메뉴 건너뛰기




Volumn 18, Issue 5, 2014, Pages 1205-1213

Spectroscopic elucidation of reaction pathways of acetaldehyde on platinum and palladium in acidic media

Author keywords

Acetaldehyde; DEMS; In situ FTIRS; Palladium; Platinum

Indexed keywords

CARBON DIOXIDE; CYCLIC VOLTAMMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MASS SPECTROMETRY; METHANE; PALLADIUM; PLATINUM;

EID: 84901623138     PISSN: 14328488     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10008-013-2283-0     Document Type: Article
Times cited : (9)

References (39)
  • 1
    • 34249309227 scopus 로고    scopus 로고
    • Catalysts for direct ethanol fuel cells
    • 1:CAS:528:DC%2BD2sXmtVSrtLw%3D 10.1016/j.jpowsour.2007.04.009
    • Antolini E (2007) Catalysts for direct ethanol fuel cells. J Power Sources 170(1):1-12
    • (2007) J Power Sources , vol.170 , Issue.1 , pp. 1-12
    • Antolini, E.1
  • 2
    • 1542304757 scopus 로고    scopus 로고
    • International activities in DMFC R&D: Status of technologies and potential applications
    • 1:CAS:528:DC%2BD2cXhvVGktbg%3D 10.1016/j.jpowsour.2003.09.032
    • Dillon R, Srinivasan S, Aricò AS, Antonucci V (2004) International activities in DMFC R&D: status of technologies and potential applications. J Power Sources 127(1-2):112-126
    • (2004) J Power Sources , vol.127 , Issue.1-2 , pp. 112-126
    • Dillon, R.1    Srinivasan, S.2    Aricò, A.S.3    Antonucci, V.4
  • 3
    • 0028404065 scopus 로고
    • A DEMS and FTIR spectroscopic investigation of adsorbed ethanol on polycrystalline platinum
    • 1:CAS:528:DyaK2cXksFKru7g%3D 10.1016/0013-4686(94)80097-9
    • Iwasita T, Pastor E (1994) A DEMS and FTIR spectroscopic investigation of adsorbed ethanol on polycrystalline platinum. Electrochim Acta 39(4):531-537
    • (1994) Electrochim Acta , vol.39 , Issue.4 , pp. 531-537
    • Iwasita, T.1    Pastor, E.2
  • 4
    • 0028404329 scopus 로고
    • D/H exchange of ethanol at platinum electrodes
    • 1:CAS:528:DyaK2cXitVarsb0%3D 10.1016/0013-4686(94)80099-5
    • Pastor E, Iwasita T (1994) D/H exchange of ethanol at platinum electrodes. Electrochim Acta 39(4):547-551
    • (1994) Electrochim Acta , vol.39 , Issue.4 , pp. 547-551
    • Pastor, E.1    Iwasita, T.2
  • 5
    • 84869478368 scopus 로고    scopus 로고
    • Quantitative DEMS study of ethanol oxidation: Effect of surface structure and Sn surface modification
    • 1:CAS:528:DC%2BC38Xhs1ajs7vE 10.1039/c2cp42520c
    • Mostafa E, Abd-El-Latif AEAA, Ilsley R, Attard G, Baltruschat H (2012) Quantitative DEMS study of ethanol oxidation: effect of surface structure and Sn surface modification. Phys Chem Chem Phys 14(46):16115-16129
    • (2012) Phys Chem Chem Phys , vol.14 , Issue.46 , pp. 16115-16129
    • Mostafa, E.1    Abd-El-Latif, A.2    Ilsley, R.3    Attard, G.4    Baltruschat, H.5
  • 6
    • 34548669594 scopus 로고    scopus 로고
    • Electrooxidations of ethanol, acetaldehyde and acetic acid using PtRuSn/C catalysts prepared by modified alcohol-reduction process
    • 1:CAS:528:DC%2BD2sXhtVKqsr7K 10.1016/j.jpowsour.2007.07.034
    • Wu G, Swaidan R, Cui G (2007) Electrooxidations of ethanol, acetaldehyde and acetic acid using PtRuSn/C catalysts prepared by modified alcohol-reduction process. J Power Sources 172(1):180-188
    • (2007) J Power Sources , vol.172 , Issue.1 , pp. 180-188
    • Wu, G.1    Swaidan, R.2    Cui, G.3
  • 7
    • 84877041588 scopus 로고    scopus 로고
    • Reaction intermediates of ethanol electro-oxidation on platinum investigated by SFG spectroscopy
    • 1:CAS:528:DC%2BC3sXmvV2msrk%3D 10.1016/j.jcat.2013.02.024
    • Gomes JF, Bergamaski K, Pinto MFS, Miranda PB (2013) Reaction intermediates of ethanol electro-oxidation on platinum investigated by SFG spectroscopy. J Catal 302:67-82
    • (2013) J Catal , vol.302 , pp. 67-82
    • Gomes, J.F.1    Bergamaski, K.2    Pinto, M.F.S.3    Miranda, P.B.4
  • 10
    • 0001747496 scopus 로고
    • Dissociative adsorption of acetaldehyde on Pt(h, k, l) basal surfaces
    • 1:CAS:528:DyaK3cXktFels7o%3D 10.1016/0022-0728(90)87047-N
    • Cases F, Vázquez JL, Pérez JM, Aldaz A, Clavilier J (1990) Dissociative adsorption of acetaldehyde on Pt(h, k, l) basal surfaces. J Electroanal Chem 281(1-2):283-288
    • (1990) J Electroanal Chem , vol.281 , Issue.1-2 , pp. 283-288
    • Cases, F.1    Vázquez, J.L.2    Pérez, J.M.3    Aldaz, A.4    Clavilier, J.5
  • 11
    • 0041923699 scopus 로고
    • The behaviour of a platinized-platinum electrode in solutions of alcohols containing more than one carbon atom, aldehydes and formic acid
    • 1:CAS:528:DyaF28XjtlSrtA%3D%3D 1959
    • Podlovchenko BI, Petry OA, Frumkin AN, Lal H (1966) The behaviour of a platinized-platinum electrode in solutions of alcohols containing more than one carbon atom, aldehydes and formic acid. J Electroanal Chem 11(1):12-25, 1959
    • (1966) J Electroanal Chem , vol.11 , Issue.1 , pp. 12-25
    • Podlovchenko, B.I.1    Petry, O.A.2    Frumkin, A.N.3    Lal, H.4
  • 12
    • 0000475502 scopus 로고
    • The electrochemical adsorption and oxidation of acetaldehyde on polycrystalline platinum in acidic solution-A SNIFTIRS study
    • 1:CAS:528:DyaK3cXks1Ogsbo%3D 10.1016/0013-4686(90)90032-U
    • Rasch B, Iwasita T (1990) The electrochemical adsorption and oxidation of acetaldehyde on polycrystalline platinum in acidic solution-A SNIFTIRS study. Electrochim Acta 35(6):989-993
    • (1990) Electrochim Acta , vol.35 , Issue.6 , pp. 989-993
    • Rasch, B.1    Iwasita, T.2
  • 13
    • 0343006693 scopus 로고    scopus 로고
    • Reaction intermediates of acetaldehyde oxidation on Pt(111) and Pt(100). An in situ FTIR study
    • 10.1021/la9911887
    • Rodríguez JL, Pastor E, Xia XH, Iwasita T (2000) Reaction intermediates of acetaldehyde oxidation on Pt(111) and Pt(100). An in situ FTIR study. Langmuir 16(12):5479-5486
    • (2000) Langmuir , vol.16 , Issue.12 , pp. 5479-5486
    • Rodríguez, J.L.1    Pastor, E.2    Xia, X.H.3    Iwasita, T.4
  • 14
    • 33846411428 scopus 로고    scopus 로고
    • Acetaldehyde electrooxidation: The influence of concentration on the yields of parallel pathways
    • 1:CAS:528:DC%2BD2sXpslGhsA%3D%3D 10.1016/j.jelechem.2006.10.009
    • Farias MJS, Camara GA, Tanaka AA, Iwasita T (2007) Acetaldehyde electrooxidation: the influence of concentration on the yields of parallel pathways. J Electroanal Chem 600(2):236-242
    • (2007) J Electroanal Chem , vol.600 , Issue.2 , pp. 236-242
    • Farias, M.J.S.1    Camara, G.A.2    Tanaka, A.A.3    Iwasita, T.4
  • 15
    • 0037084324 scopus 로고    scopus 로고
    • Reactivity of acetaldehyde at platinum and rhodium in acidic media. A DEMS study
    • 1:CAS:528:DC%2BD38XhsV2lsb4%3D 10.1016/S0013-4686(01)00878-7
    • Silva-Chong J, Méndez E, Rodríguez JL, Arévalo MC, Pastor E (2002) Reactivity of acetaldehyde at platinum and rhodium in acidic media. A DEMS study. Electrochim Acta 47(9):1441-1449
    • (2002) Electrochim Acta , vol.47 , Issue.9 , pp. 1441-1449
    • Silva-Chong, J.1    Méndez, E.2    Rodríguez, J.L.3    Arévalo, M.C.4    Pastor, E.5
  • 16
    • 84856395679 scopus 로고    scopus 로고
    • Electrooxidation of acetaldehyde on a carbon supported Pt catalyst at elevated temperature/pressure: An on-line differential electrochemical mass spectrometry study
    • 1:CAS:528:DC%2BC38XhtlKnu7g%3D 10.1016/j.jpowsour.2011.12.024
    • Sun S, Heinen M, Jusys Z, Behm RJ (2012) Electrooxidation of acetaldehyde on a carbon supported Pt catalyst at elevated temperature/pressure: an on-line differential electrochemical mass spectrometry study. J Power Sources 204:1-13
    • (2012) J Power Sources , vol.204 , pp. 1-13
    • Sun, S.1    Heinen, M.2    Jusys, Z.3    Behm, R.J.4
  • 17
    • 0038787029 scopus 로고    scopus 로고
    • Adsorption and reaction of acetaldehyde on Pt(1 1 1) and Sn/Pt(1 1 1) surface alloys
    • 1:CAS:528:DC%2BD3sXltFOqs7o%3D 10.1016/S0039-6028(03)00602-2
    • Zhao H, Kim J, Koel BE (2003) Adsorption and reaction of acetaldehyde on Pt(1 1 1) and Sn/Pt(1 1 1) surface alloys. Surf Sci 538(3):147-159
    • (2003) Surf Sci , vol.538 , Issue.3 , pp. 147-159
    • Zhao, H.1    Kim, J.2    Koel, B.E.3
  • 18
    • 20544467711 scopus 로고    scopus 로고
    • Acetaldehyde on Pt(111) and Pt/Sn(111): A DFT study of the adsorption structures and of the vibrational spectra
    • 1:CAS:528:DC%2BD2MXjvValsbk%3D 10.1021/jp045207j
    • Delbecq F, Vigné F (2005) Acetaldehyde on Pt(111) and Pt/Sn(111): a DFT study of the adsorption structures and of the vibrational spectra. J Phys Chem B 109(21):10797-10806
    • (2005) J Phys Chem B , vol.109 , Issue.21 , pp. 10797-10806
    • Delbecq, F.1    Vigné, F.2
  • 19
    • 63149156792 scopus 로고    scopus 로고
    • DEMS analysis of small organic molecule electrooxidation: A high-temperature high-pressure DEMS study
    • 1:CAS:528:DC%2BD1MXisFKgtQ%3D%3D 10.1149/1.2981965 PART 2
    • Jusys Z, Behm RJ (2008) DEMS analysis of small organic molecule electrooxidation: a high-temperature high-pressure DEMS study. ECS Trans 16(2 PART 2):1243-1251
    • (2008) ECS Trans , vol.16 , Issue.2 , pp. 1243-1251
    • Jusys, Z.1    Behm, R.J.2
  • 21
    • 57949089648 scopus 로고    scopus 로고
    • Mechanism of the dissociation and electrooxidation of ethanol and acetaldehyde on platinum as studied by SERS
    • 1:CAS:528:DC%2BD1cXhtlGku7bN 10.1021/jp807350h
    • Lai SCS, Kleyn SEF, Rosca V, Koper MTM (2008) Mechanism of the dissociation and electrooxidation of ethanol and acetaldehyde on platinum as studied by SERS. J Phys Chem C 112(48):19080-19087
    • (2008) J Phys Chem C , vol.112 , Issue.48 , pp. 19080-19087
    • Lai, S.C.S.1    Kleyn, S.E.F.2    Rosca, V.3    Koper, M.T.M.4
  • 22
    • 55049132044 scopus 로고    scopus 로고
    • Electro-oxidation of ethanol and acetaldehyde on platinum single-crystal electrodes
    • 1:CAS:528:DC%2BD1cXht12rtb7L 10.1039/b803711f
    • Lai SCS, Koper MTM (2008) Electro-oxidation of ethanol and acetaldehyde on platinum single-crystal electrodes. Faraday Discuss 140:399-416
    • (2008) Faraday Discuss , vol.140 , pp. 399-416
    • Lai, S.C.S.1    Koper, M.T.M.2
  • 23
    • 0035925376 scopus 로고    scopus 로고
    • Kinetic studies of acetaldehyde oxidation over Pt/Rh and Pd monolithic catalysts in a spinning-basket flow reactor
    • 1:CAS:528:DC%2BD3MXht1CksLc%3D 10.1021/ie000557n
    • Liakopoulos C, Poulopoulos S, Philippopoulos C (2001) Kinetic studies of acetaldehyde oxidation over Pt/Rh and Pd monolithic catalysts in a spinning-basket flow reactor. Ind Eng Chem Res 40(6):1476-1481
    • (2001) Ind Eng Chem Res , vol.40 , Issue.6 , pp. 1476-1481
    • Liakopoulos, C.1    Poulopoulos, S.2    Philippopoulos, C.3
  • 24
    • 2442612123 scopus 로고    scopus 로고
    • Ethanol and acetaldehyde adsorption on a carbon-supported Pt catalyst: A comparative DEMS study
    • 1:CAS:528:DC%2BD2cXjvFCjs7w%3D 10.1002/fuce.200400014
    • Wang H, Jusys Z, Behm RJ (2004) Ethanol and acetaldehyde adsorption on a carbon-supported Pt catalyst: a comparative DEMS study. Fuel Cells 4(1-2):113-125
    • (2004) Fuel Cells , vol.4 , Issue.1-2 , pp. 113-125
    • Wang, H.1    Jusys, Z.2    Behm, R.J.3
  • 25
    • 33749341622 scopus 로고    scopus 로고
    • 3Sn and unsupported PtRu0.2 catalysts: A quantitative DEMS study
    • 1:CAS:528:DC%2BD28XhtVWhsr%2FE 10.1007/s10800-006-9174-3
    • 3Sn and unsupported PtRu0.2 catalysts: a quantitative DEMS study. J Appl Electrochem 36(11):1187-1198
    • (2006) J Appl Electrochem , vol.36 , Issue.11 , pp. 1187-1198
    • Wang, H.1    Jusys, Z.2    Behm, R.J.3
  • 26
    • 0037022512 scopus 로고    scopus 로고
    • Comparative study of ethanol and acetaldehyde reactivities on rhodium electrodes in acidic media
    • 10.1021/la010747i
    • Méndez E, Rodríguez JL, Arévalo MC, Pastor E (2002) Comparative study of ethanol and acetaldehyde reactivities on rhodium electrodes in acidic media. Langmuir 18(3):763-772
    • (2002) Langmuir , vol.18 , Issue.3 , pp. 763-772
    • Méndez, E.1    Rodríguez, J.L.2    Arévalo, M.C.3    Pastor, E.4
  • 27
    • 40249114771 scopus 로고    scopus 로고
    • DEMS study on the nature of acetaldehyde adsorbates at Pt and Pd by isotopic labelling
    • 1:CAS:528:DC%2BD1cXis1GltLg%3D 10.1007/s10008-007-0341-1
    • Silva-Chong JA, Guillén-Villafuerte O, Rodríguez JL, Pastor E (2008) DEMS study on the nature of acetaldehyde adsorbates at Pt and Pd by isotopic labelling. J Solid State Electrochem 12(5):517-522
    • (2008) J Solid State Electrochem , vol.12 , Issue.5 , pp. 517-522
    • Silva-Chong, J.A.1    Guillén-Villafuerte, O.2    Rodríguez, J.L.3    Pastor, E.4
  • 28
    • 0021196805 scopus 로고
    • Differential electrochemical mass spectrometry (DEMS) - A new method for the study of electrode processes
    • 1:CAS:528:DyaL2cXhs1Oitrs%3D 10.1002/bbpc.19840880103
    • Wolter O, Heitbaum J (1984) Differential electrochemical mass spectrometry (DEMS) - a new method for the study of electrode processes. Ber Bunsenges Phys Chem Chem Phys 88(1):2-6
    • (1984) Ber Bunsenges Phys Chem Chem Phys , vol.88 , Issue.1 , pp. 2-6
    • Wolter, O.1    Heitbaum, J.2
  • 30
    • 0031198346 scopus 로고    scopus 로고
    • In situ infrared spectroscopy at electrochemical interfaces
    • 1:CAS:528:DyaK1cXhs1Wlu78%3D 10.1016/S0079-6816(97)00032-4
    • Iwasita T, Nart VFC (1997) In situ infrared spectroscopy at electrochemical interfaces. Prog Surf Sci 55(4):271-340
    • (1997) Prog Surf Sci , vol.55 , Issue.4 , pp. 271-340
    • Iwasita, T.1    Nart, V.F.C.2
  • 31
    • 79957820415 scopus 로고    scopus 로고
    • Ab initio molecular dynamics investigation of the coadsorption of acetaldehyde and hydrogen on a platinum nanocluster
    • 1:CAS:528:DC%2BC3MXlslKjs7o%3D 10.1021/jp200179g
    • Vargas A, Santarossa G, Baiker A (2011) Ab initio molecular dynamics investigation of the coadsorption of acetaldehyde and hydrogen on a platinum nanocluster. J Phys Chem C 115(21):10661-10667
    • (2011) J Phys Chem C , vol.115 , Issue.21 , pp. 10661-10667
    • Vargas, A.1    Santarossa, G.2    Baiker, A.3
  • 32
    • 33845238954 scopus 로고    scopus 로고
    • Ethanol oxidation on carbon supported Pt-Sn electrocatalysts prepared by reduction with formic acid
    • 1:CAS:528:DC%2BD2sXht1yisg%3D%3D 10.1149/1.2382349
    • Colmati F, Antolini E, Gonalez ER (2007) Ethanol oxidation on carbon supported Pt-Sn electrocatalysts prepared by reduction with formic acid. J Electrochem Soc 154(1):B39-B47
    • (2007) J Electrochem Soc , vol.154 , Issue.1
    • Colmati, F.1    Antolini, E.2    Gonalez, E.R.3
  • 33
    • 0037180038 scopus 로고    scopus 로고
    • Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes. A study using DEMS and in-situ FTIR techniques
    • 10.1021/jp014645c
    • De Souza JPI, Queiroz SL, Bergamaski K, Gonzalez ER, Nart FC (2002) Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes. A study using DEMS and in-situ FTIR techniques. J Phys Chem B 106(38):9825-9830
    • (2002) J Phys Chem B , vol.106 , Issue.38 , pp. 9825-9830
    • De Souza, J.P.I.1    Queiroz, S.L.2    Bergamaski, K.3    Gonzalez, E.R.4    Nart, F.C.5
  • 34
    • 33744979019 scopus 로고    scopus 로고
    • Direct ethanol fuel cell (DEFC): Electrical performances and reaction products distribution under operating conditions with different platinum-based anodes
    • 1:CAS:528:DC%2BD28XlvFanu74%3D 10.1016/j.jpowsour.2005.08.027
    • Rousseau S, Coutanceau C, Lamy C, Léger JM (2006) Direct ethanol fuel cell (DEFC): electrical performances and reaction products distribution under operating conditions with different platinum-based anodes. J Power Sources 158(1):18-24
    • (2006) J Power Sources , vol.158 , Issue.1 , pp. 18-24
    • Rousseau, S.1    Coutanceau, C.2    Lamy, C.3    Léger, J.M.4
  • 35
    • 0742268405 scopus 로고    scopus 로고
    • On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: Electrochemical and in situ IR reflectance spectroscopy studies
    • 1:CAS:528:DC%2BD2cXotlWktg%3D%3D 10.1016/j.jelechem.2003.08.019
    • Vigier F, Coutanceau C, Hahn F, Belgsir EM, Lamy C (2004) On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies. J Electroanal Chem 563(1):81-89
    • (2004) J Electroanal Chem , vol.563 , Issue.1 , pp. 81-89
    • Vigier, F.1    Coutanceau, C.2    Hahn, F.3    Belgsir, E.M.4    Lamy, C.5
  • 36
    • 0001111329 scopus 로고    scopus 로고
    • Characterization of ethanol and 1,2-ethanediol adsorbates on platinized platinum with Fourier transform infrared spectroscopy and differential electrochemical mass spectrometry
    • 1:CAS:528:DyaK28XlvVSgsr8%3D 10.1021/la960103o
    • Gootzen JFE, Visscher W, van Veen JAR (1996) Characterization of ethanol and 1,2-ethanediol adsorbates on platinized platinum with Fourier transform infrared spectroscopy and differential electrochemical mass spectrometry. Langmuir 12(21):5076-5082
    • (1996) Langmuir , vol.12 , Issue.21 , pp. 5076-5082
    • Gootzen, J.F.E.1    Visscher, W.2    Van Veen, J.A.R.3
  • 37
    • 0011721703 scopus 로고
    • Metal crystallinity effects in electrocatalysis as probed by real-time FTIR spectroscopy: Electrooxidation of formic acid, methanol, and ethanol on ordered low-index platinum surfaces
    • 1:CAS:528:DyaK3cXks1Ohu7g%3D 10.1021/j100378a072
    • Chang SC, Leung LWH, Weaver MJ (1990) Metal crystallinity effects in electrocatalysis as probed by real-time FTIR spectroscopy: electrooxidation of formic acid, methanol, and ethanol on ordered low-index platinum surfaces. J Phys Chem 94(15):6013-6021
    • (1990) J Phys Chem , vol.94 , Issue.15 , pp. 6013-6021
    • Chang, S.C.1    Leung, L.W.H.2    Weaver, M.J.3
  • 38
    • 34848903402 scopus 로고
    • Real-time FTIR spectroscopy as an electrochemical mechanistic probe: Electrooxidation of ethanol and related species on well-defined Pt (111) surfaces
    • 1:CAS:528:DyaL1MXmsVansrg%3D 10.1016/0022-0728(89)85078-8
    • Leung L-WH, Chang S-C, Weaver MJ (1989) Real-time FTIR spectroscopy as an electrochemical mechanistic probe: electrooxidation of ethanol and related species on well-defined Pt (111) surfaces. J Electroanal Chem Interfacial Electrochem 266(2):317-336
    • (1989) J Electroanal Chem Interfacial Electrochem , vol.266 , Issue.2 , pp. 317-336
    • Leung, L.-W.1    Chang, S.-C.2    Weaver, M.J.3
  • 39
    • 0000228983 scopus 로고
    • "in situ" infrared reflectance spectroscopic study of the early stages of ethanol adsorption at a platinum electrode in acid medium
    • 1:CAS:528:DyaL1MXitl2ju7o%3D 10.1016/0022-0728(89)80026-9
    • Perez JM, Beden B, Hahn F, Aldaz A, Lamy C (1989) "In situ" infrared reflectance spectroscopic study of the early stages of ethanol adsorption at a platinum electrode in acid medium. J Electroanal Chem Interfacial Electrochem 262(1-2):251-261
    • (1989) J Electroanal Chem Interfacial Electrochem , vol.262 , Issue.1-2 , pp. 251-261
    • Perez, J.M.1    Beden, B.2    Hahn, F.3    Aldaz, A.4    Lamy, C.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.