A new type of sample tube for reducing convection effects in PGSE-NMR measurements of self-diffusion coefficients of liquid samples

Journal of Magnetic Resonance

Volumn 167, Issue 2, 2004, Pages 328-333

  Hayamizu, Kikuko ^a   Price, William S ^b  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b UNIVERSITY OF WESTERN SYDNEY   (Australia)

Author keywords

Convection; Diffusion; Ion ion and ion solvent interactions; Low viscosity liquid; NMR tube; PGSE NMR

Indexed keywords

DIFFUSION; ELECTROCHEMISTRY; ELECTROLYTES; ELECTROMAGNETIC WAVE ATTENUATION; HEAT CONVECTION; LITHIUM; NUCLEAR MAGNETIC RESONANCE; THERMAL EFFECTS; VISCOSITY;

ION-ION AND ION-SOLVENT INTERACTIONS; LOW VISCOSITY LIQUID; NMR TUBES; PGSE-NMR;

MAGNETIC RESONANCE;

EID: 1642266431     PISSN: 10907807     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jmr.2004.01.006     Document Type: Article

References (27)

1. Benard H. Les tourbillons celluaries dans une nappe liquide transportant de la chaleur par convection en regime permanent. Ann. Chim. Phys. 23:1901;62-144.
2. Rayleigh L. On convection currents on a horizontal layer of fluid when the higher temperature is on the under side. Philos. Mag. 32:1914;529-546.
3. Lounila J., Oikarinen K., Ingman P., Jokisaari J. Effects of thermal convection on NMR and their elimination by sample rotation. J. Magn. Reson. A. 118:1996;50-54.
4. Goux W.J., Verkruyse L.A., Salter S.J. The impact of Rayleigh-Benard convection on NMR pulsed field gradient diffusion measurements. J. Magn. Reson. 88:1990;609-614.
5. 1H NMR and suppression of convection in NMR probes. J. Magn. Reson. 131:1998;126-130.
6. Augé S., Amblard-Blondel B., Delsuc M.-A. Investigation of the diffusion measurement using PFG and test of robustness against experimental conditions and parameters. J. Chim. Phys. 96:1999;1559-1565.
7. 8 micelles with increasing temperature. A convection-compensated PGSE-NMR study. Langmuir. 16:2000;7548-7550.
8. Price W.S. Diffusion-based studies of aggregation, binding and conformation of biomolecules: theory and practice. Grant D.M., Harris R.K. Encyclopedia of Nuclear Magnetic Resonance. 2002;364-374 Wiley, New York.
9. Manz B., Seymour J.D., Callaghan P.T. PGSE NMR measurements of convection in a capillary. J. Magn. Reson. 125:1997;153-158.
10. Loening N.M., Keeler J. Measurement of convection and temperature profiles in liquid samples. J. Magn. Reson. 139:1999;334-341.
11. Jerschow A. Thermal convection currents in NMR: flow profiles and implications for coherence pathway selection. J. Magn. Reson. 145:2000;125-131.
12. Mohoric A., Stepišnik J. Effect of natural convection in a horizontally oriented cylinder on NMR imaging of the distribution of diffusivity. Phys. Rev. E. 62:2000;6628-6635.
13. Saarinen T.R., Johnson C.S. Jr. Imaging of transient magnetization gratings in NMR. Analogies with laser-induced gratings and applications to diffusion and flow. J. Magn. Reson. 78:1988;257-270.
14. Jerschow A., Müller N. Suppression of convection artifacts in stimulated-echo diffusion experiments. Double-stimulated-echo experiments. J. Magn. Reson. 125:1997;372-375.
15. Sørland G.H., Seland J.G., Krane J., Anthonsen H.W. Improved convection compensating pulsed field gradient spin-echo and stimulated-echo methods. J. Magn. Reson. 142:2000;323-325.
16. Zhang X., Li C.-G., Ye C.-H., Liu M.-L. Determination of molecular self-diffusion coefficient using multiple spin-echo NMR spectroscopy with removal of convection and background gradient artifacts. Anal. Chem. 73:2001;3528-3534.
17. Esturau N., Sánchez-Ferrando F., Gavin J.A., Roumestand C., Delsuc M.-A., Parella T. The use of sample rotation for minimizing convection effects in self-diffusion measurements. J. Magn. Reson. 153:2001;48-55.
18. 2 J. Chem. Phys. 117:2002;5929-5939.
19. Price W.S., Stilbs P., Jönsson B., Söderman O. Macroscopic background gradient and radiation damping effects on high-field PGSE-NMR diffusion measurements. J. Magn. Reson. 150:2001;49-56.
20. 3 systems: implications for the mechanism of ionic transport. Macromolecules. 34:2001;2660-2666.
21. Kearley G.J., Johansson P., Delaplane R.G., Lindgren J. Structure, vibrational-dynamics and first-principles study of diglyme as a model system for poly(ethyleneoxide). Solid State Ionics. 147:2002;237-242.
22. Borodin O., Smith G.D. Molecular dynamics simulations study of LiI-doped diglyme and poly(ethylene oxide) solutions. J. Phys. Chem. B. 104:2000;8017-8022.
23. 2. Restricted diffusion of the polymer and lithium ion and time-dependent diffusion of the anion. Macromolecules. 36:2003;2785-2792.
24. Hayamizu K., Akiba E., Price W.S. Ion diffusion restricted by time-dependent barriers in a viscous polyethylene-based liquid electrolyte. Macromolecules. 36:2003;8596-8598.
25. Ue M. Mobility and ionic association of lithium and quaternary ammonium salts in propylene carbonate and γ-butyrolactone. J. Electrochem. Soc. 141:1994;3336-3342.
26. 2. J. Phys. Chem. B. 103:1999;519-524.
27. Aihara Y., Bando T., Nakagawa H., Yoshida H., Hayamizu K., Akiba E., Price W.S. Ion transport properties of six lithium salts dissolved in γ-butyrolactone studied by self-diffusion and ionic conductivity measurements. J. Electrochem. Soc. 15:2004;A119-A122.