Advances in Surface Chemistry of Nanodiamond and Nanodiamond-Polymer Composites

Ultrananocrystalline Diamond: Synthesis, Properties and Applications: Second Edition

Volumn , Issue , 2012, Pages 421-456

  Neitzel, Ioannis ^a   Mochalin, Vadym ^a   Gogotsi, Yury ^a  

^a Drexel University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SURFACE CHEMISTRY;

POLYMER COMPOSITE;

NANODIAMONDS;

EID: 84901391057     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-1-4377-3465-2.00013-X     Document Type: Chapter

References (116)

1. Mochalin V.N., Shenderova O., Ho D., Gogotsi Y. The properties and applications of nanodiamonds. Nat. Nanotechnol. 2012, 7:11-23.
2. Krueger A., Lang D. Functionality is key: recent progress in the surface modification of nanodiamond. Adv. Funct. Mater. 2012, 22(5):890-906.
3. Krueger A. The structure and reactivity of nanoscale diamond. J. Mater. Chem. 2008, 18:1485-1492.
4. Krueger A. Diamond nanoparticles: jewels for chemistry and physics. Adv. Mater. 2008, 20:2445.
5. Xu X., Yu Z., Zhu Y., Wang B. Influence of surface modification adopting thermal treatments on dispersion of detonation nanodiamond. J. Solid State Chem. 2005, 178:688-693.
6. 3 carbon ratio and surface chemistry of nanodiamond powders by selective oxidation in air. J. Am. Chem. Soc. 2006, 128:11635-11642.
7. Kulakova I. Surface chemistry of nanodiamonds. Phys. Solid State 2004, 46:636-643.
8. Mochalin V., Osswald S., Gogotsi Y. Contribution of functional groups to the Raman spectrum of nanodiamond powders. Chem. Mater. 2009, 21(2):273-279.
9. Pentecost A., Gour S., Mochalin V., Knoke I., Gogotsi Y. Deaggregation of nanodiamond powders using salt- and sugar-assisted milling. ACS Appl. Mater. Interfaces 2010, 2:3289-3294.
10. V.N. Mochalin, S. Osswald, C. Portet, G. Yushin, C. Hobson, M. Havel, et al., in: Materials Research Society Symposium Proceedings, Materials Research Society Fall meeting, Boston, MA, USA, 2007, pp. 1039-1103.
11. Spitsyn B.V., Davidson J.L., Gradoboev M.N., Galushko T.B., Serebryakova N.V., Karpukhina T.A., et al. Inroad to modification of detonation nanodiamond. Diamond Relat. Mater. 2006, 15:296-299.
12. Spitsyn B.V., Gradoboev M.N., Galushko T.B., Karpukhina T.A., Serebryakova N.V., Kulakova I.I., et al. Purification and functionalization of nanodiamond. Synthesis, Properties and Applications of Ultrananocrystalline Diamond 2005, 241-252. Springer, Dordrecht. D.M. Gruen, O.A. Shenderova, A.Y. Vul' (Eds.).
13. Korolkov V.V., Kulakova I.I., Tarasevich B.N., Lisichkin G.V. Dual reaction capacity of hydrogenated nanodiamond. Diamond Relat. Mater. 2007, 16:2129-2132.
14. Lisichkin G., Korol'kov V., Tarasevich B., Kulakova I., Karpukhin A. Photochemical chlorination of nanodiamond and interaction of its modified surface with C-nucleophiles. Russ. Chem. Bull. 2006, 55:2212-2219.
15. Liu Y., Khabashesku V.N., Halas N.J. Fluorinated nanodiamond as a wet chemistry precursor for diamond coatings covalently bonded to glass surface. J. Am. Chem. Soc. 2005, 127:3712-3713.
16. Lisichkin G.V., Kulakova I.I., Gerasimov Y.A., Karpukhin A.V., Yalkovlev R.Y. Halogenation of detonation-synthesised nanodiamond surfaces. Mendeleev Commun. 2009, 19:309-310.
17. Liu Y., Gu Z.N., Margrave J.L., Khabashesku V.N. Functionalization of nanoscale diamond powder: fluoro-, alkyl-, amino-, and amino acid-nanodiamond derivatives. Chem. Mater. 2004, 16:3924-3930.
18. Kuznetsov V.L., Chuvilin A.L., Butenko Y.V., Malkov I.Y., Titov V.M. Onion-like carbon from ultra-disperse diamond. Chem. Phys. Lett. 1994, 222:343-348.
19. Portet C., Yushin G., Gogotsi Y. Electrochemical performance of carbon onions, nanodiamonds, carbon black and multiwalled nanotubes in electrical double layer capacitors. Carbon 2007, 45:2511-2518.
20. Pech D., Brunet M., Durou H., Huang P.H., Mochalin V., Gogotsi Y., et al. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 2010, 5:651-654.
21. Ganesh P., Kent P.R.C., Mochalin V. Formation, characterization, and dynamics of onion-like carbon structures for electrical energy storage from nanodiamonds using reactive force fields. J. Appl. Phys. 2011, 110:73506-73508.
22. O. Shenderova, C. Jones, V. Borjanovic, S. Hens, G. Cunningham, S. Moseenkov, et al., Detonation nanodiamond and onion-like carbon: applications, in: Composites, vol. 205, 2008, p. 2251.
23. Shenderova O., Tyler T., Cunningham G., Ray M., Walsh J., Casulli M., et al. Nanodiamond and onion-like carbon polymer nanocomposites. Diamond Relat. Mater. 2007, 16:1213-1217.
24. Su D.S., Maksimova N.I., Mestl G., Kuznetsov V.L., Keller V., Schlogl R., et al. Oxidative dehydrogenation of ethylbenzene to styrene over ultra-dispersed diamond and onion-like carbon. Carbon 2007, 45:2145-2151.
25. Zheng W.W., Hsieh Y.H., Chiu Y.C., Cai S.J., Cheng C.L., Chen C.P. Organic functionalization of ultradispersed nanodiamond: synthesis and applications. J. Mater. Chem. 2009, 19:8432-8441.
26. Mochalin V.N., Gogotsi Y. Wet chemistry route to hydrophobic blue fluorescent nanodiamond. J. Am. Chem. Soc. 2009, 131:4594-4595.
27. Cheng J.L., He J.P., Li C.X., Yang Y.L. Facile approach to functionalize nanodiamond particles with V-shaped polymer brushes. Chem. Mater. 2008, 20:4224-4230.
28. Mochalin V.N., Neitzel I., Etzold B.J.M., Peterson A., Palmese G., Gogotsi Y. Covalent incorporation of aminated nanodiamond into an epoxy polymer network. ACS Nano 2011, 5:7494-7502.
29. Khabashesku V.N., Margrave J.L., Barrera E.V. Functionalized carbon nanotubes and nanodiamonds for engineering and biomedical applications. Diamond Relat. Mater. 2005, 14:859-866.
30. Kruger A., Liang Y.J., Jarre G., Stegk J. Surface functionalisation of detonation diamond suitable for biological applications. J. Mater. Chem. 2006, 16:2322-2328.
31. Martín R., Álvaro M., Herance J.R., García H. Fenton-treated functionalized diamond nanoparticles as gene delivery system. ACS Nano 2010, 4:65-74.
32. Martín R., Hydorn P., Alvaro M., Garcia H. General strategy for high-density covalent functionalization of diamond nanoparticles using Fenton chemistry. Chem. Mater. 2009, 21:4505-4514.
33. Girard H.A., Petit T., Perruchas S., Gacoin T., Gesset C., Arnault J.C., et al. Surface properties of hydrogenated nanodiamonds: a chemical investigation. Phys. Chem. Chem. Phys. 2011, 13:11517-11523.
34. Krueger A., Boedeker T. Deagglomeration and functionalisation of detonation nanodiamond with long alkyl chains. Diamond Relat. Mater. 2008, 17:1367-1370.
35. Liang Y.J., Ozawa M., Krueger A. A general procedure to functionalize agglomerating nanoparticles demonstrated on nanodiamond. ACS Nano 2009, 3:2288-2296.
36. Yeap W.S., Chen S.M., Loh K.P. Detonation nanodiamond: an organic platform for the Suzuki coupling of organic molecules. Langmuir 2009, 25:185-191.
37. Krueger A. New carbon materials: biological applications of functionalized nanodiamond materials. Chem. A Eur. J. 2008, 14:1382-1390.
38. Krueger A., Stegk J., Liang Y.J., Lu L., Jarre G. Biotinylated nanodiamond: simple and efficient functionalization of detonation diamond. Langmuir 2008, 24:4200-4204.
39. Jarre G., Liang Y., Betz P., Lang D., Krueger A. Playing the surface game-Diels-Alder reactions on diamond nanoparticles. Chem. Commun. 2011, 47:544-546.
40. Lang D., Krueger A. The Prato reaction on nanodiamond: surface functionalization by formation of pyrrolidine rings. Diamond Relat. Mater. 2011, 20:101-104.
41. Liang Y.J., Meinhardt T., Jarre G., Ozawa M., Vrdoljak P., Scholl A., et al. Deagglomeration and surface modification of thermally annealed nanoscale diamond. J. Colloid Interface Sci. 2011, 354:23-30.
42. Comet M., Pichot V., Siegert B., Britz F., Spitzer D. Detonation nanodiamonds for doping Kevlar. J. Nanosci. Nanotechnol. 2010, 10:4286-4292.
43. Schmidlin L., Pichot V., Comet M., Josset S., Rabu P., Spitzer D. Identification, quantification and modification of detonation nanodiamond functional groups. Diamond Relat. Mater. 2012, 22:113-117.
44. Neitzel I., Mochalin V., Niu J., Cuadra J., Kontsos A., Palmese G., et al. Maximizing Young's moduli of aminated nanodiamond-epoxy composites. Macromolecules 2012, submitted.
45. Ajayan P.M., Schadler L.S., Braun P.V. Nanocomposite Science and Technology 2003, Wiley-VCH.
46. Ma P.-C., Mo S.-Y., Tang B.-Z., Kim J.-K. Dispersion, interfacial interaction and re-agglomeration of functionalized carbon nanotubes in epoxy composites. Carbon 2010, 48:1824-1834.
47. Chen C., Justice R.S., Schaefer D.W., Baur J.W. Highly dispersed nanosilica-epoxy resins with enhanced mechanical properties. Polymer 2008, 49:3805-3815.
48. Seidel G.D., Lagoudas D.C. Micromechanical analysis of the effective elastic properties of carbon nanotube reinforced composites. Mech. Mater. 2006, 38:884-907.
49. Spanos P.D., Kontsos A. A multiscale Monte Carlo finite element method for determining mechanical properties of polymer nanocomposites. Probab. Eng. Mech. 2008, 23:456-470.
50. Hooper J.B., Schweizer K.S. Contact aggregation, bridging, and steric stabilization in dense polymer-particle mixtures. Macromolecules 2005, 38:8858-8869.
51. Hooper J.B., Schweizer K.S. Theory of phase separation in polymer nanocomposites. Macromolecules 2006, 39:5133-5142.
52. Shenderova O.A., McGuire G. Nanocrystalline diamond. Nanomaterials Handbook 2006, 203-237. CRC Taylor and Francis Group, Boca Raton, FL. Y. Gogotsi (Ed.).
53. Mykhaylyk O.O., Solonin Y.M., Batchelder D.N., Brydson R. Transformation of nanodiamond into carbon onions: a comparative study by high-resolution transmission electron microscopy, electron energy-loss spectroscopy, x-ray diffraction, small-angle x-ray scattering, and ultraviolet Raman spectroscopy. J. Appl. Phys. 2005, 97:74302-74316.
54. Williams O.A., Hees J., Dieker C., Jager W., Kirste L., Nebel C.E. Size-dependent reactivity of diamond nanoparticles. ACS Nano 2010, 4:4824-4830.
55. Selzer R., Friedrich K. Mechanical properties and failure behaviour of carbon fibre-reinforced polymer composites under the influence of moisture. Composites Part A Appl. Sci. Manuf. 1997, 28:595-604.
56. Ahmed S., Jones F.R. A review of particulate reinforcement theories for polymer composites. J. Mater. Sci. 1990, 25:4933-4942.
57. Grill A. Tribology of diamondlike carbon and related materials: an updated review. Surf. Coat. Technol. 1997, 94-95:507-513.
58. Schrand A.M., Johnson J., Dai L., Hussain S.M., Schlager J.J., Zhu L., et al. Cytotoxicity and genotoxicity of carbon nanomaterials. Safety in Nanoparticles: From Manufacturing to Clinical Applications 2009, Springer, New York, pp. 1-29.
59. Monthioux M., Smith B.W., Burteaux B., Claye A., Fischer J.E., Luzzi D.E. Sensitivity of single-wall carbon nanotubes to chemical processing: an electron microscopy investigation. Carbon 2001, 39:1251-1272.
60. Gavrilov A., Voznyakovskii A. Rheological characteristics and relaxation properties of polymer-nanodiamond composites. Russ. J. Appl. Chem. 2009, 82:1041-1045.
61. Bershtein V., Karabanova L., Sukhanova T., Yakushev P., Egorova L., Lutsyk E., et al. Peculiar dynamics and elastic properties of hybrid semi-interpenetrating polymer network-3-D diamond nanocomposites. Polymer 2008, 49:836-842.
62. Jee A.-Y., Lee M. Thermal and mechanical properties of alkyl-functionalized nanodiamond composites. Curr. Appl. Phys. 2011, 11:1183-1187.
63. Behler K.D., Stravato A., Mochalin V., Korneva G., Yushin G., Gogotsi Y. Nanodiamond-polymer composite fibers and coatings. ACS Nano 2009, 3:363-369.
64. Klein J. Shear, friction, and lubrication forces between polymer-bearing surfaces. Annu. Rev. Mater. Sci. 1996, 26:581-612.
65. Lancaster J.K. Polymer-based bearing materials: the role of fillers and fibre reinforcement. Tribology 1972, 5:249-255.
66. Rehbein P., Wallaschek J. Friction and wear behaviour of polymer/steel and alumina/alumina under high-frequency fretting conditions. Wear 1998, 216:97-105.
67. Widmer M.R., Heuberger M., Vörös J., Spencer N.D. Influence of polymer surface chemistry on frictional properties under protein-lubrication conditions: implications for hip-implant design. Tribol. Lett. 2001, 10:111-116.
68. Robertson J. Properties of diamond-like carbon. Surf. Coat. Technol. 1992, 50:185-203.
69. Lee J.-Y., Lim D.-S. Tribological behavior of PTFE film with nanodiamond. Surf. Coat. Technol. 2004, 188-189:534-538.
70. Lim D.P., Lee J.Y., Lim D.S., Ahn S.G., Lyo I.W. Effect of reinforcement particle size on the tribological properties of nano-diamond filled polytetrafluoroethylene based coating. J. Nanosci. Nanotechnol. 2009, 9:4197-4201.
71. Bobrovnitchii G.S., Skury A.L.D., Monteiro S.N., Tardim R.C. Effect of nanodiamond addition on the mechanical properties of polycrystalline metallic and polymeric composites. Mater. Sci. Forum 2010, 660-661:848-853.
72. Voznyakovskii A., Ginzburg B., Rashidov D., Tochil'nikov D., Tuichiev S. Structure, mechanical, and tribological characteristics of polyurethane modified with nanodiamonds. Polym. Sci. Ser. A 2010, 52:1044-1050.
73. Stravato A., Knight R., Mochalin V., Picardi S.C. HVOF-sprayed nylon-11 + nanodiamond composite coatings: production and characterization. J. Therm. Spray Technol. 2008, 17:812-817.
74. Hassan C.M., Peppas N.A. Structure and applications of poly(vinyl alcohol) hydrogels produced by conventional crosslinking or by freezing/thawing methods. Biopolymers/PVA Hydrogels/Anionic Polymerisation Nanocomposites 2000, vol. 153:37-65. Springer-Verlag, Berlin.
75. Kurkin T.S., Ozerin A.N., Kechek'yan A.S., Gritsenko O.T., Ozerina L.A., Alkhanishvili G.G., et al. The structure and properties of polymer composite fibers based on poly(vinyl alcohol) and nanodiamond of detonation synthesis. Nanotechnol. Russ. 2010, 5:340-351.
76. Morimune S., Kotera M., Nishino T., Goto K., Hata K. Poly(vinyl alcohol) nanocomposites with nanodiamond. Macromolecules 2011, 44:4415-4421.
77. Maitra U., Prasad K.E., Ramamurty U., Rao C.N.R. Mechanical properties of nanodiamond-reinforced polymer-matrix composites. Solid State Commun. 2009, 149:1693-1697.
78. Protopapa P., Kontonasaki E., Bikiaris D., Parasekevopoulos K., Koidis P. Reinforcement of a PMMA resin for fixed interim protheses with nanodiamonds. Dent. Mater. J. 2010, 30:222-231.
79. Jee A.-Y., Lee M. Mechanical properties of polycarbonate and poly(methyl methacrylate) films reinforced with surface-functionalized nanodiamonds. J. Nanosci. Nanotechnol. 2011, 11:533-536.
80. Zhao Y.-Q., Lau K.-T., Kim J.-k., Xu C.-L., Zhao D.-D., Li H.-L. Nanodiamond/poly (lactic acid) nanocomposites: effect of nanodiamond on structure and properties of poly (lactic acid). Composite Part B Eng. 2010, 41:646-653.
81. Zhang Q., Mochalin V.N., Neitzel I., Knoke I.Y., Han J., Klug C.A., et al. Fluorescent PLLA-nanodiamond composites for bone tissue engineering. Biomaterials 2011, 32:87-94.
82. Zhang Q., Mochalin V., Neitzel I., Hazeli K., Niu J., Kontsos A., et al. Multifunctional nanodiamond-PLLA scaffolds for bone tissue engineering: enhanced mechanical strength and biomineralization. Biomaterials 2012, 33:5067-5075.
83. Guo S., Solares S.D., Mochalin V., Neitzel I., Gogotsi Y., Kalinin S., et al. Multifrequency imaging in the intermittent contact mode of atomic force microscopy: beyond phase imaging. Small 2012, 8:1264-1269.
84. Akcora P., Liu H., Kumar S.K., Moll J., Li Y., Benicewicz B.C., et al. Anisotropic self-assembly of spherical polymer-grafted nanoparticles. Nat. Mater. 2009, 8:354-359.
85. Li L., Davidson J., Lukehart C. Surface functionalization of nanodiamond particles via atom transfer radical polymerization. Carbon 2006, 44:2308-2315.
86. Zhang Q., Naito K., Tanaka Y., Kagawa Y. Grafting polyimides from nanodiamonds. Macromolecules 2008, 41:536-538.
87. Sirotinkin N., Voznyakovskii A., Ershova A. Model of formation of three-dimensional polyurethane films modified by detonation nanodiamonds. Phys. Solid State 2004, 46:746-747.
88. Prasad K.E., Das B., Maitra U., Ramamurty U., Rao C.N.R. Extraordinary synergy in the mechanical properties of polymer matrix composites reinforced with 2 nanocarbons. Proc. Nat. Acad. Sci. U.S.A. 2009, 106:13186-13189.
89. Korobko A.P., Bessonova N.P., Krasheninnikov S.V., Konyukhova E.V., Drozd S.N., Chvalun S.N. Nanodiamonds as modifier of ethylene-1-octene copolymer structure and properties. Diamond Relat. Mater. 2007, 16:2141-2144.
90. Thermoset Nanocomposites for Engineering Applications 2007, 2-10. Rapra. R. Kotsilkova (Ed.).
91. Soutis C. Carbon fiber reinforced plastics in aircraft construction. Mater. Sci. Eng. A 2005, 412:171-176.
92. Neitzel I., Mochalin V., Knoke I., Palmese G.R., Gogotsi Y. Mechanical properties of epoxy composites with high contents of nanodiamond. Compos. Sci. Technol. 2011, 71:710-716.
93. Neitzel I., Mochalin V., Bares J., Carpick R., Erdemir A., Gogotsi Y. Tribological properties of nanodiamond-epoxy composites. Tribol. Lett. 2012, 10.1007/s11249-012-9978-8.
94. Spitalsky Z., Kromka A., Matejka L., Cernoch P., Kovarova J., Kotek J., et al. Effect of nanodiamond particles on properties of epoxy composites. Adv. Compos. Lett. 2008, 17:29-34.
95. Ayatollahi M.R., Alishahi E., Shadlou S. Mechanical behavior of nanodiamond/epoxy nanocomposites. Int. J. Fract. 2011, 170:95-100.
96. Carroll B., Gogotsi Y., Kovalchenko A., Erdemir A., McNallan M.J. Effect of humidity on the tribological properties of carbide-derived carbon (CDC) films on silicon carbide. Tribol. Lett. 2003, 15:51-55.
97. Liu Y., Erdemir A., Meletis E.I. A study of the wear mechanism of diamond-like carbon films. Surf. Coat. Technol. 1996, 82:48-56.
98. Angelopoulos A.P. Introduction to physical polymer science. Mol. Cryst. Liq. Cryst. Sci. Technol. A 2002, 381:183-184.
99. Handbook of Plastics, Elastomers, and Composites 2002, 884. McGraw-Hill. fourth ed. C.A. Harper (Ed.).
100. Dolmatov V.Y. Composition materials based on elastomer and polymer matrices filled with nanodiamonds of detonation synthesis. Nanotechnol. Russia 2009, 4:556-575.
101. Dolmatov V.Y. Polymer-diamond composites based on detonation nanodiamonds. Part 2. J. Superhard Mater. 2007, 29:65-75.
102. Sordi D., De Ruijter C., Orlanducci S., Picken S.J., Sudhölter E.J.R., Terranova M.L., et al. Sulfonated liquid crystalline polyesters as resin matrix for single wall carbon nanotube and nanodiamond composites. J. Polym. Sci. Part A Polym. Chem. 2011, 49:1079-1087.
103. Shenderova O.A., Zhirnov V.V., Brenner D.W. Carbon nanostructures. Crit. Rev. Solid State Mater. Sci. 2002, 27:227-356.
104. Macutkevic J., Kuzhir P., Seliuta D., Valusis G., Banys J., Paddubskaya A., et al. Dielectric properties of a novel high absorbing onion-like-carbon based polymer composite. Diamond Relat. Mater. 2010, 19:91-99.
105. Beecroft L.L., Ober C.K. Nanocomposite materials for optical applications. Chem. Mater. 1997, 9:1302-1317.
106. Yeun J.-H., Bang G.-S., Park B.J., Ham S.K., Chang J.-H. Poly(vinyl alcohol) nanocomposite films: thermooptical properties, morphology, and gas permeability. J. Appl. Polym. Sci. 2006, 101:591-596.
107. Wissing S.A., Müller R.H. Cosmetic applications for solid lipid nanoparticles (SLN). Int. J. Pharm. 2003, 254:65-68.
108. Shenderova O., Grichko V., Hens S., Walch J. Detonation nanodiamonds as UV radiation filter. Diamond Relat. Mater. 2007, 16:2003-2008.
109. Yu S.-J., Kang M.-W., Chang H.-C., Chen K.-M., Yu Y.-C. Bright fluorescent nanodiamonds: no photobleaching and low cytotoxicity. J. Am. Chem. Soc. 2005, 127:17604-17605.
110. Grichko V., Tyler T., Grishko V.I., Shenderova O. Nanodiamond particles forming photonic structures. Nanotechnology 2008, 19:225201.
111. Tong X.C. Advanced Materials and Design for Electromagnetic Interference Shielding 2008, vol. 1. CRC Press, Boca Raton, FL, p. 130.
112. Shenderova O., Grishko V., Cunningham G., Moseenkov S., McGuire G., Kuznetsov V. Onion-like carbon for terahertz electromagnetic shielding. Diamond Relat. Mater. 2008, 17:462-466.
113. Gavrilov N.N., Okotrub A.V., Bulusheva L.G., Sedelnikova O.V., Yushina I.V., Kuznetsov V.L. Dielectric properties of polystyrene/onion-like carbon composites in frequency range of 0.5-500kHz. Compos. Sci. Technol. 2010, 70:719-724.
114. Wang H.D., Yang Q.Q., Niu C.H. Functionalization of nanodiamond particles with N,O-carboxymethyl chitosan. Diamond Relat. Mater. 2010, 19:441-444.
115. Lam R., Chen M., Pierstorff E., Huang H., Osawa E., Ho D. Nanodiamond-embedded microfilm devices for localized chemotherapeutic elution. ACS Nano 2008, 2:2095-2102.
116. Borjanovic V., Bistricic L., Vlasov I., Furic K., Zamboni I., Jaksic M., et al. Influence of proton irradiation on the structure and stability of poly(dimethylsiloxane) and poly(dimethylsiloxane)-nanodiamond composite. J. Vac. Sci. Technol. B 2009, 27:2396-2403.