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Direct extraction of the tilt angle from X-ray diffraction has been done which gives similar tendency that the tilt angle ω reached it's maximum at x = 0.05 and decreased with further increasing of x. However, the increasement of the tilt angle Δω ∼ 1.3° is larger than that from Raman data and Fe-O-Fe angles. It is probably that in this direct calculations the distortion from the transverse shift of the oxygen ions might be not excluded
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Direct extraction of the tilt angle from X-ray diffraction has been done which gives similar tendency that the tilt angle ω reached it's maximum at x = 0.05 and decreased with further increasing of x. However, the increasement of the tilt angle Δω ∼ 1.3° is larger than that from Raman data and Fe-O-Fe angles. It is probably that in this direct calculations the distortion from the transverse shift of the oxygen ions might be not excluded.
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