Pulsed-Field gradient NMR self diffusion and ionic conductivity measurements for liquid electrolytes containing libf4 and propylene carbonate

Electrochimica Acta

Volumn 130, Issue , 2014, Pages 606-618

  Richardson, P M ^a   Voice, A M ^a   Ward, I M ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

Conductivity; Ionic association; Liquid electrolyte; NMR

Indexed keywords

ASSOCIATION REACTIONS; DIFFUSION IN LIQUIDS; ELECTRIC CONDUCTIVITY; ELECTROLYTES; IONIC CONDUCTIVITY; LITHIUM; NUCLEAR MAGNETIC RESONANCE; POSITIVE IONS; VISCOSITY;

CONDUCTIVITY MEASUREMENTS; IONIC ASSOCIATION; LIQUID ELECTROLYTES; LITHIUM TETRAFLUOROBORATE; NERNST-EINSTEIN EQUATION; PULSED-FIELD GRADIENT NMR; PULSED-FIELD GRADIENTS; SELF-DIFFUSION COEFFICIENTS;

LIQUIDS;

EID: 84898444406     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.03.072     Document Type: Article

References (69)

1. P.V. Wright Recent trends in polymer electrolytes based on poly(ethylene oxide) Journal of Macromolecular Science-Chemistry A26 1989 519 550
2. M. Armand Polymer solid electrolytes - an overview Solid State Ionics 9-10 1983 745 754
3. S.A. Dobrowski, G.R. Davies, J.E. McIntyre, and I.M. Ward Ionic conduction in poly(n,n-dimethyl-acrylamide) gels complexing lithium salts Polymer 32 1991 2887 2891
4. N. Boden, S.A. Leng, and I.M. Ward Ionic-conductivity and diffusivity in polyethylene oxide electrolyte-solutions as models for polymer electrolytes Solid State Ionics 45 1991 261 270 (Pubitemid 21651985)
5. A.M. Voice, J.P. Southall, V. Rogers, K.H. Matthews, G.R. Davies, J.E. Mclntyre, and I.M. Ward Thermoreversible polymer gel electrolytes Polymer 35 16 1994 3363 3372
6. I.M. Ward, and H.V.St.A. Hubbard Polymer electrolytes: conduction mechanisms and battery applications, Chapter 21, in Ionic interactions in natural and synthetic macromolecules 2012 Wiley and Sons Inc
7. J.E. McIntyre, I.M. Ward, H.V.St.A. Hubbard, and V. Rogers, Uk patent application pct/gb92/01781. 1992.
8. P.M. Richardson, A.M. Voice, and I.M. Ward Two distinct lithium diffusive species for polymer gel electrolytes containing LiBF4, propylene carbonate (PC) and PVDF The International Journal of Hydrogen Energy 39 6 2014 2904 2908
9. P.M. Richardson, A.M. Voice, and I.M. Ward, Nmr t1 relaxation time measurements and calculations with translational and rotational components for liquid electrolytes containing libf4 and propylene carbonate. 139 (2013) 214501.
10. K. Hayamizu, Y. Aihara, S. Arai, and W.S. Price Self-diffusion coefficients of lithium, anion, polymer, and solvent in polymer gel electrolytes measured using li-7,f-19, and h-1 pulsed-gradient spin-echo nmr Electrochimica Acta 45 2000 1313 1319 (Pubitemid 30526856)
11. Y. Aihara, T. Bando, H. Nakagawa, H. Yoshida, K. Hayamizu, E. Akiba, and W.S. Price Ion transport properties of six lithium salts dissolved in gamma-butyrolactone studied by self-diffusion and ionic conductivity measurements Journal of The Electrochemical Society 151 1 2004 A119 A122
12. M.S. Ding Electrolytic conductivity and glass transition temperatures as functions of salt content, solvent composition, or temperature for libf4 in propylene carbonate plus diethyl carbonate Journal of Chemical and Engineering Data 49 2004 1102 1109
13. M.S. Ding, and T.R. Jow How conductivities and viscosities of pc-dec and pc-ec solutions of libf4, lipf6, libob, et4nbf4, and et4npf6 differ and why Journal of The Electrochemical Society 151 12 2004 A2007 A2015
14. G. Moumouzias, G. Ritzoulis, D. Siapkas, and D. Terzidis Comparative study of LiBF4, LiAsF6, LiPF6, and LiClO4 as electrolytes in propylene carbonate-diethyl carbonate solutions for Li/LiMn2O4 cells Journal of Power Sources 122 1 2003 57 66 (Pubitemid 41197313)
15. M.S. Ding Conductivity and viscosity of PC-DEC and PC-EC solutions of LiBF4 Journal of The Electrochemical Society 151 1 2004 A40 A47
16. P.K. Muhuri, and D.K. Hazra Electrical conductances for some tetraalkylammonium bromides, lithium tetrafluoroborate and tetrabutylammonium tetrabutylborate in propylene carbonate at 25 [degree]c Journal of the Chemical Society, Faraday Transactions 87 1991 3511 3513
17. H. Tsunekawa, A. Narumi, M. Sano, A. Hiwara, M. Fujita, and H. Yokoyama Solvation and ion association studies of libf4-propylenecarbonate and libf4-propylenecarbonate-trimethyl phosphate solutions Journal of Physical Chemistry B 107 2003 10962 10966
18. Y. Saito, H. Yamamoto, H. Kageyama, O. Nakamura, T. Miyoshi, and M. Matsuoka Investigation of the solution condition of lithium electrolyte solutions with LiCF3SO3 salt Journal of Materials Science 35 4 2000 809 812 (Pubitemid 30553613)
19. Y. Aihara, K. Sugimoto, W.S. Price, and K. Hayamizu Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes The Journal of Chemical Physics 113 5 2000 1981 1991
20. K. Hayamizu, and Y. Aihara Ion and solvent diffusion and ion conduction of PC-DEC and PC-DME binary solvent electrolytes of LiN(SO2CF3)2 Electrochimica Acta 49 20 2004 3397 3402
21. K. Hayamizu Temperature dependence of self-diffusion coefficients of ions and solvents in ethylene carbonate, propylene carbonate, and diethyl carbonate single solutions and ethylene carbonate + diethyl carbonate binary solutions of LiPF6 studied by NMR Journal of Chemical & Engineering Data 57 7 2012 2012 2017
22. J.S. Kim, Z. Wu, A.R. Morrow, A. Yethiraj, and A. Yethiraj Self-diffusion and viscosity in electrolyte solutions The Journal of Physical Chemistry B 116 39 2012 12007 12013
23. K. Kuratani, N. Uemura, H. Senoh, H.T. Takeshita, and T. Kiyobayashi Conductivity, viscosity and density of MClO4 (m = li and na) dissolved in propylene carbonate and gamma-butyrolactone at high concentrations Journal of Power Sources 223 2013 175 182
24. H.V.St.A. Hubbard, J.P. Southall, J.M. Cruickshank, G.R. Davies, and I.M. Ward A comparison of ionic conductivity behaviour in various ethylene oxide based polymer electrolytes Electrochimica Acta 43 10-11 1998 1485 1492 (Pubitemid 128409750)
25. M.J. Williamson, J.P. Southall, H.V.St.A. Hubbard, S.F. Johnston, G.R. Davies, and I.M. Ward Nmr measurements of ionic mobility in model polymer electrolyte solutions Electrochimica Acta 43 10-11 1998 1415 1420 (Pubitemid 128409738)
26. M.J. Williamson, J.P. Southall, H.V.St.A. Hubbard, G.R. Davies, and I.M. Ward Pulsed field gradient nmr diffusion measurements on electrolyte solutions containing licf3so3 Polymer 40 1999 3945 3955 (Pubitemid 30122484)
27. I.M. Ward, M.J. Williamson, H.V.St.A. Hubbard, J.P. Southall, and G.R. Davies Nmr studies of ionic mobility in polymer gel electrolytes for advanced lithium batteries Journal of Power Sources 81-82 1999 700 704 (Pubitemid 32077906)
28. R.M. Cotts, M.J.R. Hoch, T. Sun, and J.T. Markert Pulsed field gradient stimulated echo methods for improved nmr diffusion measurements in heterogeneous systems Journal of Magnetic Resonance 83 1989 252 266
29. K. Levenberg A method for the solution of certain non-linear problems in least squares Quarterly of Applied Mathematics 2 1944 164 168
30. D. Marquardt An algorithm for least-squares estimation of nonlinear parameters SIAM Journal on Applied Mathematics 11 2 1963 431 441
31. J. Barthel, R. Neueder, and H. Roch Density, relative permittivity, and viscosity of propylene carbonate plus dimethoxyethane mixtures from 25 degrees c to 125 degrees c Journal of Chemical and Engineering Data 45 6 2000 1007 1011 (Pubitemid 32022979)
32. G. Annat, D.R. MacFarlane, and M. Forsyth Transport properties in ionic liquids and ionic liquid mixtures: The challenges of NMR pulsed field gradient diffusion measurements The Journal of Physical Chemistry B 111 30 2007 9018 9024 (Pubitemid 47317481)
33. H.L. Yeager, J.D. Fedyk, and R.J. Parker Spectroscopic studies of ionic solvation in propylene carbonate Journal of Physical Chemistry 77 20 1973 2407 2410
34. H. Ohtani, Y. Hirao, A. Ito, K. Tanaka, and O. Hatozaki Theoretical study on thermochemistry of solvated lithium-cation with propylene carbonate Journal of Thermal Analysis Calorimetry 99 2010 139 144
35. Kikuko Hayamizu, Yuichi Aihara, Shigemasa Arai, and Garcia, Pulse-gradient spin-echo 1H, 7Li, and 19F NMR diffusion and ionic conductivity measurements of 14 organic electrolytes containing LiN(SO2CF3)2. The Journal of Physical Chemistry B, 103 (3) (1999) 519-524. (Pubitemid 129680716)
36. Kazutaka Kondo, Mitsuru Sano, Akio Hiwara, Takehiko Omi, Miho Fujita, Akio Kuwae, Masayasu Iida, Koichi Mogi, and Haruhiko Yokoyama, Conductivity and solvation of li+ ions of LiPF6 in propylene carbonate solutions. The Journal of Physical Chemistry B, 104(20)(2000)5040-5044.
37. T. Fromling, M. Kunze, M. Schonhoff, J. Sundermeyer, and B. Roling Enhanced lithium transference numbers in ionic liquid electrolytes The Journal of Physical Chemistry B 112 41 2008 12985 12990
38. C. Capiglia, Y. Saito, H. Kageyama, P. Mustarelli, T. Iwamoto, T. Tabuchi, and H. Tukamoto Li-7 and f-19 diffusion coefficients and thermal properties of non-aqueous electrolyte solutions for rechargeable lithium batteries Journal of Power Sources 81-82 1999 859 862 (Pubitemid 32077936)
39. K. Hayamizu, and W.S. Price A new type of sample tube for reducing convection effects in PGSE-NMR measurements of self-diffusion coefficients of liquid samples Journal of Magnetic Resonance 167 2 2004 328 333
40. A.M. Christie, and C.A. Vincent Conductivities of selected lithium salt complexes in propylene carbonate The Journal of Physical Chemistry 100 11 1996 4618 4621 (Pubitemid 126834768)
41. M.S. Ding, and T.R. Jow Conductivity and viscosity of PC-DEC and PC-EC solutions of LiPF6 Journal of The Electrochemical Society 150 5 2003 A620 A628
42. M.S. Ding, K. Xu, and T.R. Jow Conductivity and viscosity of PC-DEC and PC-EC solutions of LiBOB Journal of The Electrochemical Society 152 1 2005 A132 A140
43. M.S. Ding Electrolytic conductivity and glass transition temperatures as functions of salt content, solvent composition, or temperature for LiBF4 in propylene carbonate + diethyl carbonate Journal of Chemical & Engineering Data 49 4 2004 1102 1109
44. J. Cruickshank, H.V.St.A. Hubbard, N. Boden, and I.M. Ward The role of ionic salts in determining t-g and ionic-conductivity in concentrated peg electrolyte-solutions Polymer 36 19 1995 3779 3781
45. K. Hayamizu, E. Akiba, T. Bando, and Y. Aihara 1h, 7li, and 19f nuclear magnetic resonance and ionic conductivity studies for liquid electrolytes composed of glymes and polyetheneglycol dimethyl ethers of CH3O(CH2CH2O)nCH3 (n = 3-50) doped with LiN(SO2CF3)2 The Journal of Chemical Physics 117 12 2002 5929 5939
46. T.J. Simons, P.C. Howlett, A.A.J. Torriero, D.R. MacFarlane, and M. Forsyth Electrochemical, transport, and spectroscopic properties of 1-ethyl-3-methylimidazolium ionic liquid electrolytes containing zinc dicyanamide The Journal of Physical Chemistry C 117 6 2013 2662 2669
47. Y. Aihara, S. Arai, and K. Hayamizu Ionic conductivity, dsc and self diffusion coefficients of lithium, anion, polymer, and solvent of polymer gel electrolytes: the structure of the gels and the diffusion mechanism of the ions Electrochimica Acta 45 2000 1321 1326 (Pubitemid 30526857)
48. J.F. Casteel, and E.S. Amis Specific conductance of concentrated solutions of magnesium salts in water-ethanol system Journal of Chemical and Engineering Data 17 1 1972 55 59
49. A. de Diego, J.M. Madariaga, and E. Chapela Empirical model of general application to fit (k,c,t) experimental data from concentrated aqueous electrolyte solutions Electrochimica Acta 42 9 1997 1449 1456 (Pubitemid 127380891)
50. M.S. Ding Casteel-amis equation: Its extension from univariate to multivariate and its use as a two-parameter function Journal of Chemical & Engineering Data 49 5 2004 1469 1474
51. Q. Zhang, S. Sun, S. Pitula, Q. Liu, U. Welz-Biermann, and J. Zhang Electrical conductivity of solutions of ionic liquids with methanol, ethanol, acetonitrile, and propylene carbonate Journal of Chemical & Engineering Data 56 12 2011 4659 4664
52. G. Jones, and M. Dole The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride Journal of the American Chemical Society 51 1929 2950
53. J. Jiang, and S.I. Sandler A new model for the viscosity of electrolyte solutions Industrial & Engineering Chemistry Research 42 25 2003 6267 6272 (Pubitemid 37517523)
54. H. Jenkins, B. Donald, and Y. Marcus Viscosity b-coefficients of ions in solution Chemical Reviews 95 8 1995 2695 2724
55. G. Jones, and S.K. Talley The viscosity of aqueous solutions as a function of the concentration Journal of the American Chemical Society 55 2 1933 624 642
56. M. Kaminsky Z. Phys. Chem 12 1957 206
57. G. Hefter, P.M. May, P. Sipos, and A. Stanley Viscosities of concentrated electrolyte solutions Journal of Molecular Liquids 103-104 2003 261 273
58. A.L. Horvath Handbook of aqueous electrolyte solutions: physical properties, estimation and correlation methods 1985 Ellis Horwood
59. M. Deepa, N. Sharma, S.A. Agnihotry, S. Singh, T. Lal, and R. Chandra Conductivity and viscosity of liquid and gel electrolytes based on liclo4, lin(cf3so2)(2) and pmma Solid State Ionics 152-153 2002 253 258 (Pubitemid 35458993)
60. K. Hayamizu, A. Matsuo, and J. Arai A divalent lithium salt Li2B12F12 dissolved in propylene carbonate studied by nmr methods Journal of The Electrochemical Society 156 9 2009 A744 A750
61. M. Takeuchi, Y. Kameda, Y. Umebayashi, S. Ogawa, T. Sonoda, S. Ishiguro, M. Fujita, and M. Sano Ion-ion interactions of lipf6 and libf4 in propylene carbonate solutions Journal of Molecular Liquids 148 2009 99 108
62. R. Olender, and A. Nitzan Ion solvation and association in complex solvents: Theoretical considerations Electrochimica Acta 37 9 1992 1505 1509 (Pubitemid 23631215)
63. M. Forsyth, V.A. Payne, M.A. Ratner, S.W. de Leeuw, and D.F. Shriver Molecular dynamics simulations of highly concentrated salt solutions: Structural and transport effects in polymer electrolytes Solid State Ionics 53-56 Part 2 1992 1011 1026
64. R. Zarrougui, M. Dhahbi, and D. Lemordant Effect of temperature and composition on the transport and thermodynamic properties of binary mixtures of ionic liquid n-butyl-n-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide and propylene carbonate Journal of Solution Chemistry 39 7 2010 921 942
65. K. Umemoto, and N. Matsuura Formulation of stokes radii in DMF, DMSO and propylene carbonate with solvent structure cavity size as parameter Bulletin of The Chemical Society of Japan - BULL CHEM SOC JPN 48 8 1975 2253 2257
66. M. Ue Mobility and ionic association of lithium and quaternary ammonium salts in propylene carbonate and gamma-butyrolactone Journal of The Electrochemical Society 141 12 1994 3336 3342
67. Y. Saito, H. Yamamoto, O. Nakamura, H. Kageyama, H. Ishikawa, T. Miyoshi, and M. Matsuoka Determination of ionic self-diffusion coefficients of lithium electrolytes using the pulsed field gradient nmr Journal of Power Sources 81-82 1999 772 776 (Pubitemid 32077920)
68. O. Soderman, W.S. Price, M. Schonhoff, and D. Topgaard NMR diffusometry applied to liquids Journal of Molecular Liquids 156 1 2010 38 44
69. M. Ue Ionic radius of (cf3so2)3c - and applicability of stokes law to its propylene carbonate solution Journal of The Electrochemical Society 143 11 1996 L270 L272