Determination of kresoxim-methyl and its thermolabile metabolites in pear utilizing pepper leaf matrix as a protectant using gas chromatography

Journal of Advanced Research

Volumn 5, Issue 3, 2014, Pages 329-335

  Rahman, Md Musfiqur ^a   Jang, Jin ^a   Park, Jong Hyouk ^a   Abd El Aty, A M ^b   Ko, Ah Young ^a   Choi, Jeong Heui ^c   Yang, Angel ^a   Park, Ki Hun ^a   Shim, Jae Han ^a  

^a Chonnam National University   (South Korea)

^b Cairo University   (Egypt)

^c TU DORTMUND UNIVERSITY   (Germany)

Author keywords

Gas chromatography; Kresoxim methyl; Matrix effect; Metabolites; Pear

Indexed keywords

EID: 84900535189     PISSN: 20901232     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jare.2013.05.003     Document Type: Article

References (21)

1. Li J.Z., Wu X., Hu J.Y. Determination of fungicide kresoxim-methyl residues in cucumber and soil by capillary gas chromatography with nitrogen-phosphorus detection. J Environ Sci Health B 2006, 41(4):427-436.
2. Sauter H., Steglich W., Anke T. Strobilurins: evolution of new class of active substances. Angew Chem Int Ed 1999, 38(10):1328-1349.
3. Herms S., Seehaus K., Koehle H., Conrath U. A strobilurin fungicide enhances the resistance of tobacco against tobacco mosaic virus and Pseudomonas syringae pv tabaci. Plant Physiol 2002, 130(1):120-127.
4. Margot P., Huggenberger F., Amrein J., Weiss B. A new broad-spectrum strobilurin fungicide. Brighton Crop Prot Con Pest Dis 1998, 2:375-382.
5. KFDA MRLs for Pesticides in Food. Korea food and drug administration: Republic of Korea; 2011. p. 92. http://fse.foodnara.go.kr/residue/index.jsp.
6. EC (European Commission), Review report for the active substance kresoxim-methyl. Finalised in the standing committee on the food chain and animal health at its meeting on 16 October 1998 in view of the inclusion of kresoxim-methyl in Annex I of Council Directive 91/414/EEC. 7583/VI/97-Final, European Commission, Brussels; 1998. p. 1-17.
7. Cabras P., Angioni A., Vincenzo L. Fate of azoxystrobin, fluazinam, kresoximmethyl, mepanipyrim, and tetraconazole from vine to wine. J Agric Food Chem 1998, 46(8):3249-3251.
8. Navalon A., Prieto A., Araujo L. Determination of pyrimethanil and kresoximmethyl in green groceries by headspace solid-phase microextraction and gas chromatography-mass spectrometry. J Chromatogr A 2002, 975(2):355-360.
9. Sannino A., Bolzoni L., Bandini M. Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables. J Chromatogr A 2004, 1036(2):161-169.
10. Rahman M.M., Park J.H., Abd El-Aty A.M., Choi J.H., Cho S.K. Analysis of kresoxim-methyl and its thermolabile metabolites in Korean plum: an application of pepper leaf matrix as a protectant for GC amenable metabolites. J Sep Sci 2013, 36(1):203-211.
11. Movassaghi S, Thornton JB. Determination of BAS 490 F and its metabolites in pecan. Reg. Doc. # BASF 97/5282. BASF corporation - agricultural products group. Research Triangle Park, NC; 1997. http://www.epa.gov/opp00001/methods/rammethods/1998_072M.pdf.
12. Erney D.R., Gillespie A.M., Gilvydis D.M., Poole C.F. Explanation of the matrix-induced chromatographic response enhancement of organophosphorus pesticides during open tubular column gas chromatography with splitless or hot on-column injection and flame photometric detection. J Chromatogr 1993, 638:57-63.
13. Erney D.R., Poole C.F. A study of single compound additives to minimize the matrix induced chromatographic response enhancement observed in the gas chromatography of pesticide residues. J High Resolut Chrom 1997, 20:375-378.
14. Anastassiades M., Mastovska K., Lehotay S.J. Evaluation of analyte protectants to improve gas chromatographic analysis of pesticides. J Chromatogr A 2003, 1015:163-184.
15. Mastovska K., Lehotay S.J., Anastassiades M. Combination of analyte protectants to overcome matrix effects in routine GC analysis of pesticide residues in food matrixes. Anal Chem 2005, 77:8129-8137.
16. Rahman M.M., Choi J.H., Abd El-Aty A.M., Abid M.D.N., Park J.H. Pepper leaf matrix as a promising analyte protectant prior to the analysis of thermolabile terbufos and its metabolites in pepper using GC-FPD. Food Chem 2012, 133(2):604-610.
17. Rahman M.M., Park J.H., Abd El-Aty A.M., Choi J.H., Cho S.K. Analysis of kresoxim-methyl and its thermolabile metabolites in Korean plum: an application of pepper leaf matrix as a protectant for GC amenable metabolites. J Sep Sci 2013, 36:203-211.
18. European Commission. Method validation and quality control procedures for pesticide residues analysis in food and feed, Document No. SANCO/2007/3131. http://www.ec.europa.eu/food/plant/protection/resources/qualcontrol_en.pdf.
19. FAO/WHO. Pesticide residues in food - evaluation 1998. Part I - Residues, vol. II. World Health Organization, Geneva; 1999. p. 823-9.
20. Jian-Zhong L., Xian W., Ji-Ye H. Determination of fungicide kresoxim-methyl residues in cucumber and soil by capillary gas chromatography with nitrogen-phosphorus detection. J Environ Sci Health Part B 2006, 41:427-436.
21. Liu X., Dong F., Qin D., Zheng Y. Residue analysis of kresoxim-methyl and boscalid in fruits, vegetables and soil using liquid-liquid extraction and gas chromatography-mass spectrometry. Biomed Chromatogr 2010, 24:367-373.