Size and structure effects controlling the stability of the liquid organic hydrogen carrier dodecahydro- N -ethylcarbazole during dehydrogenation over pt model catalysts

Journal of Physical Chemistry Letters

Volumn 5, Issue 8, 2014, Pages 1498-1504

  Amende, Max ^a   Gleichweit, Christoph ^a   Schernich, Stefan ^a   Höfert, Oliver ^a   Lorenz, Michael P A ^a   Zhao, Wei ^a   Koch, Marcus ^a   Obesser, Katharina ^a   Papp, Christian ^a   Wasserscheid, Peter ^a   Steinrück, Hans Peter ^a   Libuda, Jörg ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

liquid organic hydrogen carrier; model catalysis; photoelectron spectroscopy; supported catalysts

Indexed keywords

AGGLOMERATION; CATALYST SUPPORTS; CATALYSTS; DEHYDROGENATION; HYDROGEN; PHOTOELECTRON SPECTROSCOPY; PHOTOELECTRONS; PLATINUM; SINGLE CRYSTALS; X RAY PHOTOELECTRON SPECTROSCOPY;

ACTIVATION BARRIERS; HIGH RESOLUTION; HYDROGEN CARRIERS; LARGE PARTICLES; LOWER TEMPERATURES; MODEL CATALYSIS; N-ETHYLCARBAZOLE; STRUCTURE EFFECT;

LIQUIDS;

EID: 84898966088     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz500157r     Document Type: Article

References (41)

1. von Wild, J.; Friedrich, T.; Cooper, A.; Tosel, B.; Muraro, G.; Tegrotenhuis, W.; Wang, Y.; Humble, P.; Karim, A.; Stolten, D. Liquid Organic Hydrogen Carriers (LOHC): An Auspicious Alternative to Conventional Hydrogen Storage Technologies Energy Environ. 2010, 78-4, 188-197
2. Ghosh, T. K.; Prelas, M. A. Energy Resources and Systems. In Renewable Resources, Band 2; Springer Science+Business Media B. V.: New York, 2011; Vol. 2.
3. Tzimas, E.; Filiou, C.; Peteves, S. D.; Petten, J. B. V. Hydrogen Storage: State-of-the-Art and Future Perspective; European Commission Institute for Energy: Petten, The Netherlands, 2003; pp 29-31.
4. James, B. D. Overview of Hydrogen Storage Technologies Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2008, 568-569
5. Eberle, U.; Felderhoff, M.; Schüth, F. Chemical and Physical Solutions for Hydrogen Storage Angew. Chem. 2009, 121, 6732
6. Teichmann, D.; Arlt, W.; Wasserscheid, P. Liquid Organic Hydrogen Carriers As an Efficient Vector for the Transport and Storage of Renewable Energy Int. J. Hydrogen Energy 2012, 37, 18118
7. Teichmann, D.; Arlt, W.; Wasserscheid, P.; Freymann, R. A Future Energy Supply Based on Liquid Organic Hydrogen Carriers (LOHC) Energy Environ. Sci. 2011, 4, 2767-2773
8. Teichmann, D.; Stark, K.; Müller, K.; Zöttl, G.; Wasserscheid, P.; Arlt, W. Energy Storage in Residential and Commercial Buildings via Liquid Organic Hydrogen Carriers (LOHC) Energy Environ. Sci. 2012, 5, 9044
9. Pez, G.; Scott, A.; Cooper, A.; Cheng, H.; Bagzis, L.; Appleby, J. Hydrogen Storage Reversible Hydrogenated of π-Conjugated Substrates. International Patent WO 2005/000457, 2005.
10. Crabtree, R. H. Hydrogen Storage in Liquid Organic Heterocycles Energy Environ. Sci. 2008, 1, 134-138
11. Eblagon, K. M.; Tam, K.; Yu, K. M. K.; Tsang, S. C. E. Comparative Study of Catalytic Hydrogenation of 9-Ethylcarbazole for Hydrogen Storage over Noble Metal Surfaces J. Phys. Chem. C 2012, 116, 7421-7429
12. Zhao, H. Y.; Oyama, S. T.; Naeemi, E. D. Hydrogen Storage by Using Heterocyclic Compounds: The Hydrogenation of 2-Methylthiophene Catal. Today 2010, 149, 172-184
13. Scherer, G. W. H.; Newson, E. Analysis of the Seasonal Energy Storage of Hydrogen in Liquid Organic Hydrides Int. J. Hydrogen Storage 1998, 23, 19-25
14. Eblagon, K. M.; Rentsch, D.; Friedrichs, O.; Remhof, A.; Zuettel, A.; Ramirez-Cuesta, A. J.; Tsang, S. C. Hydrogenation of 9-Ethylcarbazole as a Prototype of a Liquid Hydrogen Carrier Int. J. Hydrogen Energy 2010, 35, 11609-11621
15. Amende, M.; Schernich, S.; Sobota, M.; Nikiforidis, I.; Hieringer, W.; Assenbaum, D.; Gleichweit, C.; Drescher, H.-J.; Papp, C.; Steinrück, H.-P. Dehydrogenation Mechanism of Liquid Organic Hydrogen Carriers: Dodecahydro- N -ethylcarbazole on Pd(111) Chem. - Eur. J. 2013, 19, 10854-10865
16. Amende, M.; Gleichweit, C.; Werner, K.; Schernich, S.; Zhao, W.; Lorenz, M. P. A.; Höfert, O.; Papp, C.; Koch, M.; Wasserscheid, P. Model Catalytic Studies of Liquid Organic Hydrogen Carriers: Dehydrogenation and Decomposition Mechanisms of Dodecahydro- N -ethylcarbazole on Pt(111) ACS Catal. 2014, 4, 657-665
17. Gleichweit, C.; Amende, M.; Schernich, S.; Zhao, W.; Lorenz, M. P. A.; Höfert, O.; Brückner, N.; Wasserscheid, P.; Libuda, J.; Steinrück, H.-P. Dehydrogenation of Dodecahydro- N -ethylcarbazole on Pt(111) ChemSusChem 2013, 6, 974-977
18. 3 Model Catalysts Chem. - Eur. J. 2011, 17, 11542-11552
19. Libuda, J.; Winkelmann, F.; Baeumer, M.; Freund, H.-J.; Bertrams, T.; Neddermeyer, H.; Mueller, K. Structure and Defects of an Ordered Alumina Film on NiAl(110) Surf. Sci. 1994, 318, 61-73
20. Kresse, G.; Schmid, M.; Napetschnig, E.; Shishkin, M.; Köhler, L.; Varga, P. Structure of the Ultrathin Aluminum Oxide Film on NiAl(110) Science 2005, 308, 1440
21. Libuda, J.; Freund, H.-J. Molecular Beam Experiments on Model Catalysts Surf. Sci. Rep. 2005, 57, 157-298
22. Jóhanek, V.; Schauermann, S.; Laurin, M.; Libuda, J.; Freund, H.-J. Site Occupation and Activity of Catalyst Nanoparticles Monitored by In Situ Vibrational Spectroscopy Angew. Chem., Int. Ed. 2003, 42, 3035-3039
23. 3/NiAl(110) under UHV Conditions Phys. Chem. Chem. Phys. 2012, 14, 10603-10612
24. Sobota, M.; Happel, M.; Amende, M.; Paape, N.; Wasserscheid, P.; Laurin, M.; Libuda, J. Ligand Effects in SCILL Model Systems: Site-Specific Interactions with Pt and Pd Nanoparticles Adv. Mater. 2011, 23, 2617-2621
25. 2N] Thin Films on a Well-Ordered Alumina Surface Langmuir 2010, 26, 7199
26. Libuda, J.; Bäumer, M.; Freund, H.-J. Structural Characterization of Platinum Deposits Supported on Ordered Alumina Films J. Vac. Sci. Technol., A 1994, 12, 2259-2264
27. Winkelmann, F.; Wohlrab, S.; Libuda, J.; Bäumer, M.; Cappus, D.; Menges, M.; Al-Shamery, K.; Kuhlenbeck, H.; Freund, H.-J. Adsorption on Oxide Surfaces: Structure and Dynamics Surf. Sci. 1994, 307-309, 1148-1160
28. 3(111)/NiAl(110): A TEM Study Surf. Sci. 2003, 539, 31-36
29. 3/NiAl(110) Surf. Sci. 1995, 331-333, 1515-1519
30. Bäumer, M.; Freund, H.-J. Metal Deposits on Well-Ordered Oxide Films Prog. Surf. Sci. 1999, 61, 127-198
31. Schauermann, S.; Hoffmann, J.; Johánek, V.; Hartmann, J.; Libuda, J. Adsorption, Decomposition and Oxidation of Methanol on Alumina Supported Palladium Particles Phys. Chem. Chem. Phys. 2002, 4, 3909
32. Crawford, P.; Burch, R.; Hardacre, C.; Hindle, K. T.; Hu, P.; Rooney, D. W. The Energetics of Tetrahydrocarbazole Aromatization over Pd(111): A Computational Analysis J. Chem. Phys. 2008, 128, 105104
33. Amende, M. Model Experiments on the Dehydrogenation of Dodecahydro-N-ethylcarbazole. Dipl. Thesis, FAU Erlangen-Nürnberg, Erlangen, Germany, 2012.
34. Vines, F.; Lykhach, Y.; Staudt, T.; Lorenz, M. P. A.; Libuda, J.; Papp, C.; Steinrück, H.-P.; Neyman, K. M.; Görling, A. Methane Activation by Platinum: Critical Role of Edge and Corner Sites of Metal Nanoparticles Chem. - Eur. J. 2010, 16, 6530-6539
35. Lykhach, Y.; Staudt, T.; Tsud, N.; Skála, T.; Prince, K. C.; Matolín, V.; Libuda, J. Enhanced Reactivity of Pt Nanoparticles Supported on Ceria Thin Films during Ethylene Dehydrogenation Phys. Chem. Chem. Phys. 2011, 13, 253-261
36. Chaudhuri, R. G.; Paria, S. Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Chem. Rev. 2012, 112, 2373-2433
37. Esparza, R.; García-Ruiz, A. F.; Salazar, J. J. V.; Pérez, R.; José-Yacamán, M. Structural Characterization of Pt-Pd Core-Shell Nanoparticles by Cs-Corrected STEM J. Nanopart. Res. 2013, 15, 1342
38. Lei, Y.; Liu, B.; Lu, J.; Lobo-Lapidus, R. J.; Wu, T.; Feng, H.; Xia, X.; Mane, A. U.; Libera, J. A.; Greenley, J. P. Synthesis of Pt-Pd Core-Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene Chem. Mater. 2012, 24, 3525-3533
39. Schauermann, S.; Hoffmann, J.; Johánek, V.; Hartmann, J.; Libuda, J.; Freund, H.-J. Catalytic Activity and Poisoning of Specific Sites on Supported Metal Nanoparticles Angew. Chem. 2002, 41, 2532-2535
40. Fuhrmann, T.; Kinne, M.; Whelan, C. M.; Zhu, J. F.; Denecke, R.; Steinrück, H.-P. Vibrationally Resolved In Situ XPS Study of Activated Adsorption of Methane on Pt(111) Chem. Phys. Lett. 2004, 390, 208-213
41. Jaeger, R. M.; Kuhlenbeck, H.; Freund, H.-J.; Wuttig, M.; Hoffmann, W.; Franchy, R.; Ibach, H. Formation of a Well-Ordered Aluminium Oxide Overlayer by Oxidation of NiAl(110) Surf. Sci. 1991, 259, 235-252