. Chem., 17, 389, 2005.
46. Armor, J.N., The multiple roles for catalysis in the production of H2, Appl. Catal. A, Gen., 176, 159, 1999.
47. Gunardson, H., Industrial Gases in Petrochemical Processing, Marcel Dekker, New York, 1998.
48. Newsome, D.S., The water-gas shift reaction, Catal. Rev., Sci. Eng., 21, 275, 1980.
49. Liu, Q.S., et al., Progress in water-gas-shift catalysts, Prog. Chem., 17, 389, 2005.
50. Ahmed, S. and Krumpelt, M., Hydrogen from hydrocarbon fuels for fuel cells, Int. J. Hydrogen Energy, 26, 291, 2001.
51. Pettersson, L.J. and Westerholm, R., State of the art of multi-fuel reformers for fuel cell vehicles: problem identification and research needs, Int. J. Hydrogen Energy, 26, 243, 2001.
52. Moon, D.J., et al., Studies on gasoline fuel processor system for fuel-cell powered vehicles application, Appl. Catal. A, Gen., 215, 1, 2001.
53. York, A.P.E., Xiao, T.C., and Green, M.L.H., Brief overview of the partial oxidation of methane to synthesis gas, Top. Catal., 22, 345, 2003.
54. Tomishige, K., Chen, Y.G., and Fujimoto, K., Studies on carbon deposition in CO2 reforming of CH4 over nickel-magnesia solid solution catalysts, J. Catal., 181, 91, 1999.
55. Tsipouriari, V.A. and Verykios, X.E., Carbon and oxygen reaction pathways of CO2 reforming of methane over Ni/La2O3 and Ni/Al2O3 catalysts studied by isotopic tracing techniques, J. Catal., 187, 85, 1999.
56. Slagtern, A., et al., Specific features concerning the mechanism of methane reforming by carbon dioxide over Ni/La2O3 catalyst, J. Catal., 172, 118, 1997.
57. Hegarty, M.E.S., O’Connor, A.M., and Ross, J.R.H., Syngas production from natural gas using ZrO2-supported metals, Catal. Today, 42, 225, 1998.
58. Montoya, J.A., et al., Methane reforming with CO2 over Ni/ZrO2-CeO2 catalysts prepared by sol-gel, Catal. Today, 63, 71, 2000.
59. Roh, H.S., et al., Highly stable Ni catalyst supported on Ce-ZrO2 for oxy-steam reforming of methane, Catal. Lett., 74, 31, 2001.
60. Sharma, S., et al., Evidence for oxidation of ceria by CO2, J. Catal., 190, 199, 2000.
61. Wang, X. and Gorte, R.J., A study of steam reforming of hydrocarbon fuels on Pd/ceria, Appl. Catal. A, Gen., 224, 209, 2002.
62. Krumpelt, M., et al., Catalytic Autothermal Reforming, annual progress report, USDOE, Energy Efficiency and Renewable Energy, Office of Transportation Technologies, Washington, D.C., 2000, pp. 66-70.
63. Zarur, A.J. and Ying, J.Y., Reverse microemulsion synthesis of nanostructured complex oxides for catalytic combustion, Nature, 403, 65, 2000.
64. Groppi, G., Cristiani, C., and Forzatti, P., Preparation, characterisation and catalytic activity of pure and substituted La-hexaaluminate systems for high temperature catalytic combustion, Appl. Catal. B, Environ., 35, 137, 2001.
65. Schicks, J., et al., Nanoengineered catalysts for high-temperature methane partial oxidation, Catal. Today, 81, 287, 2003.
66. Chu, W.L., Yang, W.S., and Lin, L.W., The partial oxidation of methane to syngas over the nickel-modified hexaaluminate catalysts BaNiyAl12-yO19-delta, Appl. Catal. A, Gen., 235, 39, 2002.
67. Bartholomew, C.H., Carbon deposition in steam reforming and methanation, Catal. Rev., Sci. Eng., 1982, 67, 1982.
68. Swaan, H.M., et al., Deactivation of supported nickel-catalysts during the reforming of methane by carbon-dioxide, Catal. Today, 21, 571, 1994.
69. Basile, F., et al., New hydrotalcite-type anionic clays containing noble metals, Chem. Commun., 2435, 1996.
70. Basile, F., et al., Catalytic partial oxidation and CO2-reforming on Rh- and Ni-based catalysts obtained from hydrotalcite-type precursors, Appl. Clay Sci., 13, 329, 1998.
71. Shiozaki, R., et al., Partial oxidation of methane over a Ni/BaTiO3 catalyst prepared by solid phase crystallization, J. Chem. Soc., Faraday Trans., 93, 3235, 1997.
72. Takehira, K., et al., Autothermal reforming of CH4 over supported Ni catalysts prepared from Mg-Al hydrotalcite-like anionic clay, J. Catal., 221, 43, 2004.
73. Shishido, T., et al., CO2 reforming of CH4 over Ni/Mg-Al oxide catalysts prepared by solid phase crystallization method from Mg-Al hydrotalcite-like precursors, Catal. Lett., 73, 21, 2001.
74. Shishido, T., et al., Partial oxidation of methane over Ni/Mg-Al oxide catalysts prepared by solid phase crystallization method from Mg-Al hydrotalcite-like precursors, Appl. Catal. A, Gen., 223, 35, 2002.
75. Takehira, K., Shishido, T., and Kondo, M., Partial oxidation of CH4 over Ni/SrTiO3 catalysts prepared by a solid-phase crystallization method, J. Catal., 207, 307, 2002.
76. Raimondi, F., et al., Hydrogen production by methanol reforming: post-reaction characterisation of a Cu/ZnO/Al2O3 catalyst by XPS and TPD, Appl. Surf. Sci., 189, 59, 2002.
77. Peppley, B.A., et al., Methanol-steam reforming on Cu/ZnO/Al2O3, Part 1: the reaction network, Appl. Catal. A, Gen., 179, 21, 1999.
78. Turco, M., et al., Production of hydrogen from oxidative steam reforming of methanol, I: preparation and characterization of Cu/ZnO/Al2O3 catalysts from a hydrotalcitelike LDH precursor, J. Catal., 228, 43, 2004.
79. Turco, M., et al., Production of hydrogen from oxidative steam reforming of methanol, II: catalytic activity and reaction mechanism on Cu/ZnO/Al2O3 hydrotalcite-derived catalysts, J. Catal., 228, 56, 2004.
80. Breen, J.P. and Ross, J.R.H., Methanol reforming for fuel-cell applications: development of zirconia-containing Cu-Zn-Al catalysts, Catal. Today, 51, 521, 1999.
81. Velu, S., et al., Selective production of hydrogen for fuel cells via oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts, Appl. Catal. A, Gen., 213, 47, 2001.
82. Velu, S., Suzuki, K., and Osaki, T., Oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts; a new and efficient method for the production of COfree hydrogen for fuel cells, Chem. Commun., 2341, 1999.
83. Liu, S.T., et al., Hydrogen production by oxidative methanol reforming on Pd/ZnO, Appl. Catal. A, Gen., 283, 125, 2005.
84. Shabaker, J.W., et al., Aqueous-phase reforming of methanol and ethylene glycol over alumina-supported platinum catalysts, J. Catal., 215, 344, 2003.
85. Bi, Y.P., et al., Correlation of activity and size of Pt nanoparticles for methanol steam reforming over Pt/(Y)-Al2O3 catalysts, Acta Chimica Sinica, 63, 802, 2005.
86. Tsai, A.P. and Yoshimura, M., Highly active quasicrystalline Al-Cu-Fe catalyst for steam reforming of methanol, Appl. Catal. A, Gen., 214, 237, 2001.
87. Segal, S.R., et al., Low temperature steam reforming of methanol over layered double hydroxide-derived catalysts, Appl. Catal. A, Gen., 231, 215, 2002.
88. Akande, A., Idem, R.O., and Dalai, A.K., Synthesis, characterization and performance evaluation of Ni/Al2O3 catalysts for reforming of crude ethanol for hydrogen production, Appl. Catal. A, Gen., 287, 159, 2005.
89. Comas, J., et al., Bio-ethanol steam reforming on Ni/Al2O3 catalyst, Chem. Eng. J., 98, 61, 2004.
90. Diagne, C., et al., Efficient hydrogen production by ethanol reforming over Rh catalysts: effect of addition of Zr on CeO2 for the oxidation of CO to CO2, Comptes Rendus Chimie, 7, 617, 2004.
91. Fatsikostas, A.N. and Verykios, X.E., Reaction network of steam reforming of ethanol over Ni-based catalysts, J. Catal., 225, 439, 2004.
92. Fatsikostas, A.N., Kondarides, D.I., and Verykios, X.E., Steam reforming of biomassderived ethanol for the production of hydrogen for fuel cell applications, Chem. Commun., 851, 2001.
93. Klouz, V., et al., Ethanol reforming for hydrogen production in a hybrid electric vehicle: process optimisation, J. Power Sources, 105, 26, 2002.
94. Navarro, R.M., et al., Production of hydrogen by oxidative reforming of ethanol over Pt catalysts supported on Al2O3 modified with Ce and La, Appl. Catal. B, Environ., 55, 229, 2005.
95. Haga, F., et al., Catalytic properties of supported cobalt catalysts for steam reforming of ethanol, Catal. Lett., 48, 223, 1997.
96. Haga, F., et al., Effect of particle size on steam reforming of ethanol over aluminasupported cobalt catalyst, Nippon Kagaku Kaishi, 11, 758, 1997.
97. Patt, J., et al., Molybdenum carbide catalysts for water-gas shift, Catal. Lett., 65, 193, 2000.
98. Ruettinger, W., Ilinich, O., and Farrauto, R.J., A new generation of water gas shift catalysts for fuel cell applications, J. Power Sources, 118, 61, 2003.
99. Ruettinger, W., et al., Non-pyrophoric water-gas shift catalysts for hydrogen generation in fuel cell applications, Abstr. Pap. Am. Chem. Soc., 221, U494, 2001.
100. Li, K., Fu, Q., and Flytzani-Slephanopoulos, M., Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts, Appl. Catal. B, Environ., 27, 179, 2000.
101. Krause, T., et al., Water Gas Shift Catalysis, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, D.C., 2004.
102. Mendelovici, L. and Steinberg M., J. Catal., 96, 285, 1985.
103. Fu, Q., Saltsburg, H., and Flytzani-Stephanopoulos, M., Active nonmetallic Au and Pt species on ceria-based water-gas shift catalysts, Science, 301, 935, 2003.
104. Gorte, R.J. and Zhao, S., Studies of the water-gas-shift reaction with ceria-supported precious metals, Catal. Today, 104, 18, 2005.
105. Bunluesin, T., Gorte, R.J., and Graham, G.W., Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen-storage properties, Appl. Catal. B, Environ., 15, 107, 1998.
106. Swartz, S.L., et al., Fuel processing catalysts based on nanoscale ceria, Fuel Cell Bull., 30, 7, 2001.
107. Zalc, J.M., Sokolovskii, V., and Loffler, D.G., Are noble metal-based water-gas shift catalysts practical for automotive fuel processing? J. Catal., 206, 169, 2002.
108. Haruta, M., Yamada, N., Kobayashi, T., and Ijima, S., Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide, J. Catal., 115, 301, 1989.
109. Fu, Q., et al., Activity and stability of low-content gold-cerium oxide catalysts for the water-gas shift reaction, Appl. Catal. B, Environ., 56, 57, 2005.
110. Kim, C.H. and Thompson, L.T., Deactivation of Au/CeOx water gas shift catalysts, J. Catal., 230, 66, 2005.
111. Tabakova, T., et al., FTIR study of low-temperature water-gas shift reaction on gold/ceria catalyst, Appl. Catal. A, Gen., 252, 385, 2003.
112. Andreeva, D., et al., Low-temperature water-gas shift reaction over Au/CeO2 catalysts, Catal. Today, 72, 51, 2002.
113. Luengnaruemitchai, A., Osuwan, S., and Gulari, E., Comparative studies of lowtemperature water-gas shift reaction over Pt/CeO2, Au/CeO2, and Au/Fe2O3 catalysts, Catal. Commun., 4, 215, 2003.
114. Idakiev, V., et al., Gold catalysts supported on mesoporous titania for low-temperature water-gas shift reaction, Appl. Catal. A, Gen., 270, 135, 2004.
115. Panagiotopoulou, P. and Kondarides, D.I., Effect of morphological characteristics of TiO2-supported noble metal catalysts on their activity for the water-gas shift reaction, J. Catal., 225, 327, 2004.
116. Boccuzzi, F., et al., Gold, silver and copper catalysts supported on TiO2 for pure hydrogen production, Catal. Today, 75, 169, 2002.
117. Boccuzzi, F., et al., FTIR study of the low-temperature water-gas shift reaction on Au/Fe2O3 and Au/TiO2 catalysts, J. Catal., 188, 176, 1999.
118. Sakurai, H., et al., Low-temperature water-gas shift reaction over gold deposited on TiO2, Chem. Commun., 271, 1997.
119. Andreeva, D., et al., Au/alpha-Fe2O3 catalyst for water-gas shift reaction prepared by deposition-precipitation, Appl. Catal. A, Gen., 169, 9, 1998.
120. Andreeva, D., et al., Low-temperature water-gas shift reaction on Au/alpha-Fe2O3 catalyst, Appl. Catal. A, Gen., 134, 275, 1996.
121. Andreeva, D., et al., Low-temperature water-gas shift reaction over Au/alpha-Fe2O3, J. Catal., 158, 354, 1996.
122. Venugopal, A. and Scurrell, M.S., Low temperature reductive pretreatment of Au/Fe2O3 catalysts, TPR/TPO studies and behaviour in the water-gas shift reaction, Appl. Catal. A, Gen., 258, 241, 2004.
123. Daniells, S.T., Makkee, M., and Moulijn, J.A., The effect of high-temperature pretreatment and water on the low temperature CO oxidation with Au/Fe2O3 catalysts, Catal. Lett., 100, 39, 2005.
124. Farrauto, R.J., Introduction to solid polymer membrane fuel cells and reforming natural gas for production of hydrogen, Appl. Catal. B, Environ., 56, 3, 2005.
125. Rossignol, C., et al., Selective oxidation of CO over model gold-based catalysts in the presence of H2, J. Catal., 230, 476, 2005.
126. Marino, F., Descorme, C., and Duprez, D., Noble metal catalysts for the preferential oxidation of carbon monoxide in the presence of hydrogen (PROX), Appl. Catal. B, Environ., 54, 59, 2004.
127. Panzera, G., et al., CO selective oxidation on ceria-supported Au catalysts for fuel cell application, J. Power Sources, 135, 177, 2004.
128. Schumacher, B., et al., Kinetics, mechanism, and the influence of H2 on the CO oxidation reaction on a Au/TiO2 catalyst, J. Catal., 224, 449, 2004.
129. Shin, W.S., et al., Development of Au/Ce catalysts for preferential oxidation of CO in PEMFC, J. Ind. Eng. Chem., 10, 302, 2004.
130. Luengnaruemitchai, A., Osuwan, S., and Gulari, E., Selective catalytic oxidation of CO in the presence of H2 over gold catalyst, Int. J. Hydrogen Energy, 29, 429, 2004.
131. Schubert, M.M., et al., Influence of H2O and CO2 on the selective CO oxidation in H2-rich gases over Au/alpha-Fe2O3, J. Catal., 222, 32, 2004.
132. Cameron, D., Holliday, R., and Thompson, D., Gold’s future role in fuel cell systems, J. Power Sources, 118, 298, 2003.
133. Choudhary, T.V., et al., CO oxidation on supported nano-Au catalysts synthesized from a [Au6(PPh3)(6)](BF4)(2) complex, J. Catal., 207, 247, 2002.
134. Schubert, M.M., et al., Activity, selectivity, and long-term stability of different metal oxide supported gold catalysts for the preferential CO oxidation in H2-rich gas, Catal. Lett., 76, 143, 2001.
135. Avgouropoulos G., et al., CuO-CeO2 mixed oxide catalysts for the selective oxidation of carbon monoxide in excess hydrogen, Catal. Lett., 73, 33, 2001.
136. Avgouropoulos, G., et al., A comparative study of Pt/gamma-Al2O3, Au/alpha-Fe2O3 and CuO-CeO2 catalysts for the selective oxidation of carbon monoxide in excess hydrogen, Catal. Today, 75, 157, 2002.
137. Joensen, F. and Rostrup-Nielsen, J.R., Conversion of hydrocarbons and alcohols for fuel cells, J. Power Sources, 105, 195, 2002.
138. The U.S. Department of Energy, Website. U.S. Department of Energy; available online at www.doe.gov, 2005.
139. Wolf, A. and Schuth, F., A systematic study of the synthesis conditions for the preparation of highly active gold catalysts, Appl. Catal A, Gen., 226, 1, 2002.
140. Aceves, S.M., Perfect, S., and Weisberg, A., Optimum utilization of available space in a vehicle through conformable hydrogen vessels, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, D.C., 2004.
141. Weisberg, A., Next-generation physical hydrogen, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, D.C., 2004.
142. Wolf, J., Liquid-hydrogen technology for vehicles, MRS Bull., 27, 684, 2002.
143. Schuth, F., Bogdanovic, B., and Felderhoff, M., Light metal hydrides and complex hydrides for hydrogen storage, Chem. Commun., 2249, 2004.
144. Darkrim, F.L., Malbrunot, P., and Tartaglia, G.P., Review of hydrogen storage by adsorption in carbon nanotubes, Int. J. Hydrogen Energy, 27, 193, 2002.
145. Zuttel, A., et al., Hydrogen storage in carbon nanostructures, Int. J. Hydrogen Energy, 27, 203, 2002.
146. Ajayan, P.M. and Ebbesen, T.W., Nanometre-size tubes of carbon, Rep. Prog. Phys., 60, 1025, 1997.
147. Ajayan, P.M., Carbon nanotubes: novel architecture in nanometer space, Prog. Crystal Growth Characterization Mater., 34, 37, 1997.
148. Dresselhaus, M.S., et al., Graphite Fibres and Filaments, Springer, Berlin, 1998.
149. Hirscher, M., et al., Hydrogen storage in carbon nanostructures, J. Alloys Comp., 330, 654, 2002.
150. Iijima, S., Helical microtubules of graphitic carbon, Nature, 354, 56, 1991.
151. Dillon, A.C., et al., Storage of hydrogen in single-walled carbon nanotubes, Nature, 386, 377, 1997.
152. Chambers, A., et al., Hydrogen storage in graphite nanofibers, J. Phys. Chem. B, 102, 4253, 1998.
153. Chen, P., et al., Interaction of hydrogen with metal nitrides and imides, Nature, 420, 302, 2002.
154. Gupta, B.K. and Srivastava, O.N., Further studies on microstructural characterization and hydrogenation behaviour of graphitic nanofibres, Int. J. Hydrogen Energy, 26, 857, 2001.
155. Ye, Y., et al., Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes, Appl. Phys. Lett., 74, 2307, 1999.
156. Fan, Y.Y., et al., Hydrogen uptake in vapor-grown carbon nanofibers, Carbon, 37, 1649, 1999.
157. Orimo, S., et al., Hydrogen desorption property of mechanically prepared nanostructured graphite, J. Appl. Phys., 90, 1545, 2001.
158. Orimo, S., et al., Hydrogen in the mechanically prepared nanostructured graphite, Appl. Phys. Lett., 75, 3093, 1999.
159. Ahn, C.C., et al., Hydrogen desorption and adsorption measurements on graphite nanofibers, Appl. Phys. Lett., 73, 3378, 1998.
160. Tibbetts, G.G., Meisner, G.P., and Olk, C.H., Hydrogen storage capacity of carbon nanotubes, filaments, and vapor-grown fibers, Carbon, 39, 2291, 2001.
161. Shiraishi, M., Takenobu, T., and Ata, M., Gas-solid interactions in the hydrogen/single- walled carbon nanotube system, Chem. Phys. Lett., 367, 633, 2003.
162. Strobel, R., et al., Hydrogen adsorption on carbon materials, J. Power Sources, 84, 221, 1999.
163. Schimmel, H.G., et al., Hydrogen adsorption in carbon nanostructures: comparison of nanotubes, fibers, and coals, Chem-Eur. J., 9, 4764, 2003.
164. Yang, R.T., Hydrogen storage by alkali-doped carbon nanotubes-revisited, Carbon, 38, 623, 2000.
165. Hirscher, M., et al., Hydrogen storage in sonicated carbon materials, Appl. Phys. A, Mater. Sci. Process., 72, 129, 2001.
166. Dillon, A.C. and Heben, M.J., Hydrogen storage using carbon adsorbents: past, present and future, Appl. Phys. A, Mater. Sci. Process., 72, 133, 2001.
167. Cheng, H., Pez, G.P., and Cooper, A.C., Mechanism of hydrogen sorption in singlewalled carbon nanotubes, J. Am. Chem. Soc., 123, 5845, 2001.
168. Fakioglu, E., Yurum, Y., and Veziroglu, T.N., A review of hydrogen storage systems based on boron and its compounds, Int. J. Hydrogen Energy, 29, 1371, 2004.
169. Chen, J. and Wu, F., Review of hydrogen storage in inorganic fullerene-like nanotubes, Appl. Phys. A, Mater. Sci. Process., 78, 989, 2004.
170. Rosi, N.L., et al., Hydrogen storage in microporous metal-organic frameworks, Science, 300, 1127, 2003.
171. Kesanli, B., et al., Highly interpenetrated metal-organic frameworks for hydrogen storage, Angewandte Chemie-International Edition, 44, 72, 2005.
172. Panella, B. and Hirscher, M., Hydrogen physisorption in metal-organic porous crystals, Adv. Mater., 17, 538, 2005.
173. Zhou, L., Progress and problems in hydrogen storage methods, Renew. Sust. Energy Rev., 9, 395, 2005.
174. Sandrock, G., A panoramic overview of hydrogen storage alloys from a gas reaction point of view, J. Alloys Comp., 295, 877, 1999.
175. Grochala, W. and Edwards, P.P., Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen, Chem. Rev., 104, 1283, 2004.
176. Zuttel, A., et al., Hydrogen storage properties of LiBH4, J. Alloys Comp., 356, 515, 2003.
177. Zuttel, A., et al., LiBH4: a new hydrogen storage material, J. Power Sources, 118, 1, 2003.
178. Bogdanovic, B. and Schwickardi, M., Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials, J. Alloys Comp., 253, 1, 1997.
179. Zaluska, A., Zaluski, L., and Strom-Olsen, J.O., Sodium alanates for reversible hydrogen storage, J. Alloys Comp., 298, 125, 2000.
180. Gross, K.J., Thomas, G.J., and Jensen, C.M., Catalyzed alanates for hydrogen storage, J. Alloys Comp., 330, 683, 2002.
181. Sandrock, G., Gross, K., and Thomas, G., Effect of Ti-catalyst content on the reversible hydrogen storage properties of the sodium alanates, J. Alloys Comp., 339, 299, 2002.
182. Anton, D.L., Hydrogen desorption kinetics in transition metal modified NaAlH4, J. Alloys Comp., 356, 400, 2003.
183. Bogdanovic, B. and Sandrock, G., Catalyzed complex metal hydrides, MRS Bull., 27, 712, 2002.
184. Johnson, S.R., et al., Chemical activation of MgH2: a new route to superior hydrogen storage materials, Chem. Commun., 2823, 2005.
185. Ichikawa, T., et al., Lithium nitride for reversible hydrogen storage, J. Alloys Comp., 365, 271, 2004.
186. Kojima, Y., et al., Compressed hydrogen generation using chemical hydride, J. Power Sources, 135, 36, 2004.
187. Kojima, Y., et al., Hydrogen generation by hydrolysis reaction of lithium borohydride, Int. J. Hydrogen Energy, 29, 1213, 2004.
188. Kojima, Y., et al., Development of 10 kW-scale hydrogen generator using chemical hydride, J. Power Sources, 125, 22, 2004.
189. Kojima, Y., et al., Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide, Int. J. Hydrogen Energy, 27, 1029, 2002.
190. Schlesinger, H.I., et al., Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen, J. Am. Chem. Soc., 75, 215, 1953.
191. Wu, Y., Kelly, M.T., and Ortega, J.V., Low-Cost, off-board regeneration of sodium borohydride, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, DC, 2005.
192. Wilding, B., et al., Hydrogen storage: radiolysis for borate regeneration, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, DC, 2005.
193. Cooper, A., et al., Design and development of new carbon-based sorbent systems for an effective containment of hydrogen, DOE Hydrogen Program, FY 2004 Progress Report, U.S. Department of Energy, Washington, DC, 2004.
194. Jensen, C.M., et al., Catalytically enhanced systems for hydrogen storage, in Proceedings of the 2002 U.S. DOE Hydrogen Program Review, U.S. Department of Energy, Washington, DC, 2002.
195. Cho, A., Fire and ICE: revving up for H2, Science, 305, 964, 2004.
196. Grove, W.R., On voltaic series and the combination of gases by platinum, Philos. Mag., 14, 127, 1839.
197. Kordesch, K. and Simader, G., Fuel cell powered electric vehicles, chap. 7 in Fuel Cells and Their Applications, VCH, Weinheim, 1996.
198. Mauritz, K.A. and Moore, R.B., State of understanding of Nafion®, Chem. Rev., 104, 4535, 2004.
199. Hickner, M.A., et al., Alternative polymer systems for proton exchange membranes (PEMs), Chem. Rev., 104, 4587, 2004.
200. Demirdoven, N. and Deutch, J., Hybrid cars now, fuel cell cars later, Science, 305, 974, 2004.