Metal/phthalocyanine hybrid interface states on Ag(111)

Journal of Physical Chemistry Letters

Volumn 5, Issue 10, 2014, Pages 1679-1684

  Caplins, Benjamin W ^a,b   Suich, David E ^a,b   Shearer, Alex J ^a,b   Harris, Charles B ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

charge transfer; density functional theory; electron dynamics; organic thin films; phthalocyanine; two photon photoemission (TPPE)

Indexed keywords

CHARGE TRANSFER; DENSITY FUNCTIONAL THEORY; INTERFACE STATES; NITROGEN COMPOUNDS; SURFACE STATES;

3 ,4 ,9 ,10-PERYLENE-TETRACARBOXYLIC-DIANHYDRIDE; ELECTRON DYNAMICS; HYBRID INTERFACE; IRON PHTHALOCYANINES; ORGANIC THIN FILMS; PHTHALOCYANINE; SHOCKLEY SURFACE STATE; TWO-PHOTON PHOTOEMISSION;

SILVER;

EID: 84901020263     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz500571z     Document Type: Article

References (37)

1. Hwang, J.; Wan, A.; Kahn, A. Energetics of Metal-Organic Interfaces: New Experiments and Assessment of the Field Mater. Sci. Eng. Rep. 2009, 64, 1-31
2. Braun, S.; Salaneck, W. R.; Fahlman, M. Energy-Level Alignment at Organic/Metal and Organic/Organic Interfaces Adv. Mater. 2009, 21, 1450-1472
3. Scott, J. C. Metal-Organic Interface and Charge Injection in Organic Electronic Devices J. Vac. Sci. Technol., A 2003, 21, 521-531
4. Ishii, H.; Sugiyama, K.; Ito, E.; Seki, K. Energy Level Alignment and Interfacial Electronic Structures at Organic/Metal and Organic/Organic Interfaces Adv. Mater. 1999, 11, 605-625
5. Gonzalez-Lakunza, N.; Fernandez-Torrente, I.; Franke, K. J.; Lorente, N.; Arnau, A.; Pascual, J. I. Formation of Dispersive Hybrid Bands at an Organic-Metal Interface Phys. Rev. Lett. 2008, 100, 156805
6. Scheybal, A.; Müller, K.; Bertschinger, R.; Wahl, M.; Bendounan, A.; Aebi, P.; Jung, T. Modification of the Cu(110) Shockley Surface State by an Adsorbed Pentacene Monolayer Phys. Rev. B 2009, 79, 115406
7. Heinrich, B. W.; Limot, L.; Rastei, M. V.; Iacovita, C.; Bucher, J. P.; Djimbi, D. M.; Massobrio, C.; Boero, M. Dispersion and Localization of Electronic States at a Ferrocene/Cu(111) Interface Phys. Rev. Lett. 2011, 107, 216801
8. Galbraith, M. C. E.; Marks, M.; Tonner, R.; Höfer, U. Formation of an Organic/Metal Interface State from a Shockley Resonance J. Phys. Chem. Lett. 2014, 5, 50-55
9. Temirov, R.; Soubatch, S.; Luican, A.; Tautz, F. S. Free-Electron-Like Dispersion in an Organic Monolayer Film on a Metal Substrate Nature 2006, 444, 350-353
10. Schwalb, C. H.; Sachs, S.; Marks, M.; Schöll, A.; Reinert, F.; Umbach, E.; Höfer, U. Electron Lifetime in a Shockley-Type Metal-Organic Interface State Phys. Rev. Lett. 2008, 101, 146801
11. Yang, A.; Shipman, S.; Garrett-Roe, S.; Johns, J.; Strader, M.; Szymanski, P.; Muller, E.; Harris, C. Two-Photon Photoemission of Ultrathin Film PTCDA Morphologies on Ag(111) J. Phys. Chem. C 2008, 112, 2506-2513
12. Sachs, S.; Schwalb, C. H.; Marks, M.; Schöll, A.; Reinert, F.; Umbach, E.; Höfer, U. Electronic Structure at the Perylene-tetracarboxylic Acid Dianhydride/Ag(111) Interface Studied with Two-Photon Photoelectron Spectroscopy J. Chem. Phys. 2009, 131, 144701
13. Schwalb, C. H.; Marks, M.; Sachs, S.; Schöll, A.; Reinert, F.; Umbach, E.; Höfer, U. Time-Resolved Measurements of Electron Transfer Processes at the PTCDA/Ag(111) Interface Eur. Phys. J. B 2010, 75, 23-30
14. Marks, M.; Zaitsev, N. L.; Schmidt, B.; Schwalb, C. H.; Schöll, A.; Nechaev, I. A.; Echenique, P. M.; Chulkov, E. V.; Höfer, U. Energy Shift and Wave Function Overlap of Metal-Organic Interface States Phys. Rev. B 2011, 84, 081301
15. Dyer, M. S.; Persson, M. The Nature of the Observed Free-Electron-Like State in a PTCDA Monolayer on Ag(111) New J. Phys. 2010, 12, 063014
16. Zaitsev, N.; Nechaev, I.; Chulkov, E. Change in Surface States of Ag(111) Thin Films upon Adsorption of a Monolayer of PTCDA Organic Molecules J. Exp. Theor. Phys. 2010, 110, 114-120
17. Zaitsev, N. L.; Nechaev, I. A.; Echenique, P. M.; Chulkov, E. V. Transformation of the Ag(111) Surface State Due to Molecule-Surface Interaction with Ordered Organic Molecular Monolayers Phys. Rev. B 2012, 85, 115301
18. Shockley, W. On the Surface States Associated with a Periodic Potential Phys. Rev. 1939, 56, 317-323
19. Li, Z.; Li, B.; Yang, J.; Hou, J. G. Single-Molecule Chemistry of Metal Phthalocyanine on Noble Metal Surfaces Acc. Chem. Res. 2010, 43, 954-62
20. Niu, T.; Li, A. Exploring Single Molecules by Scanning Probe Microscopy: Porphyrin and Phthalocyanine J. Phys. Chem. Lett. 2013, 4, 4095-4102
21. Lindstrom, C. D.; Zhu, X.-Y. Photoinduced Electron Transfer at Molecule-Metal Interfaces Chem. Rev. 2006, 106, 4281-300
22. 2-Phthalocyanine on Ag(111) Phys. Rev. B 2012, 86, 195412
23. Caplins, B. W.; Shearer, A. J.; Suich, D. E.; Muller, E. A.; Harris, C. B. Measuring the Electronic Corrugation at the Metal/Organic Interface Phys. Rev. B 2014, 89, 155422
24. Grothe, S.; Johnston, S.; Chi, S.; Dosanjh, P.; Burke, S.; Pennec, Y. Quantifying Many-Body Effects by High-Resolution Fourier Transform Scanning Tunneling Spectroscopy Phys. Rev. Lett. 2013, 111, 246804
25. Huang, Y. L.; Wruss, E.; Egger, D. A.; Kera, S.; Ueno, N.; Saidi, W. A.; Bucko, T.; Wee, A. T. S.; Zojer, E. Understanding the Adsorption of CuPc and ZnPc on Noble Metal Surfaces by Combining Quantum-Mechanical Modelling and Photoelectron Spectroscopy Molecules 2014, 19, 2969-92
26. Henze, S.; Bauer, O.; Lee, T.-L.; Sokolowski, M.; Tautz, F. Vertical Bonding Distances of PTCDA on Au(111) and Ag(111): Relation to the Bonding Type Surf. Sci. 2007, 601, 1566-1573
27. Stadler, C.; Hansen, S.; Schöll, A.; Lee, T.-L.; Zegenhagen, J.; Kumpf, C.; Umbach, E. Molecular Distortion of NTCDA upon Adsorption on Ag(111): a Normal Incidence X-ray Standing Wave Study New J. Phys. 2007, 9, 50-50
28. Echenique, P.; Berndt, R.; Chulkov, E.; Fauster, T.; Goldmann, A.; Höfer, U. Decay of Electronic Excitations at Metal Surfaces Surf. Sci. Rep. 2004, 52, 219-317
29. Bobaru, S. C.; Salomon, E.; Layet, J.-M.; Angot, T. Structural Properties of Iron Phtalocyanines on Ag(111): From the Submonolayer to Monolayer Range J. Phys. Chem. C 2011, 115, 5875-5879
30. Mugarza, A.; Robles, R.; Krull, C.; Korytár, R.; Lorente, N.; Gambardella, P. Electronic and Magnetic Properties of Molecule-Metal Interfaces: Transition-Metal Phthalocyanines Adsorbed on Ag(100) Phys. Rev. B 2012, 85, 155437
31. Gopakumar, T. G.; Brumme, T.; Kroger, J.; Toher, C.; Cuniberti, G.; Berndt, R. Coverage-Driven Electronic Decoupling of Fe-Phthalocyanine from a Ag(111) Substrate J. Phys. Chem. C 2011, 115, 12173-12179
32. Petraki, F.; Peisert, H.; Aygül, U.; Latteyer, F.; Uihlein, J.; Vollmer, A.; Chassé, T. Electronic Structure of FePc and Interface Properties on Ag(111) and Au(100) J. Phys. Chem. C 2012, 116, 11110-11116
33. Feyer, V.; Graus, M.; Nigge, P.; Wießner, M.; Acres, R.; Wiemann, C.; Schneider, C.; Schöll, A.; Reinert, F. Adsorption Geometry and Electronic Atructure of Iron Phthalocyanine on Ag Surfaces: A LEED and Photoelectron Momentum Mapping Study Surf. Sci. 2014, 621, 64-68
34. Seufert, K.; Auwärter, W.; Garcia de Abajo, F. J.; Ecija, D.; Vijayaraghavan, S.; Joshi, S.; Barth, J. V. Controlled Interaction of Surface Quantum-Well Electronic States Nano Lett. 2013, 13, 6130-6135
35. Lingle, R.; Ge, N.-H.; Jordan, R.; McNeill, J.; Harris, C. Femtosecond Studies of Electron Tunneling at Metal-Dielectric Interfaces Chem. Phys. 1996, 205, 191-203
36. Giannozzi, P.; Baroni, S.; Bonini, N.; Calandra, M.; Car, R.; Cavazzoni, C.; Ceresoli, D.; Chiarotti, G. L.; Cococcioni, M.; Dabo, I. QUANTUM ESPRESSO: A Modular and Open-Source Software Project for Quantum Simulations of Materials J. Phys.: Condens. Matter 2009, 21, 395502
37. Sperl, A.; Kröger, J.; Berndt, R. Controlled Metalation of a Single Adsorbed Phthalocyanine Angew. Chem., Int. Ed. 2011, 50, 5294-5297