A review on Fenton and improvements to the Fenton process for wastewater treatment

Journal of Environmental Chemical Engineering

Volumn 2, Issue 1, 2014, Pages 557-572

  Babuponnusami, Arjunan ^a   Muthukumar, Karuppan ^b  

^a ADHIPARASAKTHI ENGINEERING COLLEGE   (India)

^b ANNA UNIVERSITY   (India)

Author keywords

Advanced oxidation processes; Fenton; Hybrid Fenton; Nano zero valent iron

Indexed keywords

OXIDATION RESISTANCE; REFRACTORY MATERIALS; WASTEWATER TREATMENT;

ADVANCED OXIDATION PROCESS; ADVANCED OXIDATION PROCESSES; ELECTRO-FENTON; FENTON; FENTON PROCESS; HYBRID FENTON; REFRACTORY COMPOUNDS; VALENT IRON;

WASTEWATER DISPOSAL;

EID: 84897114623     PISSN: None     EISSN: 22133437     Source Type: Journal    
DOI: 10.1016/j.jece.2013.10.011     Document Type: Review

References (166)

1. A. Garg, I.M. Mishra, and S. Chand Oxidative phenol degradation using non-noble metal based catalysts CLEAN 38 2010 27 34
2. L.A. Bernal-Martinez, C. Barrera-Diaz, C. Solis-Morelos, and N. Reyna Synergy of electrochemical and ozonation processes in industrial wastewater treatment Chem. Eng. J. 165 2010 71 77
3. A. Cybulski Catalytic wet air oxidation: are monolithic catalyst and reactors feasible? Ind. Eng. Chem. Res. 46 2007 4007 4033
4. P. Kritzer, and E. Dinjus An assessment of supercritical water oxidation (SCWO): existing problems, possible solutions and new reactor concepts Chem. Eng. J. 83 2001 207 214
5. S.T. Kolaczkowski, P. Plucinski, F.J. Beltran, F.J. Rivas, and D.B. McLurgh Wet air oxidation: a review of process technologies and aspects in reactor design Chem. Eng. J. 73 1999 143 160
6. J. Levec, and A. Pintar Catalytic wet air oxidation processes. A review Catal. Today 124 2007 172 184
7. S. Malato, J. Blanco, A. Vidal, and C. Richter Photocatalysis with solar energy at a pilot-plant scale: an overview Appl. Catal. B: Environ. 37 2002 1 15
8. W.H. Glaze, J.W. Kang, and D.H. Chapin The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation Ozone Sci. Eng. 9 1987 335 352
9. J. Hoigne Inter-calibration of OH radical sources and water quality parameters Water Sci. Technol. 35 1997 1 8
10. R.C. Weast Hand Book of Chemistry and physics 58th ed. 1977 CRC Press Ohio
11. R. Munter Advanced oxidation processes-current status and prospects Proc. Est. Acad. Sci. Chem. 50 2001 59 80
12. M. Klavarioti, D. Mantzavinos, and D. Kassinos Removal of residual pharmaceutical from aqueous systems by advanced oxidation processes Environ. Int. 35 2009 402 417
13. J.V. Anderson, H. Link, M. Bohn, and B. Gupta Development of solar detoxification technology in the USA: an introduction Sol. Energy Mater. 24 1991 538 549
14. H.J.H. Fenton Oxidation of tartaric acid in the presence of iron J. Chem. Soc. Trans. 65 1894 899 910
15. -) in aqueous solution J. Phys. Chem. Ref. Data 17 1988 513 886
16. E. Neyens, and J. Baeyens A review of classic Fenton's peroxidation as an advanced oxidation technique J. Hazard. Mater. 98 2003 33 50
17. P. Bautista, A.F. Mohedano, J.A. Casas, J.A. Zazo, and J.J. Rodriguez An overview of the application of Fenton oxidation to industrial wastewaters treatment J. Chem. Technol. Biotechnol. 83 2008 1323 1338
18. 2 and of the oxidation of organic substrates Russ. Chem. Rev. 64 1995 1105 1129
19. J.J. Pignatello, E. Oliveros, and A. Mackay Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry Crit. Rev. Environ. Sci. Tech. 36 2006 1 84
20. C.T. Benatti, A.C.S. Da-Costa, and C.R.G. Tavares Characterization of solids originating from the Fenton's process J. Hazard. Mater. 163 2009 1246 1253
21. E. Chamarro, A. Marco, and S. Esplugas Use of Fenton reagent to improve organic chemical biodegradability Water Res. 35 2001 1047 1051
22. E.M. Siedlecka, and P. Stepnowski Phenols degradation by Fenton reaction in the presence of chlorides and sulfates Pol. J. Environ. Stud. 14 2005 823 828
23. P.J.D. Ranjit, K. Palanivelu, and C.S. Lee Degradation of 2,4-dichlorophenol in aqueous solution by sono-Fenton method Korean J. Chem. Eng. 25 2008 112 117
24. M.S. Yalfani, S. Contreras, F. Medina, and J. Sueiras Phenol degradation by Fenton's process using catalytic in situ generated hydrogen peroxide Appl. Catal. B: Environ. 89 2009 519 526
25. A.A. Burbano, D.D. Dionysiou, M.T. Suidan, and T.L. Richardson Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent Water Res. 39 2005 107 118
26. C. Jiang, S. Pang, F. Ouyang, J. Ma, and J. Jiang A new insight into Fenton and Fenton-like processes for water treatement J. Hazard. Mater. 174 2010 813 817
27. S.H. Lin, and C.C. Lo Fenton process for treatment of desizing wastewater Water Res. 31 1997 2050 2056
28. S.H. Lin, C.M. Lin, and H.G. Leu Operating characteristics and kinetics studies of surfactant wastewater treatment by Fenton oxidation Water Res. 33 1999 1735 1741
29. G. Lofrano, L. Rizzo, M. Grassi, and V. Belgiorno Advanced oxidation of catechol: a comparison among photocatalysis, Fenton and photo-Fenton processes Desalination 249 2009 878 883
30. D.L. Sedlak, and A.W. Andren Oxidation of chlorobenzene with Fenton's reagent Environ. Sci. Technol. 25 1991 777 782
31. Y.W. Kang, and K.Y. Hwang Effects of reaction conditions on the oxidation efficiency in the Fenton process Water Res. 34 2000 2786 2790
32. F.J. Rivas, F.J. Beltran, J. Frades, and P. Buxeda Oxidation of p-hydroxybenzoic acid by Fenton's reagent Water Res. 35 2001 387 396
33. H.R. Eisenhauer Oxidation of phenolic wastes J. Water Pollut. Control Fed. 36 1964 1116 1128
34. Y.S. Ma, S.T. Huang, and J.G. Lin Degradation of 4-nitro phenol using the Fenton process Water Sci. Technol. 42 2000 155 160
35. A. Babuponnusami, and K. Muthukumar Degradation of phenol in aqueous solution by Fenton, sono-Fenton, Sono-photo-Fenton methods Clean-Soil Air Water 39 2011 142 147
36. S. Parsons Advanced Oxidation Processes for Water and Wastewater Treatment 2004 IWA Publishing London
37. S.H. Bossmann, E. Oliveros, S. Gob, S. Siegwart, E.P. Dahlen, Payawan Jr., M. Straub, M. Worner, and A.M. Braun New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced Fenton reaction J. Phys. Chem. 102 1998 5542 5550
38. L. Szpyrkowicz, C. Juzzolino, and S.N. Kaul A Comparative study on oxidation of disperse dye by electrochemical process, ozone, hypochlorite and Fenton reagent Water Res. 35 2001 2129 2136
39. V. Kavitha, and K. Palanivelu Destruction of cresols by Fenton oxidation process Water Res. 39 2005 3062 3072
40. 2 processes Sep. Purif. Technol. 68 2009 261 266
41. B.G. Kwon, D.S. Lee, N. Kang, and J. Yoon Characteristics of p-chlorophenol oxidation by Fentons reagent Water Res. 33 1999 2110 2118
42. F.J. Benitez, J.L. Acero, F.J. Real, F.J. Rubio, and A.I. Leal The role of hydroxyl radicals for the decomposition of p-hydroxy phenylacetic acid in aqueous solutions Water Res. 35 2001 1338 1343
43. 3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide Environ. Sci. Technol. 26 1992 944 951
44. K. Ito, W. Jian, W. Nishijima, A.U. Baes, E. Shoto, and M. Okada Comparison of ozonation and AOPs combined with biodegradation for removal of THM precursors in treated sewage effluents Water Sci. Technol. 38 1998 179 186
45. F.K. Nesheiwat, and A.G. Swanson Clean contaminated sites using Fenton's reagent Chem. Eng. Prog. 96 2000 61 66
46. A. Francony, and C. Petrier Sonochemical degradation of carbon tetrachloride in aqueous solution at two frequencies: 20 kHz and 500 kHz Ultrason. Sonochem. 3 1996 S77 S82
47. T.J. Mason, and E.D. Cordemans Ultrasonic intensification of chemical processing and related operations: a review Chem. Eng. Res. Des. 74 1996 511 516
48. K.S. Susick, S.J. Doktycz, and E.B. Flint On the origin of sonoluminescence and sonochemistry Ultrasonics 28 1990 280 290
49. O. Dahlem, V. Demaiffe, V. Halloin, and J. Reisse Direct sonication system suitable for medium-scale sonochemical reactors AIChE J. 44 1998 2724 2730
50. J. Liang, S. Komarov, N. Hayashi, and K. Eiki Recent trends in the decomposition of chlorinated aromatic hydrocarbons by ultrasound irradiation and Fenton's reagent J. Mater. Cycles Waste Manage. 9 2007 47 55
51. 2: isotope exchange and isotopic distribution of hydrogen peroxide J. Phys. Chem. 90 1986 1954 1956
52. N. Serpone, R. Terzian, H. Hisdaka, and E. Pelizetti Ultrasonic induced dehalogenation and oxidation of 2-, 3-, and 4-chlorophenol in air-equilibrated aqueous media. Similarities with irradiated semiconductor particulates J. Phys. Chem. 98 1994 2634 2640
53. A. Kotronarou, G. Mills, and M.R. Hoffmann Ultrasonic irradiation of p-nitrophenol in aqueous solution J. Phys. Chem. 95 1991 3630 3638
54. 2/CWO process Water Res. 33 1999 1187 1194
55. 2 process: Multivariate study by factorial design of experiments Appl. Catal. B: Environ. 66 2006 198 207
56. Z. Gou, Z. Zheng, S. Zheng, W. Hu, and R. Feng Effect of various sono-oxidation parameters on the removal of aqueous 2,4-dinitrophenol Ultrason. Sonochem. 12 2005 461 465
57. A.A. Pradhan, and P.R. Gogate Degradation of p-nitrophenol using acoustic cavitation and Fenton chemistry J. Hazard. Mater. 173 2010 517 522
58. R.Y. Emery, M. Papadaki, and D. Mantzavinos Sonochemical degradation of phenolic pollutants in aqueous solution Environ. Technol. 24 2003 1491 1500
59. Y. Nagata, M. Nakagawa, H. Okuno, Y. Mizukoshi, B. Yim, and Y. Maeda Sonochemical degradation of chlorophenols in water Ultrason. Sonochem. 7 2000 115 120
60. B. Neppolian, J.S. Park, and H. Choi Effect of Fenton-like oxidation on enhanced oxidative degradation of para-chlorobenzoic acid by ultrasonic irradiation Ultrason. Sonochem. 11 2004 273 279
61. S.N. Nam, S.K. Han, J.W. Kang, and H. Choi Kinetics and mechanism of the sonolytic destruction of non-volatile organic compounds: investigation of the sonochemical reaction zone using several OH monitoring techniques Ultrason. Sonochem. 10 2003 139 147
62. Y.S. Ma, and C.F. Sung Investigation of carbofuran decomposition by a combination of ultrasound and Fenton process Sustain. Environ. Res. 20 2010 213 219
63. 3 core-shell nanowires as iron reagent. 1. Efficient degradation of Rhodamine B by a noval sono-Fenton process J. Phys. Chem. C 111 2007 4087 4093
64. C. Pulgarin, and J. Kiwi Overview on photocatalytic and electrocatalytic pretreatment of industrial non-biodegradable pollutants and pesticides Chimia 50 1996 50 55
65. C. Comninellis, and C. Pulgarin Anodic oxidation of phenol for waste water treatment J. Appl. Electrochem. 21 1991 703 708
66. 2 anodes J. Appl. Electrochem. 23 1993 108 112
67. R. Morselli, J. Garcia-Gomez, P.A. Michaud, M.A. Rodrigo, and C. Comninellis Electro generation of hydroxyl radicals on boron-doped dimond electrodes J. Electrochem. Soc. 150 2003 D79 D83
68. M. Panizza, and G. Cerisola Application of diamond electrodes to electrochemical processes Electrochim. Acta 51 2005 191 199
69. W.P. Ting, M.C. Lu, and Y.H. Huang The reactor design and comparison of Fenton, electro-Fenton and photoelectron-Fenton processes for mineralization of benzene sulfonic acid (BSA) J. Hazard. Mater. 156 2008 421 427
70. U. Kurt, O. Apaydin, and M.T. Gonullu Reduction of COD in wastewater from an organized tannery industrial region by electro-Fenton process J. Hazard. Mater. 143 2007 33 40
71. ® and peroxi-coagulation processes using a flow reactor for waste water treatment Chemosphere 47 2002 241 248
72. C. Badellino, C.A. Rodrigues, and R. Bertazzoli Oxidation of pesticides by in situ electrogenerated hydrogen peroxide: study for the degradation of 2,4-dichlorophenoxyacetic acid J. Hazard. Mater. 137 2006 856 864
73. H. Zhang, D. Zhang, and J. Zhou Removal of COD from landfill leachate by electro-Fenton method J. Hazard. Mater. 135 2006 106 111
74. H. Zhang, C. Fei, D. Zhang, and F. Tang Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method J. Hazard. Mater. 145 2007 227 232
75. E. Guivarch, S. Trevin, C. Lahitte, and M.A. Oturan Degradation of azo dyes in water by electro-Fenton process Environ. Chem. Lett. 1 2003 38 44
76. I. Sires, C. Arias, P.L. Cabot, F. Centellas, J.A. Garrido, R.M. Rodriguez, and E. Brillas Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton Chemosphere 66 2007 1660 1669
77. M. Pimental, N. Oturan, M. Dezotti, and M.A. Oturan Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode Appl. Catal. B: Environ. 83 2008 140 149
78. C. Flox, S. Ammar, C. Arias, E. Brillas, A.V. Vargas-Zavala, and R. Abdelhedi Electro-Fenton and photoelectro-Fenton degradation of indigo carmine in acidic aqueous medium Appl. Catal. B: Environ. 67 2006 93 104
79. Y.H. Huang, C.C. Chen, G.H. Huang, and S.S. Chou Comparison of a novel electro-Fenton method with Fenton's reagent in treating a highly contaminated wastewater Water Sci. Technol. 43 2001 17 24
80. A.D. Moreno, B.A.F. Uribe, and R.M.R. Zamora Electro-Fenton as a feasible advanced treatment process to produce reclaimed water Water Sci. Technol. 50 2004 83 90
81. S. Yuan, M. Tian, Y. Cui, L. Lin, and X. Lu Treatment of nitrophenols by cathode reduction and electro-Fenton methods J. Hazard. Mater. 137 2006 573 580
82. G. Ruppert, R. Bauer, and G. Heisler The photo-Fenton reaction - an effective photochemical wastewater treatment process J. Photochem. Photobiol. A-Chem. 73 1993 75 78
83. 2/UV Environ. Sci. Technol. 27 1993 304 310
84. P.R. Gogate, and A.B. Pandit A review of imperative technologies for wastewater treatment II: hybrid methods Adv. Environ. Res. 8 2004 553 597
85. B.C. Faust, and J. Hoigne Photolysis of Fe(III)-hydroxy complexes as sources of OH radicals in clouds, fog and rain Atmos. Environ. 24A 1990 79 89
86. R. Bauer, and H. Fallmann The photo-Fenton oxidation - a cheap and efficient wastewater treatment method Res. Chem. Intermed. 23 1997 341 354
87. R.G. Zepp, B.C. Faust, and J. Hoigne Hydroxyl radical formation in aqueous reactions (pH 3-8) of iron(II) with hydrogen peroxide: the photo-Fenton reaction Environ. Sci. Technol. 26 1992 313 319
88. B.D. McGinnis, V.D. Adams, and E.J. Middlebrooks Degradation of ethylene glycol in photo Fenton systems Water Res. 34 2000 2346 2354
89. A. Safarzadeh-Amiri, J.R. Bolton, and S.R. Cater Ferrioxalate-mediated photodegradation of organic pollutants in contaminated water Water Res. 31 1997 787 798
90. I.S. De Oliveira, L. Viana, C. Verona, V.L.V. Fallavena, C.M.N. Azevedo, and M. Pires Alkydic resin wastewaters treatment by Fenton and photo-Fenton processes J. Hazard. Mater. 146 2007 564 568
91. S.M. Kim, S.U. Geissen, and A. Vogelpohl Landfill leachate treatment by a photoassisted Fenton reaction Water Sci. Technol. 35 1997 239 248
92. O. Legrini, E. Oliveros, and A.M. Braun Photochemical processes for water treatment Chem. Rev. 93 1993 671 698
93. A.M. Amat, A. Arques, M.A. Miranda, and S. Segui Photo-Fenton reaction for the abatement of commercial surfactants in a solar pilot plant Sol. Energy 77 2004 559 566
94. S.M. Kim, and A. Vogelpohl Degradation of organic pollutant by the photo-Fenton-process Chem. Eng. Technol. 21 1998 187 191
95. Z.M. Li, P.J. Shea, and S.D. Comfort Nitrotoluene degradation by UV-catalyzed Fenton oxidation Chemosphere 36 1998 1849 1865
96. P.L. Huston, and J.J. Pignatello Degradation of selected pesticide active ingredients and commercial formulations in water by the photo-assisted Fenton reaction Water Res. 33 1999 1238 1246
97. 2 system Water Res. 34 2000 895 901
98. I.A. Balcioglu, T. Arslan, M.T. Sacan, and Homogeneous heterogeneous advanced oxidation of the two commercial reactive dyes Environ. Technol. 22 2001 813 822
99. F. Martinez, G. Calleja, J.A. Melero, and R. Molina Heterogeneous photo-Fenton degradation of phenolic aqueous solutions over iron-containing SBA-15 catalyst Appl. Catal. B: Environ. 60 2005 181 190
100. C. Wu, X. Liu, D. Wej, J. Fan, and L. Wang Photosonochemical degradation of phenol in water Water Res. 35 2001 3927 3933
101. P. Vaishnave, A. Kumar, R. Ameta, P.B. Punjabi, and S.C. Ameta Photo oxidative degradation of azure-B by sono-photo-Fenton and photo-Fenton reagents Arabian J. Chem. 2012 10.1016/j.arabjc.2010.12.019
102. Y. Segura, R. Molina, F. Martinez, and J.A. Melero Integrated heterogeneous sono-photo-Fenton processes for the degradation of phenolic aqueous solution Ultrason. Sonochem. 16 2009 417 424
103. F. Mendez-Arriaga, R.A. Torres-Palma, C. Petrier, S. Esplugas, J. Gimenez, and C. Pulgarin Mineralization enhancement of a recalcitrant pharmaceutical pollutant in water by advanced oxidation hybrid processes Water Res. 43 2009 3984 3991
104. X. Zhong, S. Royer, H. Zhang, Q. Huang, L. Xiang, S. Valange, and J. Barrault Mesoporous silica iron-doped as stable and efficient heterogeneous catalyst for the degradation of C.I. Acid Orange 7 using sono-photo-Fenton process Sep. Purif. Technol. 80 2011 163 171
105. J.M. Joseph, H. Destaillats, H.M. Hung, and M.R. Hoffmann The sonochemical degradation of azobenzene and related azo dyes: rate enhancements via Fenton's reactions J. Phys. Chem. A 104 2000 301 307
106. C. Minero, M. Lucchiari, D. Vione, and V. Maurino Fe(III)-enhanced sonochemical degradation of methylene blue in aqueous solution Environ. Sci. Technol. 39 2005 8936 8942
107. Y.G. Adewuyi Sonochemistry in environmental remediation. 1. Combinative and hybrid sonophotochemical oxidation processes for the treatment of pollutants in water Environ. Sci. Technol. 39 2005 3409 3420
108. M.E. Abdelsalam, and P.R. Birkin A study investigating the sonoelectrochemical degradation of an organic compound employing Fenton's reagent Phys. Chem. Chem. Phys. 4 2002 5340 5345
109. Y. Yasman, V. Bulatov, V.V. Gridin, S. Agur, N. Galil, R. Armon, and I. Schechter A new sono-electrochemical method for enhanced detoxification of hydrophilic chloroorganic pollutants in water Ultrason. Sonochem. 11 2004 365 372
110. M.A. Oturan, I. Sires, N. Oturan, S. Perocheau, J.L. Laborde, and S. Trevin Sonoelectro-Fenton process: a novel hybrid technique for the destruction of organic pollutants in water J. Electroanal. Chem. 624 2008 329 332
111. H. Li, H. Lei, Q. Yu, Z. Li, X. Feng, and B. Yang Effect of low frequency ultrasonic irradiation on the sonoelectro-Fenton degradation of cationic red X-GRL Chem. Eng. J. 160 2010 417 422
112. S.S. Martinez, and E.V. Uribe Enhanced sonochemical degradation of azure B dye by the electroFenton process Ultrason. Sonochem. 19 2012 174 178
113. B. Boye, M.M. Dieng, and E. Brillas Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods Environ. Sci. Technol. 36 2002 3030 3035
114. A. Babuponnusami, and K. Muthukumar Advanced oxidation of phenol: a comparison between Fenton, electro-Fenton, sono-electro-Fenton and photo-electro-Fenton processes Chem. Eng. J. 183 2012 1 9
115. E. Brillas, M.A. Banos, and J.A. Garrido Mineralization of herbicide 3,6-dichloro-2-methoxybenzoic acid in aqueous medium by anodic oxidation, electro-Fenton and photoelectro-Fenton Electrochim. Acta 48 2003 1697 1705
116. B. Boye, M.M. Dieng, and E. Brillas Anodic oxidation, electro-Fenton and photoelectro-Fenton treatments of 2,4,5-trichlorophenoxyacetic acid J. Electroanal. Chem. 557 2003 135 146
117. E. Brillas, B. Boye, M.M. Dieng, and General UV-assisted cathodic Fenton treatments for the mineralization of herbicide MCPA J. Electrochem. Soc. 150 2003 583 589
118. S. Irmak, H.I. Yavuz, and O. Erbatur Degradation of 4-chloro-2- methylphenol in aqueous solution by electro-Fenton and photoelectro-Fenton processes Appl. Catal. B: Environ. 63 2006 243 248
119. C. Flox, J.A. Garrido, R.M. Rodriguez, P.L. Cabot, F. Centellas, C. Arias, and E. Brillas Mineralization of herbicide mecoprop by photoelectro-Fenton with UVA and solar light Catal. Today 129 2007 29 36
120. E. Brillas, E. Mur, R. Sauleda, L. Sanchez, J. Peral, X. Domenech, and J. Casado Aniline mineralization by AOPs: anodic oxidation, photocatalysis, electro-Fenton and photoelectro-Fenton processes Appl. Catal. B: Environ. 16 1998 31 42
121. R. Priambodo, Y.J. Shih, Y.J. Huang, and Y.H. Huang Treatment of real wastewater using semi batch (photo)-electro-Fenton method Sustain. Environ. Res. 21 2011 389 393
122. A. Wang, Y.Y. Li, and A.L. Estrada Mineralization of antibiotic sulfamethoxazole by photoelectro-Fenton treatment using activated carbon fiber cathode and under UVA irradiation Appl. Catal. B: Environ. 102 2011 378 386
123. B. Iurascu, I. Siminiceanu, D. Vione, M.A. Vicente, and A. Gil Phenol degradation in water through a heterogeneous photo-Fenton process catalyzed by Fe-treated laponite Water Res. 43 2009 1313 1322
124. R.M. Powell, R.W. Puls, S.K. Hightower, and D.A. Sabatini Coupled iron corrosion and chromate reduction: mechanisms for subsurface remediation Environ. Sci. Technol. 29 1995 1913 1922
125. K.D. Warren, R.G. Arnold, T.L. Bishop, L.G. Lindholm, and E.A. Betterton Kinetics and mechanism of reductive dehalogenation of carbon tetrachloride using zero-valence metals J. Hazard. Mater. 41 1995 217 227
126. S.H. Joo, A.J. Feitz, and T.D. Waite X oxidative degradation of the carbothioate herbicide, molinate using nanoscale zero-valent iron Environ. Sci. Technol. 38 1995 2242 2247
127. A. Babuponnusami, and K. Muthukumar Removal of phenol by heterogenous photo electro Fenton-like process using nano-zero valent iron Separ. Purif. Technol. 98 2012 130 135
128. J.A. Bergendahl, and T.P. Thies Fenton's oxidation of MTBE with zero-valent iron Water Res. 38 2004 327 334
129. 2/iron powder system Chemosphere 32 1996 947 958
130. Y. Takemura, K. Seno-o, T. Mukai, and M. Suzzuki Decomposing organic chlorine compounds in dry cleaning wastewater by Fenton's reaction on reticulated iron Water Sci. Technol. 30 1994 129 137
131. S.H. Joo, A.J. Feitz, D.L. Sedlak, and T.D. Waite Quantification of the oxidizing capacity of nanoparticulate zero-valent iron Environ. Sci. Technol. 39 2005 1263 1268
132. A.J. Feitz, S.H. Joo, J. Guan, Q. Sun, D.L. Sedlak, and T.D. Waite Oxidative transformation of contaminant s using colloidal zero-valent iron Colloids Surf., A 265 2005 88 94
133. I. Sanchez, S. Frank, J. Font, A. Fortuny, A. Fabregat, and C. Bengoa Elimination of phenol and aromatic compounds by zero valent iron and EDTA at low temperature and atmospheric pressure Chemosphere 68 2007 338 344
134. T. Zhou, T.T. Lim, X. Lu, Y. Li, and F.S. Wong Simultaneous degradation of 4CP and EDTA in a heterogeneous ultrasound/Fenton like system at ambient circumstance Sep. Purif. Technol. 68 2009 367 374
135. T. Zhou, X. Lu, T.T. Lim, Y. Li, and F.S. Wong Degradation of chlorophenols (CPs) in an ultrasound-irradiated Fenton-like system at ambient circumstance: the QSPR (quantitative structure-property relationship) study Chem. Eng. J. 156 2010 347 352
136. T. Zhou, X. Lu, J. Wang, F.S. Wong, and Y. Li Rapid decolorization and mineralization of simulated textile wastewater in a heterogeneous Fenton like system with/without external energy J. Hazard. Mater. 165 2009 193 199
137. T. Zhou, T.T. Lim, Y. Li, X. Lu, and F.S. Wong The role and fate of EDTA in ultrasound-enhanced zero-valent iron/air system Chemosphere 78 2010 576 582
138. W.X. Zhang Nanoscale iron particles for environmental remediation: an overview J. Nanopart. Res. 5 2003 323 332
139. D. Elliott, and W. Zhang Field assessment of nanoscale bimetallic particles for groundwater treatment Environ. Sci. Technol. 35 2001 4922 4926
140. Y. Xu, and D. Zhou Reductive immobilization of chromate in water and soil using stabilized iron nanoparticles Water Res. 41 2007 2101 2108
141. M.A. Tarr Chemical degradation methods for wastes and pollutants: environmental and industrial applications Sci. Poll. Cont. Series 26 2003 165 200
142. L. Xu, and J. Wang A heterogeneous Fenton-like system with nanoparticulate zero-valent iron for removal of 4-chloro-3-methyl phenol J. Hazard. Mater. 186 2011 256 264
143. W.X. Zhang Nanoscale iron particles for environmental remediation; an overview J. Nanopart. Res. 5 2003 323 332
144. X.Q. Zi, D.W. Elliott, and W.X. Zhang Zero-valent nano particles for abatement of environmental pollutants; materials and engineering aspects Crit. Rev. Solid State Mater. Sci. 31 2006 111 112
145. T. Phenrat, N. Saleh, K. Sirk, R.D. Tilton, G.V. Lowry, and Aggregation Sedimentation of aqueous nanoscale zerovalent iron dispersions Environ. Sci. Technol. 41 2007 284 290
146. 0 in and on PVA microspheres for nitrobenzene reduction J. Hazard. Mater. 172 2009 1357 1364
147. A. Babuponnusami, and K. Muthukumar Treatment of phenol-containing wastewater by photo electro-Fenton method using supported nanoscale zero-valent iron Environ. Sci. Pollut. Res. 2012 10.1007/s11356-012-0990-1
148. A.N. Bezbaruah, S. Krajangpan, B.J. Chisholm, E. Khan, and J.J.E. Bermudez Entrapment of iron nanoparticles in calcium alginate beads for groundwater remediation applications J. Hazard. Mater. 166 2009 1339 1343
149. ® and its applicability to the photo-Fenton method Chemosphere 38 1999 2315 2325
150. J. Feng, X. Hu, P.L. Yue, H.Y. Zhu, and G.Q. Lu A novel laponite clay-based Fe nanocomposite and its photo-catalytic activity in photo-assisted degradation of Orange-II Chem. Eng. Sci. 58 2003 679 685
151. M.A. De Leon, J. Castiglioni, J. Bussi, and M. Sergio Catalytic activity of an iron-pillared montmorillonitic clay mineral in heterogeneous photo-Fenton process Catal. Today 133-135 2008 600 605
152. A. Bozzi, T. Yuranova, J. Mielczarski, A. Lopez, and J. Kiwi Abatement of oxalates catalyzed by Fe-silica structured surfaces via cyclic carboxylate intermediates in photo-Fenton reactions Chem. Commun. 19 2002 2202 2203
153. 3 catalyst Catal. Commun. 8 2007 981 986
154. M. Rios-Enriquez, N. Shahin, C. Duran-De-Bazua, J. Lang, E. Oliveros, S.H. Bossmann, and A.M. Braun Optimization of the heterogeneous Fenton - oxidation of the model pollutant 2,4-xylidine using the optimal experimental design methodology Sol. Energy 77 2004 491 501
155. X. Lv, Y. Xu, K. Lv, and G. Zhang Photo-assisted degradation of anionic and cationic dyes over iron(III)-loaded resin in the presence of hydrogen peroxide J. Photochem. Photobiol. A- Chem. 173 2005 121 127
156. 2 photocatalysts on the cotton material for application in a flow photocatalytic reactor for decomposition of phenol in water J. Hazard. Mater. 151 2008 623 627
157. M.A.P. Nunes, H.V. Real, P.C.B. Fernandes, and M.H.L. Ribeiro Immobilization of naringinase in PVA-alginate matrix using an innovative technique Appl. Biochem. Biotechnol. 160 2010 2129 2147
158. R.J. Kieber, S.A. Sicrabal, B.J. Smith, and J.D. Willey Organic complexation of Fe(II) and its impact on the redox cycling of iron in rain Environ. Sci. Technol. 39 2005 1576 1583
159. M.R. Dhananjeyan, J. Kiwi, P. Albers, and O. Enea Photo-assisted immobilized Fenton degradation upto pH 8 of Azo Dye Orange II mediated by Fe3+/Nafion/Glass fibers Hel. Chim. Acta 84 2001 3433 3445
160. S. Sabhi, and J. Kiwi Degradation of 2,4-dichlorophenol by immobilized iron catalyst Water Res. 35 2001 1994 2002
161. J. Fernandez, J. Bandara, A. Lopez, P. Buffat, and J. Kiwi Photoassisted Fenton degradation of nonbiodegradable Azo Dye (Orange II) in Fe-free solutions mediated by cation transfer membranes Langmuir 15 1999 185 192
162. A. Bosnjakovic, M.K. Kadirov, and S. Schlick Using ESR spectroscopy to study radical intermediates in proton-exchange membranes exposed to oxygen radicals Res. Chem. Intermed. 33 2007 677 687
163. J. Ramirez, L.A. Godinez, M. Mendez, Y. Meas, and F.J. Rodriguez Heterogeneous photo-electro-Fenton process using different iron supporting materials J. Appl. Electrochem. 40 2010 1729 1736
164. M. Noorjahan, V. Durga Kumari, M. Subrahmanyan, L. Panda, and Immobilized Fe(III)-HY: an efficient and stable photo-Fenton catalyst Appl. Catal. B: Environ. 57 2005 291 298
165. M.B. Kasiri, H. Aleboyeh, and A. Aleboyeh Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst Appl. Catal. B: Environ. 84 2008 9 15
166. R.L. Pozzo, M.A. Baltanas, and A.E. Cassano Supported titanium oxide as photocatalyst in water decontamination: state of the art Catal. Today 39 1997 219 231